Abstract
Organic-rich shale samples from the Late Cretaceous Galhak Formation were collected from one well location in the northern Melut Basin, Sudan, and analyzed by integrated organic geochemical and microscopic techniques. The study investigates the nature and preservation conditions of the organic facies and their relevance to petroleum resource potential. Judging from the high total organic contents (total organic carbon (TOC) > 2%), the analyzed Galhak shales are organically rich and include favorable source rocks. The organic richness in these shale sediments may be attributed to enhance the preservation of organic matter under suboxic conditions as implied from the n-alkanes and isoprenoid biomarkers. Biological markers, including of n-alkanes, isoprenoids, terpanes, and steranes, further suggest that the Galhak shale sediments were deposited in a relatively fresh lacustrine environment and received largely aquatic organic matter of plankton and bacteria with little terrestrial plant input. An abundance of aquatic-derived organic matter is consistent with types I and II kerogen as indicated by high Rock-Eval HI values of more than 400 mg HC/g TOC. The hydrogen-rich kerogen types I and II in the analyzed samples suggests an oil-prone source. According to the optical and geochemical maturity indicators, the organic matter in the Galhak oil shale is thermally immature; thus, they have not reached sufficient oil-window maturity for commercial oil generation. Therefore, the deeper parts of the Melut Basin, where the Galhak Formation reached high mature of peak-oil generation window, are recommended for further petroleum exploration and production.
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Introduction
Sudan’s interior contains several onshore sedimentary basins (Fig. 1), all of which are related to the rifting activities of the Western, Central, and East African Rift systems (Browne et al. 1985; Schull 1988). The Muglad and Melut onshore rift basins constitute the richest petroleum province in Sudan (Dou et al. 2007; Makeen et al. 2015a, b; 2016a, b). The Muglad Basin is an important hydrocarbon basin containing several hydrocarbon accumulations and several well-known oil fields (Makeen et al. 2015b). With its high potential for conventional petroleum exploration and development, the Muglad Basin has received attention of the petroleum industry and academic researchers (e.g., Dou et al. 2013; Makeen et al. 2015a, b, 2016a, b; Mohamed et al. 1999; Mohamed et al. 2000; Mohamed et al. 2002; Tong et al. 2004).
The Melut Basin, another important Sudanese rift basin, is the target of this study. This basin lies in the Upper Nile and Jonglei regions, south of the capital Khartoum, and east of the Nile River (Fig. 1A). It contains many oilfields (Fig. 1B), including the Great Palogue oilfield with estimated reserves of 900 million barrels (Dou et al. 2007). Although hydrocarbons exist in the Melut Basin, hydrocarbon exploration in this region began only recently, and data are scarce. Published research on the geochemical characteristics of source rocks in the Melut Basin and their relation to potential petroleum generation has been conducted and provided is limited (e.g., Dou et al. 2007). According to Dou et al. (2007), the main source rocks in the Melut Basin are the lacustrine shales of the Early Cretaceous Al-Gayger Formation; however, organic-rich shale intervals are found in the Late Cretaceous Galhak Formation and need to be studied. In parallel with previous studies of the organic-rich interval in the older Al-Gayger Formation (e.g., Dou et al. 2007), we considered characteristics of the organic-rich shale intervals within the Galhak Formation to obtain more information on the origin of organic matter in the Galhak shale intervals and gain deep insight into their hydrocarbon generation potential, with relevance to a broad perspective on exploring for conventional petroleum resources.
Using organic geochemical analyses coupled with the kerogen microscopic method, this study comprehensively investigates the source rock characteristics of the organic-rich shale intervals in the Late Cretaceous Galhak Formation. Samples were collected from a well in the northern Melut Basin. The aim is to understand the richness of organic matter, the nature of the organic facies, and their connection to the oil-source rock potential. In addition, the nature and environmental conditions of deposition associated with the organic matter sources, the biomarker results of the aliphatic fraction are integrated into the bulk geochemical and visual kerogen data.
