Various methods were developed and compared for determining the concentration of hydroxyl groups in oligomers using azide-substituted oligooxetane diols as examples. A rapid IR spectroscopic method was the most convenient for substituted azide-substituted oligooxetane diols and had the advantages of high accuracy, good reproducibility, fast analysis, and low sensitivity to moisture. The principles underlying the developed methods were suitable for the development of other methods for determining the concentration of hydroxyl groups in various oligomers and polymers.
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Translated from Zhurnal Prikladnoi Spektroskopii, Vol. 84, No. 2, pp. 186–191, March–April, 2017.
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Tarasov, A.E., Lodygina, V.P., Komratova, V.V. et al. New IR-Spectroscopic Methods for Determining the Hydroxyl Content in Oligomers. J Appl Spectrosc 84, 211–216 (2017). https://doi.org/10.1007/s10812-017-0453-z
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DOI: https://doi.org/10.1007/s10812-017-0453-z