Abstract
A novel fiber optic sensor based on optical composite oxygen-sensitive film was developed for determination of 2,4-dichlorophenol (DCP). The optical composite oxygen-sensitive film consists of tris(2,2′-bipyridyl) dichloro ruthenium(II) hexahydrate (Ru(bpy)3Cl2) as the fluorescence indicator and iron(III) tetrasulfophthalocyanine (Fe(III)PcTs) as bionic enzyme. A lock-in amplifier was used for detecting the lifetime of the composite oxygen-sensitive film by measuring the phase delay of the sensor head. The different variables affecting the sensor performance were evaluated and optimized. Under the optimal conditions (i e, pH 6.0, 25 °C, Fe(III)PcTs concentration of 5.0·10−5 mol/L), the linear detection range, detection limit and response time of the fiber optic sensor are 3.0×10−7–9.0×10−5 mol/L, 4.8×10−8 mol/L(S/N=3), and 220 s, respectively. The sensor displays high selectivity, good repeatability and stability, which have good potentials in analyzing DCP concentration in practical water samples.
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Agboola B, Ozoemena KI, Nyokong T. Hydrogen Peroxide Oxidation of 2-Chlorophenol and 2,4,5-trichlorophenol Catalyzed by Monomeric and Aggregated Cobalt Tetrasulfophthalocyanine[J]. J. Mol. Catal. A: Chem., 2005, 227(1–2): 209–216
Iliev V, Mihaylova A, Bilyarska L. Photooxidation of Phenols in Aqueous Solution, Catalyzed by Mononuclear and Polynuclear Metal Phthalocyanine Complexis[J]. J. Mol. Catal. A: Chem., 2002, 184: 121–130
Li DP, Tong YL, Huang J, et al. First Observation of Tetranitro Iron(II) Phthalocyanine Catalyzed Oxidation of Phenolic Pollutant Assisted with 4-Aminoantipyrine using Dioxygen as Oxidant[J]. J. Mol. Catal. A: Chem., 2011, 345: 108–116
Mckinley R, Plant JA, Bell JNB, et al. Endocrine Disrupting Pesticides: Implications for Risk Assessment[J]. Environment International, 2008, 34(4): 168–172
Mehmood Z, Kelly DE, Kelley SL. Cytochrome P450 3A4 Mediated Metabolism of 2,4-Dichlorophenol[J]. Chemosphere, 1997, 31(18): 2 281–2 291
Niu JF, Xu JJ, Dai YR, et al. Immobilization of Horseradish Peroxidase by Electrospun Fibrous films for Adsorption and Degradation of Pentachlorophenol in Water[J]. J. Hazard. Mater., 2013, 246: 119–125
Wu L, Li A, Gao GD, et al. Efficient Photodegradation of 2,4-Dichlorophenolin Aqueous Solution Catalyzed by Polydivinylbenzene-supported Zinc Phthalocyanine[J]. J. Mol. Catal. A: Chem., 2007, 269: 183–189
Agboola B, Ozoemena KI, Nyokong T. Comparative Efficiency of Immobilized Non-transition Metal Phthalocynine Photosensitizers for the Visible Light Transformation of Chlorophenols[J]. J. Mol. Catal. A: Chem., 2006, 248: 84–92
Peng JF, Liu JF, Hu XL. Direct Determination of Chlorophenols in Environmental Water Samples by Hollow Fiber Supported Ionic Liquid film Extraction Coupled with High-performance Liquid Chromatography[J]. J. Chromatogr. A., 2007, 1139: 165–170
Gurka DF, Pyle S, Titus R. Environmental Applications of Gas Chromatography/Atomic Emission Detection[J]. Anal. Chem., 1997, 69(21): 2 411–2 415
Campillo N, Aguinaga N, Viñas P, et al. Capillary Gas Chromatography with Atomic Emission Detection for Determining Chlorophenols in Water and Soil Samples[J]. Anal. Chim. Acta., 2005, 552: 182–189
Alberici RM, Sparrapan R, Jardim WF, et al. Selective Trace Lever Analysis of Phenolic Compounds in Water by Flow Injection Analysis — film Introduction Mass Spectrometry[J]. Environ. Sci. Technol., 2001, 35(8): 2 084–2 088
Santana CM, Padrón MET, Ferrera ZS, et al. Development of a Solid-phase Microextraction Method with Micellar Desorption for the Determination of Chlorophenols in Water Samples-comparison with Conventional Solid-phase Microextraction method[J]. J. Chromatogr. A, 2007, 1140: 13–20