Geological setting
The Melut rift basin extends over 33,000 km2. With a maximum width of 100 km and a length exceeding 310 km (Dou et al. 2007), it ranges from southeast Sudan to central Ethiopia (Fig. 1A). The Melut Basin is defined as an intracontinental Cretaceous–Tertiary rift basin resulting from strike-slip movement (Binks and Fairhead 1992; Genik 1993; Guiraud and Maurin 1992). Rifting began in the Early Cretaceous (Guiraud and Maurin 1992; McHargue et al. 1992) creating several sub-basin rift systems in the Melut Basin, namely, the Northern, Eastern, Central, Western, and Southeastern (Fig. 2A) sub-basins characterized by downwarped, horst, and tilted blocks (Fig. 2B), which developed favorable structural traps for hydrocarbons. These structural traps formed during the Early Cretaceous and evolved during the Tertiary (Genik 1993; Guiraud and Maurin 1992; McHargue et al. 1992).
The Melut Basin contains up to 10 km of sediments (Dou et al. 2007), ranging in age from Early Cretaceous to Quaternary (Fig. 3). The older exposed sedimentary rock is represented by the Early Cretaceous Al-Gayger Formation (Fig. 3) resting on Precambrian basement rocks with an unconformable content. The Al-Gayger Formation is divided into two units varying from fluvial–deltaic to lacustrine in their sedimentary environment (Dou et al. 2007). The lower unit is mainly composed of thin sandstones that are interbedded with thin claystones, whereas the upper unit contains dark gray and black dense shales with interbedded thin sandstones (Fig. 3). The upper part, representing the semi-deep and deep lacustrine sediments, containing proven source rocks in the Melut Basin (Dou et al. 2007). The Al-Gayger Formation is accompanied by thick sediments from the Late Cretaceous Galhak and Melut Formations (Fig. 3). These sediments are mainly sandstones with interbedded shales of the Galhak and Melut Formations, indicating a depositional environment ranging from deltaic/fluvial to shallow lacustrine (Dou et al. 2007). The Galhak Formation lies on the Al-Gayger shales with an unconformable contact of late Senomanian to Turonian age (Dou et al. 2007), which was formed in braided delta to shallow lake environments (Dou et al. 2007).
The Late Cretaceous Melut Formation was followed by mixed sandstone and claystone clastic sediments of the Tertiary megasequence with an unconformable contact (Fig. 3). The Tertiary megasequence comprises the Samma, Yabus, Adar, Jimidi, Lau, Miadol, and Daga Formations (Fig. 3). The Tertiary sediments are mainly composed of sandstones and siltstones with interbedded claystones and shales. They were deposited during the Paleocene–Pliocene (Fig. 3), although the Cretaceous Melut and Paleocene Samma and Yabus sandstones in the Melut Basin are primarily considered petroleum reservoirs (Fig. 3). The overlying Eocene Adar Formation mainly comprises sediments such as shales and claystones, providing excellent regional seal rocks for the underlying Cretaceous and Paleocene oil-bearing reservoir rocks (Fig. 3). The Quaternary-dated Agor Formation is the youngest stratigraphic formation in the basin that mainly comprises sandstones (Fig. 3) and that unconformably covers the Late Miocene–Pliocene Daga Formation.
Samples and methods
The Melut Basin is still under hydrocarbon exploration and the available samples for the Galhak Formation the basin are limited, where the drilled wells are also limited. In this regard, thirteen cuttings samples were collected from the shale intervals of the Late Cretaceous Galhak Formation in a well located in the northern Melut Basin (Table 1). Prior to analysis, the cuttings were washed with cold water to remove contaminants from drilling mud and other drilling additives present.
