Abstract
The current work describes the synthesis of a new bio-waste derived cellulosic-carbon supported-palladium nanoparticles enriched magnetic nanocatalyst (Pd/Fe3O4@C) using a simple multi-step process under aerobic conditions. Under mild reaction conditions, the Pd/Fe3O4@C magnetic nanocatalyst demonstrated excellent catalytic activity in the Hiyama cross-coupling reaction for a variety of substrates. Also, the Pd/Fe3O4@C magnetic nanocatalyst exhibited excellent catalytic activity up to five recycles without significant catalytic activity loss in the Hiyama cross-coupling reaction. Also, we explored the use of Pd/Fe3O4@C magnetic nanocatalyst as an electrocatalyst for hydrogen evolution reaction. Interestingly, the Pd/Fe3O4@C magnetic nanocatalyst exhibited better electrochemical activity compared to bare carbon and magnetite (Fe3O4 nanoparticles) with an overpotential of 293 mV at a current density of 10 mA·cm−2.
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The authors thank DST-SERB, India (YSS/2015/000010), DST-Nanomission, India (SR/NM/NS-20/2014), and Jain University, India for financial support.
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Pd/Fe3O4 supported on bio-waste derived cellulosic-carbon as a nanocatalyst for C-C coupling and electrocatalytic application
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Kandathil, V., Moolakkil, A., Kulkarni, P. et al. Pd/Fe3O4 supported on bio-waste derived cellulosic-carbon as a nanocatalyst for C-C coupling and electrocatalytic application. Front. Chem. Sci. Eng. 16, 1514–1525 (2022). https://doi.org/10.1007/s11705-022-2158-y
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DOI: https://doi.org/10.1007/s11705-022-2158-y