Abstract
A spacer-armed pentasaccharide structurally related to a fragment of the mannan from the cell wall of the fungus Candida albicans and corresponding to the antigenic factor 6 has been synthesized. This compound, comprising two α-(1→2)- and three β-(1→2)-linked mannose residues, was prepared by glycosylation of a selectively protected α-(1→2)-dimannoside bearing an aglycone spacer and a free OH group at atom C(2´) with a β-(1→2)-trimannoside glycosyl donor. The successful synthesis evidences that large β-(1→2)-oligomannoside donor blocks can be used for the preparation of oligosaccharides including extended sequences of repeating β-(1→2)-linked mannose residues.
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Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 12, pp. 2942—2948, December, 2015.
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Karelin, A.A., Tsvetkov, Y.E., Paulovičová, E. et al. Blockwise synthesis of a pentasaccharide structurally related to the mannan fragment from the Candida albicans cell wall corresponding to the antigenic factor 6. Russ Chem Bull 64, 2942–2948 (2015). https://doi.org/10.1007/s11172-015-1251-5
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DOI: https://doi.org/10.1007/s11172-015-1251-5