The cuttings samples were finely milled (60 μm) for TOC content determination using a LECO CS-125 instrument. Of these samples, seven samples were subsequent screened using a Rock-Eval II instrument to determine the basic source rock parameters. These parameters include S1 (amount of free hydrocarbons), S2 (amount of hydrocarbons generated by thermal cracking of non-volatile organics), S3 (amount of CO2 generated by kerogen pyrolysis), and Tmax (temperature of maximum hydrocarbon release by kerogen cracking) of the samples were measured during pyrolysis. The geochemical parameters—hydrogen index (HI), oxygen index (OI), potential yield (PY), and production index (PI)—were calculated (see Table 1) as defined by Espitalie et al. (1977, 1985), and Peters and Cassa (1994).
Four representative shale samples were selected for further various organic geochemical analyses: extraction and fractionation of bitumen, and gas chromatography and gas chromatography–mass spectrometry (GC–MS) of the saturated hydrocarbon fraction. In addition, their vitrinite reflectance was measured and their kerogen was visually examined. The samples were selected based on their Rock-Eval pyrolysis results.
After grinding, the bitumen in the analyzed four shale samples was extracted using a solvent of DCM and methanol (CH3OH) for 72 h. The extracted bitumen was then separated into aliphatic, aromatic, and polar fractions using liquid column chromatography with silica gel topped with alumina oxide. The aliphatic fraction of the samples was analyzed using a flame ionization detector gas chromatograph. The furnace temperature of the gas chromatograph was programmed between 140°C and 211 °C at a rate of 1 °C/min and held at 300 °C for 10 min.
Additionally, the saturated fraction of three extracted samples was analyzed with a gas chromatography–mass spectrometry (GC–MS) equipped. The flame ionization detector of GC-MS experimental analysis was operated in an HP–DB5–MS column with a distance of 30 m, an interior diameter of 0.30 mm, and a film thickness of 0.25 μm. The furnace temperature was programmed between 50°C and 180 °C at a rate of 3 °C/min and held at 300 °C for 25 min.
The terpane and sterane biomarkers were estimated by integrating the m/z 191 and m/z 217 ions, respectively, using Chemstation software. The biomarker compounds were selected based on retention times and mass spectra reported in published works such as Hakimi et al. (2020), Makeen et al. (2015a), and Philp (1985). Biomarker ratios were calculated using peak heights.
The organic geochemical analyses of the four representative shale samples were augmented through microscopic observations, including visual kerogen microscopy and reflectance measurements of the vitrinite organic matter using a Leitz Dialux/Laborlux microscope and a Leitz Orthoplan/MPV photometry system.
Microscopic examination of visual kerogen was prepared using standard palynological procedures; however, oxidation or acetolysis were omitted. Acid maceration requires hot hydrochloric acid (30% HCl) to dissolve the carbonates and hot hydrofluoric acid (60% HF) to extract or break down the silicates. Mineral residues were isolated from the kerogen using combined ultrasonic vibration and flotation in zinc bromide. The kerogen residues were categorized by placing them in glycerin jelly on glass slides and examining them under transmitted light using a Leitz Dialux/Laborlux microscope.
The vitrinite reflectance (%VRo) of two samples was analyzed using the polished block technique. The whole cutting samples were rough-crushed to approximately pea-sized fragments (2–3 mm) and then coated with epoxy resin. The VRo was measured using standard methods as described by Taylor et al. (1998). The analysis was conducted using oil immersion with a Zeiss microscope fitted with a Leitz Orthoplan/MPV photometry device under reflected light. The reflectance was calibrated on glasses and gemstones in the VRo range of 0.2–5.1%.
Results and discussion
Richness of organic matter and generative potential
The richness of organic matter content, and contributing to petroleum generation potential during maturation was primarily evaluated using TOC content (Peter and Cassa 1994). From the weight percentage of the TOC content, we can assess the organic richness in a source rock (Bissada 1982; Peter and Cassa 1994; Katz and Lin 2014).
