Abstract
Chemical modification of cellulose in solutions of methanesulfonic acid (MSA) is studied. It was found using IR spectroscopy, capillary electrophoresis, and scanning electron microscopy that by treatment of cellulose in 10 and 15 M methanesulfonic acid solutions, cellulose is hydrolyzed to form soluble forms of cellulose (cellobiose) and insoluble products (microcrystalline cellulose and nanocellulose). It was also shown by IR, UV, and Raman spectroscopy that the interaction of OH groups of the studied carbohydrate molecules with MSA leads to the formation of mesylates esters.
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The research was performed using equipment of the Centers for Collective Use of the Dagestan Federal Research Center of Russian Academy of Sciences (DFRC RAS) and the Dagestan State University.
The authors express their special gratitude to A. Sh. Asvarov (the senior researcher of the Institute of Physics of the DFRC RAS) for the analysis of the initial and obtained substances by the method of scanning electron microscopy.
Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 2, pp. 412–419, February, 2021.
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Akhmedov, M.A., Khidirov, S.S. & Khibiev, K.S. Modification of cellulose in the solution of methanesulfonic acid. Russ Chem Bull 70, 412–419 (2021). https://doi.org/10.1007/s11172-021-3101-y
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DOI: https://doi.org/10.1007/s11172-021-3101-y