Abstract
Abstraction of groundwater resources is increasing over the years to meet its ever-increasing demand for industrial, agricultural and domestic purposes throughout the world. The scenario is even worse in the east flowing rivers of the Western Ghats, where the demand of water is high under changing climatic conditions. Such situation may affect the groundwater resources of the river basin on a long run. The aim of the present study is to characterize the geochemistry of groundwater in Tamiraparani sub-basin through geochemical modeling and deduce the ionic interactions with the aid of geostatistical and multivariate statistical techniques. A total of 40 groundwater samples from shallow aquifers were collected randomly throughout the sub-basin for assessing its physicochemical parameters, which include physical properties of the water, major ions and nutrients. Two major hydrogeochemical facies were identified such as mixed Ca-Mg-Cl and Ca-HCO3 groups. The nutrients derived from agricultural runoff, urban discharge and organic decomposition alters the nutrient level in the groundwater. The dissolution/precipitation of minerals such as calcite and dolomite controls the chemical constituents of the groundwater. The multivariate statistical analysis indicates that natural weathering of source rocks is the main contributors of ions in the groundwater followed by anthropogenic activities such as agricultural practices and urbanization. The insights obtained from this study can be helpful for sustainable groundwater management and long-term monitoring studies.
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References
Almasri, M.N. and Kaluarachchi, J.J. (2004) Assessment and management of long-term nitrate pollution of ground water in agriculture-dominated watersheds. Jour. Hydrol., v.295, pp.225–245.
APHA (1995) Standard methods for the examination of water and wastewater, 19th ed, American Public Health Association, Washington, DC, pp.23-68.
Brindha, K. and Elango, L. (2011) Spatial assessment of groundwater quality based on minor ions. American Geophysical Union 2011 Fall Meeting, San Francisco, California, USA, 5th to 9th December 2011, H53H-1500.
CGWB (2009) Report of the group for suggesting new and alternate methods of ground water resources assessment, Central Ground Water Board, Ministry of Water Resources, Govt. of India, Faridabad, 26p.
Chandrasekar, N., Selvakumar, S., Srinivas, Y., Wilson, J.S.J., Peter, T.S. and Magesh, N.S. (2014) Hydrogeochemical assessment of groundwater quality along the coastal aquifers of southern Tamil Nadu, India. Environ. Earth Sci., v.71, pp.4739–4750.
Edmunds, W.M. (1994) Characterization of groundwater in semi-arid and arid zones using minor elements. In: H. Nash and G.J.H. McCall (Eds.) Groundwater Quality. Chapman and Hall, London, pp.19–30.
Golterman, H.L. (1975) Physiological Limnology: an approach to the physiology of lake ecosystems, Elsevier Scientific Publication, Amsterdam, 489p.
GSI (1998) Geological and Mineral map of Tamil Nadu and Pondicherry, published in 1:500,000 scale by the Director General, Geological Survey of India.
Jagadeshan, G. and Elango, L. (2015) Suitability of Fluoride-Contaminated Groundwater for Various Purposes in a Part of Vaniyar River Basin, Dharmapuri District, Tamil Nadu. Water Qual. Expo. Health, no.7, pp.1–10.
Kanagaraj, G. and Elango, L. (2016) Hydrogeochemical processes and impact of tanning industries on groundwater quality in Ambur, Vellore district, Tamil Nadu, India. Environ. Sci. Poll. Res., v.23, pp.24364–24383.
Krishnakumar, S., Bharani, R., Magesh, N.S., Godson, P.S. and Chandrasekar, N. (2014) Hydrogeochemistry and groundwater quality appraisal of part of south Chennai coastal aquifers, Tamil Nadu, India using WQI and fuzzy logic method. Appld. Water Sci., v.4, pp.341–350.
Krishnakumar, S., Magesh, N.S. and Chandrasekar, N. (2012a) Trace element concentration in groundwater, Tuticorin city, Tamil Nadu, India, Bull. Environ. Contamin. Toxicol., v.88, pp.876–879.
Krishnakumar, S., Chandrasekar, N., Seralathan, P., Godson, P.S. and Magesh, N.S. (2012b) Hydrogeochemical study of shallow carbonate aquifers, Rameswaram Island, India. Environ. Monit. Assess. v.184, pp.4127–4138.
Krivoruchko, K. (2011) Spatial statistical data analysis for GIS Users. ESRI Press, Redlands, CA, 928p.
Laftouhi, N., Vanclooster, M. and Jalal, M. (2003) Groundwater nitrate pollution in the Essaouira Basin (Morocco), C. R. Geosci., v.335, pp.307–317.
Lloyd, J.W. and Heathcoat, J.A. (1985) Natural inorganic chemistry in relation to groundwater, Claredon Press, Oxford.
Lloyd, J.W., Miles, J.C., Chessman, G.R. and Bugg, S.F. (1981) A groundwater resources study of a Pacific Ocean atoll-Tarawa, Gilbert Islands. Water Resour. Bull., v.16, pp.646–653.
Ma, J., Ding, Z., Wei, G., Zhao, H. and Huang, T. (2009) Sources of water pollution and evolution of water quality in the Wuwei basin of Shiyang river, northwest China. Jour. Environ. Manag., v.90, pp.1168–1177.
Magesh, N.S. and Chandrasekar, N. (2013) Evaluation of spatial variations in groundwater quality by WQI and GIS technique: a case study of Virudunagar district, Tamil Nadu, India. Arab. Jour. Geosci., v.6, pp.1883–1898.