In this study, TOC and Rock-Eval pyrolysis results are shown in Table 1 and used to evaluate the amount of organic matter in the analyzed shale samples from the Galhak Formation and their generative potential. In this regard, the TOC contents of the analyzed Galhak shales ranged from 2.24 to 5.08%. Therefore, the analyzed Galhak shales are considered to have probably high potential as source rocks, with the TOCs exceeding 2% (Bissada 1982). TOC content alone is not enough to satisfy all the requirements of a generative potential and must be collaborated with the Rock-Eval S2 yield (e.g., Peters 1986; Peters and Cassa 1994; Dembicki 2009). The analyzed shale samples exhibited high total hydrocarbon yields from kerogen cracking (S2) in the range of 10.44–29.82 mg HC/g rock (Table 1). The high S2 yields concur with the TOC results and show that most of the analyzed shale samples of the Galhak Formation attained very good to excellent source rock potential for hydrocarbon generation (Fig. 4).
Kerogen characteristics
Quantitative and qualitative results of organic type were geochemically and optically investigated throughout this study (Table 1). From these results, we can assess the kerogen types and their characteristics, representing the source of organic matter input in the analyzed shale samples.
The qualitative organic type (bulk kerogen) in the analyzed shale samples was evaluated based on their geochemical parameters of Rock-Eval HI and OI (Espitalie et al. 1985; Peters and Cassa 1994; Mukhopadhyay et al. 1995).
The analyzed shale sediments are dominated by HI with values between 452 and 612 mg HC/g TOC, and underwent minimal kerogen oxidation, as evidenced by their relatively low OI values (<69 mg CO2/g TOC; see Table 1). Therefore, both HI and OI parameters were useful for classifying the bulk kerogen in the analyzed Galhak shales. Based on the overall Rock-Eval results, the analyzed samples mainly fell into types I and II kerogen, as obtained from the modified van Krevelen diagram of HI against OI (Fig. 5A). A modified-HI versus Tmax plot further confirmed that the analyzed shale samples are dominated by kerogen of types I and II (Fig. 5B).
The derived organic facies are compatible with the optical application for obtaining the quantitative organic matter type under microscope, and provides accurate and more reliable assessments of the kerogen type (e.g., Makeen et al. 2015a, b; Abdullah et al. 2017). Table 1 shows summary the kerogen microscopic results, including the organic facies in the analyzed samples. The kerogen assemblages in the analyzed shales were dominated by primarily sapropelic organic matter, with volumes up to 85%. Several analyzed samples also contain minor amounts of vitrinite and inertinite organic matter in the range of 5–10% (Table 1). The high organic sapropelic matter is compatible with the presence of oil-prone kerogen. This inference of the kerogen characteristics is further supported by the distribution of kerogen assemblages (Cornford 1979). The distributions of sapropelic, vitrinite, and inertinite organic matter in the analyzed shale samples (Table 1) are plotted on the ternary diagram of Cornford (1979), and indicate that the organic facies in the analyzed shales predominantly belong to type I kerogen (Fig. 6).
Biomarker fingerprints and their relevance to organic matter inputs and preservation conditions
The nature of the organic matter and preservation conditions of the Galhak shales Formation were assessed using biomarkers and their proportions and parameters (e.g., Huang and Meinschein 1979; Volkman 1986; Waples and Machihara 1991).
The saturated hydrocarbon gas chromatograms and the GC–MS mass fragmentograms of the m/z 191 and m/z 217 ions are presented in Figs. 7 and 8.
The chromatograms of most of the analyzed shale samples show a unimodal distribution of normal alkanes between C13 and C36, with elevated of mid length chain (C18–C27) n-alkanes (Fig. 7), suggesting a mixture of organic matter in the analyzed samples with high abundance of aquatic organic matter and significant amounts of land plants. However, this distribution of normal alkanes further displays a relatively high carbon preference index in the range of 1.23–1.35 (Table 2).
