Abstract
A reaction of perfluoroalkyltrimethylsilanes with 3, 6-di(tert-butyl)-o-benzoquinone was used to obtain new perfluoroalkyl-substituted sterically hindered o-benzoquinones. Their structure was established by 1H, 13C, and 19F NMR spectroscopy and IR spectroscopy, as well as by electron absorption spectroscopy. The ability of new perfluoroalkylated derivatives to form o-semiquinone metal complexes was studied by EPR spectroscopy in solution.
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Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 11, pp. 2718—2724, November, 2015.
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Cherkasov, V.K., Druzhkov, N.O., Zolotukhin, A.A. et al. 3, 6-Di(tert-butyl)-o-benzoquinone fluoroalkylated derivatives. Russ Chem Bull 64, 2718–2724 (2015). https://doi.org/10.1007/s11172-015-1213-y
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DOI: https://doi.org/10.1007/s11172-015-1213-y