Abstract
The sorption of the actinium(iii) ions as 225,228Ac isotopes on hydroxyapatite (HAP) with various textures was studied. A “reverse” generator using an extraction chromatographic sorbent based on diglycolamide derivative (DGA Resin) was proposed for 228Ac production. The chemical yield of the product was ≥90%. The optimal acidity of the solution during sorption (pH 6–7) and the ratio of solid and liquid phases (20 mg of the sorbent per mL of the solution) were determined in preliminary experiments. The process kinetics is adequately described by pseudo-second-order model. The stationary state is reached rapidly (in 10 min) when a HAP suspension is used, whereas time (20–30 min) is needed for textured samples. The possibility of actinium ion diffusion within the bulk of these samples is shown. The diffusion coefficient of actinium estimated by diffusion in a wet HAP paste layer (one-dimensional model) was (1.0±0.2) • 10−7 cm2 s−1.
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This work was fi nancially supported by the Russian Foundation for Basic Research (Project No. 18-03-00432) and performed using research equipment of the Center for Collective Use of the Institute for Nuclear Research, Russian Academy of Sciences (contract with the Ministry of Education and Science No. 14.621.21.0014, unique identifi er RFMEF162117X0014).
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Severin, A.V., Vasiliev, A.N., Gopin, A.V. et al. Sorption and diffusion behavior of actinium(iii) ions in contact with hydroxyapatite as a transporter of medical radionuclides. Russ Chem Bull 69, 2286–2293 (2020). https://doi.org/10.1007/s11172-020-3041-y
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DOI: https://doi.org/10.1007/s11172-020-3041-y