The formation of Jaggregates of 21-thia-5,10,15,20-(tetra-4-sulfonatophenyl)-porphyrin in acidified aqueous solutions is reported for the first time. The spectral-luminescent properties of these species were measured and ascribed to excitonic interactions. The number of coherent interacting monomeric porphyrin molecules in the aggregate was determined. J-Aggregates of this heteroporphyrin were found to fluoresce. The fluorescence quantum yield Φfl was found to be 1.8·10–4. The J-aggregates were found to be photolabile. Upon their photo-excitation to the absorption band at 503 nm, these species collapse to the monomeric doubly-protonated molecules. The photomonomerization process is reversible: the J-aggregates form again upon maintenance of the solution in the dark.
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Translated from Zhurnal Prikladnoi Spektroskopii, Vol. 89, No. 2, pp. 177–183, March–April, 2022. https://doi.org/10.47612/05147506202289177183.
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Melnik, A.D., Zhebit, T.S., Krylov, A.B. et al. Formation of J-Aggregates of 21-thia-5,10,15,20-tetra-(4-sulfonatophenyl)-porphyrin in Acidified Aqueous Solutions. J Appl Spectrosc 89, 232–237 (2022). https://doi.org/10.1007/s10812-022-01348-y
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DOI: https://doi.org/10.1007/s10812-022-01348-y