Abstract
Phenolic resins were employed to prepare electrospun porous carbon nanofibers with a high specific surface area as free-standing electrodes for high-performance supercapacitors. However, the sustainable development of conventional phenolic resin has been challenged by petroleum-based phenol and formaldehyde. Lignin with abundant phenolic hydroxyl groups is the main non-petroleum resource that can provide renewable aromatic compounds. Hence, lignin, phenol, and furfural were used to synthesize bio-based phenolic resins, and the activated carbon nanofibers were obtained by electrospinning and one-step carbonization activation. Fourier transform infrared and differential scanning calorimetry were used to characterize the structural and thermal properties. The results reveal that the apparent activation energy of the curing reaction is 89.21 kJ·mol−1 and the reaction order is 0.78. The activated carbon nanofibers show a uniform diameter, specific surface area up to 1100 m2·g−1, and total pore volume of 0.62 cm3·g−1. The electrode demonstrates a specific capacitance of 238 F·g−1 (0.1 A·g−1) and good rate capability. The symmetric supercapacitor yields a high energy density of 26.39 W·h·kg−1 at 100 W·kg−1 and an excellent capacitance retention of 98% after 10000 cycles. These results confirm that the activated carbon nanofiber from bio-based phenolic resins can be applied as electrode material for high-performance supercapacitors.
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References
Li Z, Gadipelli S, Yang Y, He G, Guo J, Li J, Lu Y, Howard C A, Brett D J L, Parkin I P, Li F, Guo Z. Exceptional supercapacitor performance from optimized oxidation of graphene-oxide. Energy Storage Materials, 2019, 17: 12–21
Li Y, Huang J, Kang L, Tian Z, Lai F, Brett D J L, Liu T, He G. Self-assembled carbon nanoribbons with the heteroatom doping used as ultrafast charging cathodes in zinc-ion hybrid supercapacitors. Science China Materials, 2022, 65(6): 1495–1502
Sui D, Chang M, Wang H, Qian H, Yang Y, Li S, Zhang Y, Song Y. A brief review of catalytic cathode materials for Na-CO2 batteries. Catalysts, 2021, 11(5): 603–605
Zhang W, Yuan X, Yan X, You M, Jiang H, Miao J, Zhou W, Zhu Y, Cheng X. Tripotassium citrate monohydrate derived carbon nanosheets as a competent assistant to manganese dioxide with remarkable performance in the supercapacitor. Frontiers of Chemical Science and Engineering, 2022, 16(3): 420–432
Lei C, Amini N, Markoulidis F, Wilson P, Tennison S, Lekakou C. Activated carbon from phenolic resin with controlled mesoporosity for an electric double-layer capacitor (EDLC). Journal of Materials Chemistry A: Materials for Energy and Sustainability, 2013, 1(19): 6037–6042
Ji H K, Ko Y I, Kim Y A, Kim K S, Yang C M. Sulfur-doped carbon nanotubes as a conducting agent in supercapacitor electrodes. Journal of Alloys and Compounds, 2021, 855: 157282
Li Z F, Zhang H, Liu Q, Sun L, Xie J. Fabrication of high-surface-area graphene/polyaniline nanocomposites and their application in supercapacitors. ACS Applied Materials & Interfaces, 2013, 5(7): 2685–2691
Ma C, Song Y, Shi J, Zhang D, Zhong M, Guo Q, Liu L. Phenolic-based carbon nanofiber webs prepared by electrospinning for supercapacitors. Materials Letters, 2012, 76: 211–214
Jain A, Tripathi S K. Fabrication and characterization of energy storing supercapacitor devices using coconut shell based activated charcoal electrode. Materials Science and Engineering B, 2014, 183: 54–60
Zheng Z, Gao Q. Hierarchical porous carbons prepared by an easy one-step carbonization and activation of phenol–formaldehyde resins with high performance for supercapacitors. Journal of Power Sources, 2011, 196(3): 1615–1619
Du B, Zhu H, Chai L, Cheng J, Wang X, Chen X, Zhou J, Sun R. Effect of lignin structure in different biomass resources on the performance of lignin-based carbon nanofibers as supercapacitor electrode. Industrial Crops and Products, 2021, 170: 113745
Chen W, Wang H, Lan W, Li D, Zhang A, Liu C. Construction of sugarcane bagasse-derived porous and flexible carbon nanofibers by electrospinning for supercapacitors. Industrial Crops and Products, 2021, 170: 113700
