Abstract
The inclusion of metamorphic buffer layers (MBLs) in the design of lattice-mismatched semiconductor heterostructures is important in enhancing reliability and performance of optoelectronic and electronic devices through proper control of threading dislocations; threading dislocation can be reduced by allowing the distribution of the misfit dislocations throughout the MBL, rather than concentrating them at the interface where substrate defects and tangling can pin dislocations or otherwise reduce their mobility. Compositionally graded layers have been particularly used for this purpose and in this work we considered heterostructures involving a step-graded In x Ga1−x As or In x Al1−x As epitaxial layer on a GaAs (001) substrate. For each structure type, we present minimum energy calculations including (i) the surface and (ii) average in-plane strain and (iii) the misfit dislocation density profile with various grading coefficients (thickness and indium composition variation). In both types of structures, the average in-plane strain and misfit dislocation density profile scale with the average grading coefficient, but In x Al1−x As structures with a greater average elastic stiffness constants exhibit slightly higher average compressive in-plane strain (absolute valued) which is associated with higher misfit dislocation densities. However, the rate of change in the normalized relaxation percentage per unit thickness of each step with respect to the lattice mismatch of the step is lower in the In x Al1−x As material system. The difference of the in-plane strain is small (<3%), however, so that these material systems are virtually interchangeable in terms of their mechanical behavior (<5.1% change in elastic constants).
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Kujofsa, T., Ayers, J.E. Equilibrium Lattice Relaxation and Misfit Dislocations in Step-Graded In x Ga1−x As/GaAs (001) and In x Al1−x As/GaAs (001) Metamorphic Buffer Layers. J. Electron. Mater. 45, 2831–2836 (2016). https://doi.org/10.1007/s11664-016-4377-9
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DOI: https://doi.org/10.1007/s11664-016-4377-9