In addition, the chromatograms of the analyzed shale samples contained significant amounts of the acyclic isoprenoid hydrocarbons, i.e., pristane (Pr) and phytane (Ph) (Fig. 7). The chromatograms also revealed a predominance of Pr over Ph (Fig. 7), resulting in relatively high Pr/Ph ratios between 1.97 and 2.57 (Table 2). The isoprenoid ratios relative to the n-alkane concentrations (Pr/n-C17 and Ph/n-C18) were found to be in the range of 0.52–1.08 and 0.28–0.50, respectively (Table 2). The isoprenoids and their ratios are the most commonly used as indicators for the redox conditions and inputs of organic matter in depositional environments (e.g., Chandra et al. 1994; Didyk et al. 1978). In this regard, the relatively high ratios of Pr/Ph, pristane/n-C17, and phytane/n-C18 suggest that a mixture of organic matter deposited in lacustrine environment under suboxic to relatively oxic conditions (Fig. 9).
The GC–MS mass fragmentograms of the m/z 191 and m/z 217 ions affirmed the presence of hopanoids and steroids (Fig. 8) and were further used to provide specific information on the nature of organic matter and sedimentary environmental conditions (Huang and Meinschein 1979; Burwood et al. 1992; Hanson et al. 2000; Marynowski et al. 2000). The mass fragmentogram of m/z 191 reveals a higher proportion of hopanes than tricyclic terpanes (Fig. 8A). The identified hopanoid components included C30 hopane, C29 norhopane, 17α (H)-trisnorneohopane (Tm), 18α (H)-trisnorneohopane (Ts), and C31–C35 homohopanes. The C30-hopanes dominated over the C29 norhopanes (Fig. 8A), with C29/C30 ratios less than 1 (Table 2). Such low C29/C30 ratios imply that the lithofacies are clay-rich sediments (e.g., Gürgey 1999). In particular, C31 dominated the homohopane distributions; however, its proportion gradually decreased with the increasing carbon content (Fig. 8A). Meanwhile, the C31 22R-series homohopanes were less abundant than C30 hopane (Fig. 8A) as evidenced by the low C31 22R homohopane/C30 hopane (C31R/C30H) ratios between 0.11 and 0.16 (see Table 2). The low C31-22R homohopane/C30-hopane (C31R/C30H) ratios are consistent with the accumulation of mixed organic matter in a lacustrine depositional environment as demonstrated from the combination of the Pr/Ph and C31R/C30H ratios (Fig. 10).
Moreover, the low amounts of gammacerane were also recorded in the m/z 191 mass fragmentogram of the analyzed samples (Fig. 8A), yielding low gammacerane/C30 hopane ratios between 0.06 and 0.09 (Table 2). The presence of gammacerane derivatives is characteristic of either hypersalinity or water column stratification during deposition (Moldowan et al. 1985; ten Haven et al. 1989; Sinninghe Damsté et al. 1995). In the analyzed samples, the low amounts of gammacerane in m/z 191 fragmentograms (Fig. 9) and the gammacerane/C30-hopane suggest that the analyzed shale samples were in relatively fresh lacustrine environment.
Sterane and diasterane biomarker compounds were found in the m/z 217 mass fragmentograms of the analyzed shale samples (Fig. 8B). Sterane was abundant in the aliphatic hydrocarbons of the samples (Fig. 8B). Among the regular C27–C29 steranes, the C27 and C29 steranes were more abundant than regular C28 steranes (see the steroid distributions in Fig. 8B). The relative abundances of C27, C28, and C29 regular steranes were 38.52–47.10%, 11.90–26.40%, and 32.90–49.58%, respectively (Table 2).
The distribution of these regular steranes (C27–C29) when plotted on a Huang–Meinschein ternary diagram (1979) provide evidence for the high contributions of planktonic and bacterial organic matter in the analyzed samples (Fig. 11). The plot of C27/C29 regular sterane and Pr/Ph ratios further indicted evidence of high contributions of aquatic organic matter (Fig. 12).
