Abstract
The Miocene Oxaya Formation, exposed along the western Andean slope in northern Chile, represents one of the largest ignimbrite provinces on earth. In this study, magnetic fabric data were acquired from a ~ 1-km-long core drilled vertically through a single cooling unit of the Oxaya Formation the ca.22 Ma Cardones ignimbrite. Samples for magnetic analysis were obtained every 20 m from the fine-grained matrix of the core. Detailed measurements of the variation in bulk magnetic properties, including natural remanent magnetization (NRM), susceptibility, and anisotropy of magnetic susceptibility (AMS), were used to monitor changes in magnetic mineralogy as well as changes in the strength and orientation of the magnetic fabric throughout the flow. AMS ellipsoid orientation and shape reflect rapid deposition from a concentrated granular fluidized flow and constrain both the location of the source caldera for this catastrophic eruption and processes of transport and deposition in this large-volume ignimbrite. After utilizing the magnetic remanence to correct for rotation about the core axis, well-grouped and imbricated petrofabric orientations reveal a well-defined SW (247°) transport direction down a proto-Western Andean slope indicating syn- or post-welding flow and confirming the deformed Lauca caldera as the likely source of the eruption. Systematic variations in fabric shape (T) and intensity (P) with depth reveal a predominately oblate fabric toward the top and base of the flow and predominately prolate fabrics in the center. These vertical changes in fabric reveal that this massive, apparently homogeneous, deposit has a systematic layering. This layering reflects depth-dependent temperature variations, temporal changes in the flow boundary zone during deposition and post-depositional processes.
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Introduction
The Central Andes of northern Chile and southern Peru exposes the Oxaya Formation, a sequence of four ignimbrites that constitute one of the largest Miocene ignimbrite provinces on Earth (Salas et al. 1966; Wörner et al. 2000; García et al. 2004; van Zalinge et al. 2016). Oxaca Formation ignimbrites form a prominent plateau along the western escarpment of the Western Cordillera (Fig. 1). Ignimbrites of this magnitude (M > 8 using the magnitude scale of Mason et al. 2004) are a result of large catastrophic explosive eruptions and caldera collapse. They commonly travel to distances exceeding 100 km from their source and represent some of the most dangerous and destructive eruptions on the planet. However, because there have been no eruptions of this magnitude in recorded history, fundamental depositional processes within the associated large pyroclastic eruptions remain poorly constrained. Examination of magnetic petrofabrics using the anisotropy of magnetic susceptibility (AMS) can yield important insights into the transport and deposition of these enormous flows as well as post-depositional processes.
Anisotropy of magnetic susceptibility is a technique that measures the strength, orientation, and shape of the rock petrofabric at the centimeter scale as reflected by the shape, distribution, and alignment of its magnetic minerals. Using AMS to delineate the magnetic fabric has been shown to reliably reflect the microscopic rock fabric even in apparently homogeneous rocks (Tarling and Hrouda 1993). Over the last several decades AMS studies of ignimbrites have been used to constrain flow patterns and processes in both inter and intra caldera settings. These studies, beginning with Ellwood (1982), are summarized by Cañón-Tapia and Mendoza-Borunda (2014), Willcock et al. (2015), and Ort et al. (2015). Magnetic fabrics in pyroclastic flows have been shown to vary in shape, direction, and intensity with distance from the source caldera and have been used to infer changes in transport direction and depositional process (Fisher et.al. 1993; Baer et al. 1997; Le Pennec et al. 1998; Ort et al. 2003, Porreca et al. 2003, LaBerge et al. 2009; Willcock et al. 2015). Relatively few studies, however, have systematically examined the variation of fabric with depth in a single ignimbrite (MacDonald and Palmer 1990; Hillhouse and Wells 1991; Ort et al. 2003; LaBerge et al. 2009; Willcock et al. 2015).
During a 2012 drilling campaign by BHP along the Western Andean escarpment east of Arica, Chile, nearly 8 km (7773 m) of core was recovered from the early Miocene ignimbrites exposed at or near the surface in 11 holes at elevations ranging from 2336 to 3903 m. The drill cores penetrated through the entire Oxaya formation ignimbrites and into the basement. Samples for this study were collected from a 1.14-km long drill core drilled at an altitude of 3692 m where the Oxaya Formation is exposed at the surface (Fig. 1; Hole 1 in van Zalinge et al. 2016). The core recovered 981 m of ignimbrite and 15 m of underlying sediment and volcaniclastic before penetrating 148 m of basement.
