Abstract
Nickel catalysts with diazabutadiene ligands promote cross-coupling of benzaldehydes with aryl halides in the presence of zinc as reducing agent, which leads to the corresponding benzhydrols and benzophenones. The benzophenone percentage considerably increases when lithium chloride additive is used.
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Dedicated to Academician of the Russian Academy of Sciences N. S. Zefirov on the occasion of his 80th birthday.
Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 2, pp. 0456—0463, February, 2016.
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Asachenko, A.F., Valaeva, V.N., Kudakina, V.A. et al. Coupling of aromatic aldehydes with aryl halides in the presence of nickel catalysts with diazabutadiene ligands. Russ Chem Bull 65, 456–463 (2016). https://doi.org/10.1007/s11172-016-1321-3
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DOI: https://doi.org/10.1007/s11172-016-1321-3