Abstract
The hydrogenation of biomass-based furan compounds is an important step for the catalytic valorization of biobased chemicals. In this work, Ru-based catalysts supported on different supports, such as HY, MgO and Amberlyst-15, were prepared and estimated for the hydrogenation of dimethyl 2,5-furandicarboxylate (FDMC). Among them, Ru/HY provided a desirable yield of 99.4% for tetrahydrofuran-2,5-dicarboxylic acid dimethyl ester (THFDMC) under 90 °C and 3 MPa H2. Based on catalyst characterization, Ru/HY could offer more surface Ru0 species and carbon radical intermediates than other catalysts, which could largely favor the activation of hydrogen and then promote the hydrogenation of FDMC over Ru/HY.
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Acknowledgements
We are grateful for the funding supported by the National Natural Science Foundation of China (Grant nos. U22A20421; 22078275), the Fundamental Research Funds for the Central Universities (Grant no. 20720220065).
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Li, C., Lyu, Q., Li, Z. et al. Hydrogenation of dimethyl 2,5-furandicarboxylate to dimethyl tetrahydrofuran-2,5-dicarboxylate over Ru/HY. Korean J. Chem. Eng. 40, 2149–2158 (2023). https://doi.org/10.1007/s11814-023-1463-6
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DOI: https://doi.org/10.1007/s11814-023-1463-6