These recognized organic facies are also consistent with the results of the geochemical and visual kerogen analyses (Table 1). The Rock-Eval results reveal rich organic matter in the Galhak Formation samples that are dominated by types I and II kerogen (Fig. 5). An abundance of these kerogen types indicates a dominance of algal and bacteria organic matters (Taylor et al. 1998; Hakimi et al. 2012, 2016). The large quantities of organic matter derived from phytoplankton algae and microorganisms are further indicated by the predominance of sapropelic organic matter observed under the microscope (Table 1; Fig. 6).
Thermal maturation of organic matter
The level of thermal maturity of the organic matter in the Galhak shale analyzed in this study was assessed based on the several maturity indicators, including Rock-Eval geochemical Tmax and production index (PI), vitrinite reflectance (%VRo) (Table 1), and biomarker parameters (Table 2).
The most accurate maturity indicator was vitrinite reflectance (%VRo), which provides valuable information on organic maturation and the evolution of petroleum generation (Teichmüller et al. 1998; Sweeney and Burnham 1990; Waples 1994). The VR values ranged from 0.43 to 0.47% (Table 1), confirming that the analyzed samples are immature.
Temperature of the maximum pyrolysis rate (Tmax) is a commonly used measure of maturity (Bordenave et al. 1993; Peters 1986; Tissot et al. 1987). As kerogen matures, its Tmax increases. During pyrolysis analysis, the Tmax of the analyzed samples was determined as 438°C–447°C (Table 1), suggesting early to peak maturity of the oil window (Fig. 6B).
Along with the VRo values, the PI values of the analyzed samples were deemed sufficiently accurate for maturity evaluation. The PI values were 0.03–0.04 (Table 1), confirming the presence of immature organic matter (Peters and Cassa 1994; Fatma and Sadettin 2013). Furthermore, the lower S1 values compared with S2 (Table 1) indicate that the analyzed samples have not yet generated oil because of the low thermal maturation level.
The thermal maturity level of organic matter in the analyzed samples was determined from the biomarkers in the aliphatic hydrocarbon fraction, namely, the 22S/(22S + 22R) ratio of C32 homohopanes, the moretane to hopane (C30M/C30H) ratio, Ts/Tm, and the 20S/(20S+20R), and ββ/(ββ +αα) ratios of C29 sterane (Table 2).
The biomarker ratios of C32 hopane 22S/(22S+22R) and C29 sterane 20S/(20S+20R), and ββ/(ββ+αα) as well as Ts/Tm indicate maturity levels over the early mature range with increasing maturity (e.g. Seifert and Moldowan 1978, 1981, 1986; Roushdy et al. 2010; El Nady et al. 2014), whereas the low CM30/C30 values further indicate mature source rocks (Mackenzie et al. 1980).
The C32 20S/(20S+20R) ratio of more than 0.50 suggests material reaching oil window maturity (Seifert and Moldowan 1986). The C32 hopane ratio in the analyzed shale samples ranged from 0.49 to 0.50, indicating that the organic matter in these sediments is approaching the oil window maturity.
Some aliphatic parameters, namely, the ββ/(ββ + αα) and 20S/(20S + 20R) ratios of C29 sterane were also used as maturity indicators (Seifert and Moldowan 1978, 1981, 1986). The C29 20S/(20S+20R) and ββ/(ββ+αα) sterane ratios for three extracted rock samples were calculated have the low values in the ranges of 0.30–0.40 and 0.40–0.42, respectively (Table 2). Together with the C29 sterane ββ/(ββ +αα)) ratio, the C32 hopane ratio suggests immature organic matter in the analyzed shales (Fig. 13A). This immature stage is consistent with the values of Ts/Tm and CM30/C30 ratios (Fig. 13B). Consequently, immature stage implied by the biomarker ratios and low VRs (<0.50%) is incompatible with relatively high Tmax values (Table 1). The high Tmax values of the analyzed samples could be attributed to the interference in the muddy–silty rich mineral matrix (Espitalié et al. 1980; Peters 1986). This suggestion is supported by the significantly reduced amounts of pyrolytic effluents (S2) adsorbed by clay minerals in the analyzed shale samples (Espitalié et al. 1980; Peters 1986). Therefore, the Tmax data are probably inaccurate for assessing the thermal maturation of the analyzed samples.