Wang J, Chen G, Chatrathi MP, et al. Capillary Electrophoresis Microchip with a Carbon Nanotube-modified Electrochemical Detector[J]. Anal. Chem., 2004, 76: 298–302
Muna GW, Quaiserová-Mocko V, Swain GM. Chlorinated Phenol Analysis Using Off-line Solid-phase Extraction and Capillary Electrophoresis Coupled with Amperometric Detection and a Boron-doped Diamond Microelectrode[J]. Anal.Chem., 2005, 77(21): 6 542–6 548
Ozkan D, Kerman K, Meric B, et al. Heterostructured Fluorohectorite Clay as an Electrochemical Sensor for the Detection of 2,4-dichlorophenol and the Herbicide 2,4-Dichlorophenolin[J]. Chem. Mater., 2002, 14(8): 1 755–1 761
Hendricks NR, Waryo TT, Arotiba O, et al. Microsomal Cytochrome P450-3A4 (CYP3A4) Nanobiosensor for the Determination of 2,4-Dichlorophenol-An Endocrine Disruptor Compound[J]. Electrochim. Acta., 2009, 54(5): 1 925–1 931
Jantra J, Zilouei H, Liu J, et al. Microbial Biosensor for the Analysis of 2,4-Dichlorophenol[J]. Anal. Lett., 2005, 38(7): 1 071–1 083
Figmegos YC, Stalikas CD, Karayannis MI, et al. Synthesis and Analytical Application of 4-Aminopyrazolone Derivatives as Chromogenic Agents for the Spectrophotometric Determination of Phenols[J]. Anal. Chim. Acta., 2000, 403: 315–323
Doong RA, Tsai HC. Immobilization and Characterization of Sol-Gel-encapsulated Acetylcholinesterase Fiber-optic Biosensor[J]. Anal Chim. Acta., 2001, 434: 239–246
Singh S, Mishra SK, Gupta BD. SPR Based Fibre Optic Biosensor for Phenolic Compounds Using Immobilization of Tyrosinase in Polyacrylamide Gel[J]. SensorActuat B-Chem., 2013, 186: 388–396
Tong YL, Li DP, Huang J. A Fiber Optic Sensor for Determination of 2,4-Dichlorophenol Based on Oxygen Oxidation Catalyzed by Iron(III) Tetrasulfophthalocyanine[J]. Bull. Korean Chem. Soc., 2013, 34(11): 3 307–3 311
Ali H, Langlois R, Wagner JR, et al. Biological Activities of Phthalocyanines—X. Syntheses and Analyses of Sulfonated phthalocyanines[J]. Photochem. Photobiol., 1988, 47(8): 713–717
Huang J, Wang HL, Li DP, et al. A New Immobilized Glucose Oxidase Using SiO2 Nanoparticles as Carrier[J]. Mater. Sci. Eng. C, 2011, 31(5): 1 374–1 378
Huang J, Fang H, Liu C, et al. A Novel Fiber Optic Biosensor for the Determination of Adrenaline based on Immobilized Laccase Catalysis[J]. Anal. Lett., 2008, 41: 1 430–1 442
Bazzan G, Deneault JR, Kang TS, et al. Nanoparticle/dye Interface Optimization in Dye-sensitized Solar Cells[J]. Advanced Functional Materials, 2011, 21(17): 3 268–3 274
Wang YH, Tong YL, Huang J, et al. A Fiber Optic Sensor for Determination of 2,4-Dichlorophenol Based on Iron(II) Phthalocyanine Catalysis[J]. J. of Wuhan Uni. of Tech.-Mater. Sci. Ed., 2015, 30(6): 1 317–1 320
Agboola B, Ozoemena KI, Nyokong T. Hydrogen Peroxide Oxidation of 2-Chlorophenol and 2,4,5-Trichlorophenol Catalyzed by Monomeric and Aggregated Cobalt Tetrasulfophthalocyanine[J]. J. Mol. Catal. A: Chem., 2005, 227: 209–216
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Funded by the National Natural Science Foundation of China (No. 61205062), and the Scientific Research Foundation for Doctor of University (No. 2019Y02)
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Tong, Y., Zeng, Z., Yu, K. et al. A Fiber Optic Sensor for 2,4-dichlorophenol Analysis based on Optical Composite Oxygen-sensitive Film. J. Wuhan Univ. Technol.-Mat. Sci. Edit. 35, 743–749 (2020). https://doi.org/10.1007/s11595-020-2316-3
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DOI: https://doi.org/10.1007/s11595-020-2316-3