Magesh, N.S., Chandrasekar, N. and Elango, L. (2016) Occurrence and distribution of fluoride in the groundwater of the Tamiraparani River basin, South India: a geostatistical modeling approach. Environ. Earth Sci., v.75, pp.1483.
Magesh, N.S., Chandrasekar, N. and Elango, L. (2017) Trace element concentrations in the groundwater of the Tamiraparani river basin, South India: Insights from human health risk and multivariate statistical techniques. Chemosphere, v.185, pp.468–479.
Magesh, N.S., Krishnakumar, S., Chandrasekar, N. and Soundranayagam, J.P. (2013) Groundwater quality assessment using WQI and GIS techniques, Dindigul district, Tamil Nadu, India. Arab. Jour. Geosci., v.6, pp.4179–4189.
Manoj, S., Thirumurugan, M., Elango, L. (2017) An integrated approach for assessment of groundwater quality in and around uranium mineralized zone, Gogi region, Karnataka, India. Arab. Jour Geosci., v.10, pp.557.
Milovanovic, M. (2007) Water quality assessment and determination of pollution sources along the Axios/Vardar river, southeastern Europe. Desalination, v.213, pp.159–173.
Narayanaswami, S. and Lakshmi, P. (1967) Charnockite rocks of Tinnevelly district, Madras, Jour. Geol. Soc. India, v.8, pp.38–50.
Nas, B. and Berktay, A. (2006) Groundwater contamination by nitrates in the city of Konya (Turkey): a GIS perspective. Jour. Environ. Manag., v.79, pp.30–37.
Nickson, R.T., McArthur, J.M., Sherestha, B., Kyaw-Myint and Lowry, D. (2005) Arsenic and other drinking water quality issues, Muzaffargarh district. Pakistan. Appld. Geochem., v.20, pp.55–68.
Nriagu, J.O. (1986) Chemistry of the River Niger II. Trace metals. Sci. Total Environ., v.58, pp.89–92.
Obiri, S. (2007) Determination of heavy metals in water from boreholes in Dumasi in the Wassa West District of western region of Republic of Ghana, Environ. Monit. Assess., v.130, pp.455–463.
Parkhurst, D.L. and Appelo, C.A.J. (1999) User’s guide to PHREEQC (version 2)—a computer program for speciation, batch-reaction, one-dimensional transport, and inverse geochemical calculations, USGS Water-Resources Investigations Report., no.99, pp.42–59.
Piper, A.M. (1944) A graphic procedure in the geochemical interpretation of water analysis, Trans. Amer. Geophys. Union, v.25, pp.914–923.
Pitchamuthu, C.S. (1979) Physical geography of India, National Book Trust India, New Delhi, p.212.
Prasanth, S.V.S., Magesh, N.S., Jitheshlal, K.V., Chandrasekar, N. and Gangadhar, K. (2012) Evaluation of groundwater quality and its suitability for drinking and agricultural use in the coastal stretch of Alappuzha District, Kerala, India, Appl. Water Sci., v.2, pp.165–175.
Raghunath, H.M. (1987) Groundwater. 2nd ed. New York: John Wiley, p.563.
Raju, K.C.B. (1998) Importance of recharging depleted aquifers: State of the art of artificial recharge in India, Jour. Geol. Soc. India, v.51, pp.429–454.
Ramyapriya, R. and Elango, L. (2018) Evaluation of geogenic and anthropogenic impacts on spatio temporal variation in quality of surface water and groundwater along Cauvery River, India. Environ. Earth Sci., v.77, pp.2.
Reid, D.C., Edwards, A.C., Cooper, D., Wilson, E. and Mcgaw, B.A. (2003) The quality of drinking water from private water supplies in Aberdeenshire, UK. Water Res., v.37, pp.245–254.
Schoeller, H. (1965) Qualitative evaluation of groundwater resources, In: methods and techniques of groundwater investigations and development. UNESCO, pp.54–83.
Schoeller, H. (1967) Geochemistry of ground water, an international guide for research and practice. UNESCO, v.15, pp.1–18.
Selvakumar, S., Chandrasekar, N. and Magesh, N.S. (2012) Preliminary investigation of groundwater quality along the coastal aquifers of southern Tamil Nadu using GIS techniques. Bonfring Int. Jour. Ind. Engg. Manag. Sci., v.2, pp.46–52.
Singh, K.P., Singh, V.K., Malik, A. and Basant, N. (2006) Distribution of nitrogen species in groundwater aquifers of an industrial area in alluvial Indo-Gangetic Plains—a case study. Environ. Geochem. Health., v.28, pp.473–485.
Tijani, M.N. (2009) Contamination of shallow groundwater system and soil–plant transfer of trace metals under amended irrigated fields. Agric. Water Manag., v.96, pp.437–444.
Wakida, F.T. and Lerner, D.N. (2005) Non-agricultural sources of groundwater nitrate: a review and case study. Water Res., v.39, pp.3–16.
WHO (2004) Guidelines for drinking water quality, 3rd edition. World Health Organization, Geneva, p.31.
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Magesh, N.S., Chandrasekar, N. & Elango, L. Groundwater Environment of a Tropical East Flowing River of Western Ghats, Southern India. J Geol Soc India 92, 634–644 (2018). https://doi.org/10.1007/s12594-018-1078-4
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DOI: https://doi.org/10.1007/s12594-018-1078-4