Abstract
Using the condensation of acetophenone under the action of triethyl orthoformate as an example, the effect of ratios of solvents (CH(OEt)3 and toluene) and the starting re-actants on the composition and yields of aromatic products was studied. After treatment of reaction mixtures with ammonia, 1,3,5-triphenylbenzene, m-terphenyl, and 2,6-diphen-ylpyridine were isolated.
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This work was performed under financial support of the Russian Foundation for Basic Research (Project No. 20-03-00087). The NMR studies were carried out under financial support of Ministry of Science and Higher Education of the Russian Federation with the use of the equipment of the Center for molecule composition studies of INEOS RAS.
No human or animal subjects were used in this research.
The authors declare no competing interests.
Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, Vol. 72, No. 5, pp. 1186–1191, May, 2023.
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Kovaleva, M.A., Kovalev, A.I. & Khotina, I.A. Alternative pathways of the reaction between acetophenone and triethyl orthoformate. Russ Chem Bull 72, 1186–1191 (2023). https://doi.org/10.1007/s11172-023-3888-9
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DOI: https://doi.org/10.1007/s11172-023-3888-9