Si L, Yan K, Li C, Huang Y, Pang X, Yang X, Sui D, Zhang Y, Wang J, Charles Xu C. Binder-free SiO2 nanotubes/carbon nanofibers mat as superior anode for lithium-ion batteries. Electrochimica Acta, 2022, 404: 139747
Zhang Y, Ferdosian F, Yuan Z, Xu C. Sustainable glucose-based phenolic resin and its curing with a DGEBA epoxy resin. Journal of the Taiwan Institute of Chemical Engineers, 2017, 71: 381–387
Xi Y, Yang D, Qiu X, Wang H, Huang J, Li Q. Renewable lignin-based carbon with a remarkable electrochemical performance from potassium compound activation. Industrial Crops and Products, 2018, 124: 747–754
Cheng S, Yuan Z, Leitch M, Anderson M, Xu C. Highly efficient de-polymerization of organosolv lignin using a catalytic hydrothermal process and production of phenolic resins/adhesives with the depolymerized lignin as a substitute for phenol at a high substitution ratio. Industrial Crops and Products, 2013, 44: 315–322
Mahmood N, Xu C, Zhang Y, Huang S, Yuan Z. Sustainable biophenol-hydroxymethylfurfural resins using phenolated depolymerized hydrolysis lignin and their application in biocomposites. Industrial Crops and Products, 2016, 79: 84–90
Minami E, Kawamoto H, Saka S. Reaction behavior of lignin in supercritical methanol as studied with lignin model compounds. Journal of Wood Science, 2003, 49(2): 158–165
Lee Y K, Kim D J, Kim H J, Hwang T S, Sokolov J. Activation energy and curing behavior of resol- and novolac-type phenolic resins by differential scanning calorimetry and thermogravimetric analysis. Journal of Applied Polymer Science, 2010, 89(10): 2589–2596
Zhang Y, Yuan Z, Xu C. Engineering biomass into formaldehyde-free phenolic resin for composite materials. AIChE Journal, 2015, 61(4): 1275–1283
Xu W B, Bao S P, Shen S J, Hang G P, He P S. Curing kinetics of epoxy resin-imidazole-organic montmorillonite nanocomposites determined by differential scanning calorimetry. Journal of Applied Polymer Science, 2010, 88(13): 2932–2941
Wang M, Leitch C. Synthesis of phenol-formaldehyde resol resins using organosolv pine lignins. European Polymer Journal, 2009, 45(12): 3380–3388
Khan M A, Ashraf S M, Malhotra V P. Eucalyptus bark lignin substituted phenol formaldehyde adhesives: a study on optimization of reaction parameters and characterization. Journal of Applied Polymer Science, 2004, 92(6): 3514–3523
Cheng S, D’Cruz I, Yuan Z, Wang M, Anderson M, Leitch M, Xu C C. D′Cruz I, Yuan Z, Wang M, Anderson M, Leitch M, Xu C. Use of biocrude derived from woody biomass to substitute phenol at a high-substitution level for the production of biobased phenolic resol resins. Journal of Applied Polymer Science, 2011, 121(5): 2743–2751
Zhuang Q Q, Cao J P, Zhao X Y, Wu Y, Wei X Y. Preparation of layered-porous carbon from coal tar pitch narrow fractions by single-solvent extraction for superior cycling stability electric double layer capacitor application. Journal of Colloid and Interface Science, 2020, 567: 347–356
Sui D, Xu L, Zhang H, Sun Z, Kan B, Ma Y, Chen Y. A 3D cross-linked graphene-based honeycomb carbon composite withexcellent confinement effect of organic cathode material for lithium-ion batteries. Carbon, 2020, 157: 656–662
Sui D, Wu M, Shi K, Li C, Lang J, Yang Y, Zhang X, Yan X, Chen Y. Recent progress of cathode materials for aqueous zincion capacitors: carbon-based materials and beyond. Carbon, 2021, 185: 126–151
Wu F, Gao J, Zhai X, Xie M, Sun Y, Kang H, Tian Q, Qiu H. Hierarchical porous carbon microrods derived from albizia flowers for high performance supercapacitors. Carbon, 2019, 147: 242–251
Wu Y, Cao J P, Zhao X Y, Hao Z Q, Zhuang Q Q, Zhu J S, Wang X Y, Wei X Y. Preparation of porous carbons by hydrothermal carbonization and KOH activation of lignite and their performance for electric double layer capacitor. Electrochimica Acta, 2017, 252: 397–407
Dandan G, Jin Q, Ranran X, Zhen Z, Wei J. Facile synthesis of nitrogen-enriched nanoporous carbon materials for high performance supercapacitors. Journal of Colloid and Interface Science, 2019, 538: 199–208
Wang J G, Yang Y, Huang Z H, Kang F. A high-performance asymmetric supercapacitor based on carbon and carbon-MnO2 nanofiber electrodes. Carbon, 2013, 61: 190–199