Petroleum generation potential
The potential of petroleum generation is generally evaluated based on the organic facies of the kerogen dispersed in the source rock and their maturation level (e.g., Dow 1977; Peters and Cassa 1994; Abdullah et al. 2017). In the current study, geochemical results were integrated with the visual kerogen microscopy and used to discuss the characteristics of the kerogen of the analyzed Galhak shale samples and predict their potential as a petroleum resource in the northern Melut Basin, Sudan. The geochemical results of Rock-Eval pyrolysis, with HI values more than 400-mg HC/g TOC predict that the organic matter type of the Galhak shale samples under study is mainly types I and III kerogen (Fig. 5). The organic facies of high proportions of type I and II kerogens suggest primarily sapropel derived from algal organic matter as demonstrated by the organic biomarkers and kerogen microscopy results. These shale sediments of the Galhak Formation under study contain high proportions of type I and II kerogens that can generate notable amounts of oil. This conclusion can also be deduced from the chemical correlations between the TOC content and the S2/S3 and HI Rock-Eval parameters (Fig. 14). The potential for hydrocarbon generation of mainly oil from the Galhak shale also conforms from the microscopic kerogen assemblages plotted on a Tissot and Welte (1978) ternary diagram (Fig. 15).
Beside the organic facies of the kerogen, the petroleum generation potential was further assessed from the thermal alteration of organic matter in the analyzed Galhak shale samples. In agreement with previously obtained maturity data, these shale sediments from the studied well in the northern Melut Basin generally represent immature source rocks and have not yet reached oil-window maturity level. Accordingly, the Galhak source-rock containing types I and II kerogen in the deeper well locations in the Melut Basin may be sufficiently mature of peak oil-window and could lead to lucrative oil generation.
Conclusions
Organic geochemical and microscopic investigations were performed on organic-rich shales of the Late Cretaceous Galhak Formation. Samples were collected from one well in the northern Melut Basin, Sudan. The main conclusions are outlined below.
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1-
The TOC contents of the Galhak shales all exceeded 2%, indicating that the shales are favorable source rocks for prospecting.
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2-
The Galhak organic-rich shales contain high levels of aquatic-derived sapropel or sapropelite and were classified as hydrogen-rich types I and II kerogen, with HI values between 452 and 612 mg HC/g TOC. Thus, they can potentially generate commercial amounts of oil.
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3-
The biomarker distributions revealed that the Galhak oil-prone shales were deposited in a relatively fresh lacustrine environment under suboxic to relatively oxic conditions. High contributions of algal organic matter with few plant inputs were accumulated during the deposition.
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4-
The biomarkers and the optical and chemical maturity data further confirm immature organic matter in the Galhak shales. Oil has not yet been generated at the current shallow burial depth.
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5-
These conclusions enhance the prospects and exploration strategies for commercial oil generation and production along deep parts of the Melut Basin, where these organic-rich shales could reach a good maturity level.
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Acknowledgements
The authors would like to thank and appreciate the Ministry of Energy and Mining of Sudan for their helping and giving the data for this research. The authors also extend their sincere appreciation to the Deanship of Scientific Research at King Saud University for funding the work. The constructive comments by an Associate Editor Dr. Barry Katz and an anonymous reviewer that improved the original manuscript are gratefully acknowledged.
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Hakimi, M.H., Abas, A.N., Hadad, Y.T. et al. Bulk pyrolysis and biomarker fingerprints of Late Cretaceous Galhak Shale Formation in the northern Melut Basin, Sudan: implications on lacustrine oil-source rock. Arab J Geosci 14, 520 (2021). https://doi.org/10.1007/s12517-021-06740-0
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DOI: https://doi.org/10.1007/s12517-021-06740-0