Abstract
Bamboo cellulose (BC) is hydrophilic, biodegradable and inexhaustible. The bamboo cellulose membrane (BCM) is one of the best materials to replace petroleum-based polymer film for water purification. In this study, the N-methylmorpholine-N-oxide (NMMO) was used as a solvent to dissolve cellulose 6 wt.%, and regenerated cellulose membrane was prepared by phase inversion. A new kind of cellulose nanofiltration membrane (BC-NFM) was obtained by the hydrolysis and carboxymethylation of dense cellulose membrane (BCM). The modification was carried out through hydrolysis followed by carboxymethylation. The BC-NFM was characterized by XRD, FT-IR, SEM and thermal analysis. BC-NFM performance evaluation instrument were used to evaluate retention rate and water flux of nanofiltration membrane. BCM was immersed in 1 mol/l NaOH and 3 wt/v.% chloroacetic acid solution to obtain BC-NFM. By calculating, pore size of nanofiltration membrane was 0.63 nm. With a pressure of 0.5 MPa, the water flux of nanofiltration membrane for Na2SO4 solution was 10.32 l/m2h, and the retention rate was 68.4 %. The water flux for NaCl solution was 13.12 l/m2h, and the retention rate was 34.9 %. And the retention rates were 93.0 % and 98.9 % for methyl orange and methyl blue, respectively. The stability of the nanofiltration membrane was measured by the thermal analyzer, following the order of BC>BCM>BC-NFM. The prepared cellulose nanofiltration membrane exhibited good stability in water treatment process, and can be used to remove organic compounds in aqueous solutions.
Article PDF
Similar content being viewed by others
Explore related subjects
Discover the latest articles, news and stories from top researchers in related subjects.Avoid common mistakes on your manuscript.
References
N. Hilal, H. Al-Zoubi, N. A. Darwish, A. W. Mohammad, and M. Abu Arabi, Desalination, 170, 281 (2004).
J. Su, Q. Yang, J. F. Teo, and T. S. Chung, J. Membr. Sci., 355, 36 (2010).
Z. Thong, Y. Cui, Y. K. Ong, and T. S. Chung, ACS Sustain. Chem. Eng., 4, 5570 (2016).
Y. He, Y. P. Tang, and T. S. Chung, Ind. Eng. Chem. Res., 55, 12929 (2016).
Y. Zhang, S. Zhang, J. Gao, and T. S. Chung, J. Membr. Sci., 515, 230 (2016).
N. Bolong, A. F. Ismail, M. R. Salim, D. Rana, T. Matsuura, and A. Tabe-Mohammadi, Sep. Purif. Technol., 73, 92 (2010).
T. Goma Bilongo, J. C. Remigy, and M. J. Clifton, J. Membr. Sci., 364, 304 (2010).
D. Wang, K. Li, and W. K. Teo, J. Membr. Sci., 162, 211 (1999).
S. M. Dutczak, M. W. J. Luiten-Olieman, H. J. Zwijnenberg, L. A. M. Bolhuis-Versteeg, L. Winnubst, M. A. Hempenius, N. E. Benes, M. Wessling, and D. Stamatialis, J. Membr. Sci., 372, 182 (2011).
A. Pinkert, K. N. Marsh, S. Pang, and M. P. Staiger, Chem. Rev., 109, 6712 (2009).
S. Zhu, Y. Wu, Q. Chen, Z. Yu, C. Wang, S. Jin, Y. Ding, and G. Wu, Green Chem., 8, 325 (2006).
T. Heinze and T. Liebert, Progr. Polym. Sci., 26, 1689 (2001).
T. Nishino, I. Matsuda, and K. Hirao, Macromolecules, 37, 7683 (2004).
S. L. Williamson, R. S. Armentrout, R. S. Porter, and C. L. McCormick, Macromolecules, 31, 8134 (1998).
K. J. Edgar, K. M. Arnold, W. W. Blount, J. E. Lawniczak, and D. W. Lowman, Macromolecules, 28, 4122 (1995).
J. F. Masson and R. S. John Manley, Macromolecules, 24, 5914 (1991).
J. F. Masson and R. S. John Manley, Macromolecules, 24, 6670 (1991).
K. Hattori, J. A. Cuculo, and S. M. Hudson, J. Polym. Sci., Part A: Polym. Chem., 40, 601 (2002).
H. P. Fink, P. Weigel, H. J. Purz, and A. Bohn, Recent Res. Devel In Polym. Sci., 2, 387 (1998).
M. J. Earle and K. R. Seddon, Pure Appl. Chem., 72, 1391 (2000).
S. C. Yu, Q. B. Cheng, C. M. Huang, J. Liu, X. Y. Peng, M. H. Liu, and C. J. Gao, J. Membr. Sci., 434, 44 (2013).
C. M. Shih, Y. T. Shieh, and Y. K. Twu, Carbohydr. Polym., 78, 169 (2009).
Y. Z. Xu and R. E. Lebrun, Desalination, 122, 95 (1999).
X. L. Li, L. P. Zhu, B. K. Zhu, and Y. Y. Xu, Separation and Purification Technology, 83, 66 (2011).
M. Dalwani, N. E. Benes, G. Bargeman, D. Stamatialis, and M. Wessling, J. Membr. Sci., 363, 188 (2010).
Q. Yang, T. S. Chung, and Y. E. Santoso, J. Membr. Sci., 290, 153 (2007).
S. Lin, L. H. Chen, L. L. Huang, S. L. Cao, X. L. Luo, K. Liu, and Z. H. Huang, Bioresources, 7, 5488 (2012).
H. Zhao, J. H. Kwak, Y. Wang, J. A. Franz, J. M. White, and J. E. Holladay, Energy Fuels, 20, 807 (2006).
S. K. Mahadeva and J. Kim, J. Phys. Chem. C., 113, 12523 (2009).
G. Arthanareeswaran, P. Thanikaivelan, K. Srinivasn, and M. Rajendran, Eur. Polym. J., 40, 2153 (2004).
B. K. Barai, R. S. Singhal, and P. R. Kulkarni, Carbohydr. Polym., 32, 229 (1997).
B. Vander Bruggen, J. Schaep, D. Wilms, and C. Vandecasteele, J. Membr. Sci., 156, 29 (1999).
K. Y. Wang and T. S. Chung, J. Membr. Sci., 247, 37 (2005).
C. G. Arlindo and C. G. Isolina, J. Membr. Sci., 255, 157 (2005).
Y. C. Chung, N. D. Khiem, J. W. Choi, and B. C. Chun, Fiber. Polym., 16, 492 (2015).
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
Weng, R., Chen, L., Xiao, H. et al. Preparation and characterization of cellulose nanofiltration membrane through hydrolysis followed by carboxymethylation. Fibers Polym 18, 1235–1242 (2017). https://doi.org/10.1007/s12221-017-7200-1
Received:
Revised:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s12221-017-7200-1