Yang X, Zeng X, Han G, Sui D, Zhang Y. Preparation and performance of porous carbon nanocomposite from renewable phenolic resin and halloysite nanotube. Nanomaterials, 2020, 10(9): 1703
Hao Z Q, Cao J, Dang Y L, Wu Y, Zhao X Y, Wei X Y. Three-dimensional hierarchical porous carbon with high oxygen content derived from organic waste liquid with superior electric double layer performance. ACS Sustainable Chemistry & Engineering, 2019, 7(4): 4037–4046
Guan T, Li K, Zhao J, Zhao R, Zhang G, Zhang D, Wang J. Template-free preparation of layer-stacked hierarchical porous carbons from coal tar pitch for high performance all-solid-state supercapacitors. Journal of Materials Chemistry A: Materials for Energy and Sustainability, 2017, 5(30): 15869–15878
He X, Zhao N, Qiu J, Xiao N, Yu M, Yu C, Zhang X, Zheng M. Synthesis of hierarchical porous carbons for supercapacitors from coal tar pitch with nano-Fe2O3 as template and activation agent coupled with KOH activation. Journal of Materials Chemistry A: Materials for Energy and Sustainability, 2013, 1(33): 9440–9448
Wang W, Lv H, Du J, Chen A. Fabrication of N-doped carbon nanobelts from a polypyrrole tube by confined pyrolysis for supercapacitors. Frontiers of Chemical Science and Engineering, 2021, 15(5): 1312–1321
Zhang D, He C, Wang Y, Zhao J, Wang J, Li K. Oxygen-rich hierarchically porous carbons derived from pitch-based oxidized spheres for boosting the supercapacitive performance. Journal of Colloid and Interface Science, 2019, 540: 439–447
Yan J, Liu J, Fan Z, Wei T, Zhang L. High-performance supercapacitor electrodes based on highly corrugated graphene sheets. Carbon, 2012, 50(6): 2179–2188
Li Y, Wang G, Wei T, Fan Z, Yan P. Nitrogen and sulfur codoped porous carbon nanosheets derived from willow catkin for supercapacitors. Nano Energy, 2016, 19: 165–175
Wang Y, Cui J, Qu Q, Ma W, Li F, Du W, Liu K, Zhang Q, He S, Huang C. Free-standing porous carbon nanofiber membranes obtained by one-step carbonization and activation for high-performance supercapacitors. Microporous and Mesoporous Materials, 2022, 329: 111545
Ma H, Chen Z, Wang X, Liu Z, Liu X. A simple route for hierarchically porous carbon derived from corn straw for supercapacitor application. Journal of Renewable and Sustainable Energy, 2019, 11(2): 024102
Lai C C, Lo C T. Preparation of nanostructural carbon nanofibers and their electrochemical performance for supercapacitors. Electrochimica Acta, 2015, 183: 85–93
Liu Y, Zhou J, Lu C. Highly flexible freestanding porous carbon nanofibers for electrodes materials of high-performance all-carbon supercapacitors. ACS Applied Materials & Interfaces, 2015, 7(42): 23515–23520
Dong Q, Wang G, Hu H, Yang J, Qian B, Ling Z, Qiu J. Ultrasound-assisted preparation of electrospun carbon nanofiber/graphene composite electrode for supercapacitors. Journal of Power Sources, 2013, 243: 350–353
Chen L F, Zhang X D, Liang H W, Kong M, Guan Q F, Chen P, Wu Z Y, Yu S H. Synthesis of nitrogen-doped porous carbon nanofibers as an efficient electrode material for supercapacitors. ACS Nano, 2012, 6(8): 7092–7102
Kim C, Btn N, Yang K S, Kojima M, Kim Y A, Kim Y J, Endo M, Yang S C. Self-sustained thin webs consisting of porous carbon nanofibers for supercapacitors via the electrospinning of polyacrylonitrile solutions containing zinc chloride. Advanced Materials, 2010, 19(17): 2341–2346
Acknowledgements
This work was supported by the National Natural Science Foundation of China (Grant Nos. 21908204, 52074244) and the Henan Provincial Key Research and Development Program (Grant No. 192102310202). The authors would also like to acknowledge the support from Zhengzhou University.
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Electrospun porous carbon nanofibers derived from bio-based phenolic resins as free-standing electrodes for high-performance supercapacitors
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Zhang, Y., Yang, X., Bao, J. et al. Electrospun porous carbon nanofibers derived from bio-based phenolic resins as free-standing electrodes for high-performance supercapacitors. Front. Chem. Sci. Eng. 17, 504–515 (2023). https://doi.org/10.1007/s11705-022-2260-1
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DOI: https://doi.org/10.1007/s11705-022-2260-1