In this study, we use the anisotropy of magnetic susceptibility (AMS) together with microscopy, paleomagnetic, and rock magnetic measurements to characterize the rock fabric in one of the largest members of the Oxaya Formation, the > 1000 km3 Cardones ignimbrite. We present here a petrofabric study of samples collected vertically through ~ 1 km (945 m) of a single cooling unit to evaluate changes in fabric and facies with depth. Our aim is both to place constraints on the location of the source caldera and to investigate depositional processes, emplacement mechanisms, and flow dynamics of this massive eruptive body.
Geologic setting
The Andean margin in northern Chile developed in response to the subduction of the Farallon plate beneath the South American plate and the resultant formation of a continental magmatic arc (Jordan et al. 1983; Scheuber and Gonzalez 1999; Martinod et al. 2010). In northern Chile, the Andean forarc comprise, from west to east, three major morphological units: the Coastal Cordillera, the Central Depression and the Precordillera or Western Andean Slope. The Coastal Cordillera in the west is composed principally of Mesozoic arc rocks and marine sediments. South of Arica, the Coastal Cordillera is separated from the Tertiary to recent volcanic and sediment of the Western Cordillera and the Altiplano by fanglomerates of the Central Depression. Overlying these fanglomerates and onlapping onto both the Coastal Cordillera at sea level in the west and the present volcanic arc (Western Cordillera) at ca. 4600 m in the east is the Miocene fluvio-volcaniclastic sequence that typifies the Precordillera. This sequence is dominated by a thick succession of large-volume welded ignimbrites of the Oxaya Formation (Salas et al. 1966; Vogel and Vila 1980; García et al. 1996, 2000, 2004; Wörner et al. 2000; Tobar and Salas 2015; van Zalinge et al. 2016).
The Oxaya Formation comprises a sequence of four sub-horizontal, extracaldera ignimbrites. From oldest to youngest these are the Poconchile, Cardones, Molinos, and Oxaya ignimbrites. They are generally thought to have been deposited during a Miocene ignimbrite flare-up related to the acceleration of convergence at the termination of a period of flat slab subduction along this segment of the continental margin (Wörner et al. 2000). The basal flow has been dated at 22.74 ± 0.02 Ma and the uppermost flow at 19.71 ± 0.04 Ma (van Zalinge et al. 2016).
In the study area, the Oxaya Formation defines the modern erosion surface and can be traced 130 km in an E-W direction and 300 km in a N-S direction along the coast of northern Chile and southern Peru (Fig. 1) (Tosdal et al. 1981; Schröder and Wörner 1996; Wörner et al. 2002; García et al. 2004). The total volume of the Oxaya Formation is estimated to be more than 3000 km3 (Schröder and Wörner 1996).
Since its emplacement in the early Miocene, deformation of the ignimbrite succession in the Pre-Cordillera region has been minor (van Zalinge et al. 2016, 2017a). In the study area, the ignimbrites are gently folded into a series of long wavelength, doubly plunging, asymmetric, en-echelon antiforms, the Oxaya, and Huaylillas anticlines (Fig. 1). The trend of these antiforms varies along their 50 km strike from N-S to 140°. The northernmost Oxaya anticline is bounded on its western limb by the steeply dipping Ausipar fault (van Zalinge et al. 2016), which does not rupture the modern erosion surface but is exposed in the deeply incised Azapa and Luta quebradas (Fig. 1). The drill site is located on the western flank of the Huaylillas anticline. At this location, the Oxaya succession is gently folded and dips ~ 5.7°W. van Zalinge et al. (2016) estimate that approximately 1.2° of this westward dip reflects the initial dip of the surface at the time of emplacement of the ignimbrites.
The source of Oxaya Formation ignimbrites is not well established. Garcia et al. (2000) suggested that they may have originated from the subsequently deformed Lauca Caldera. The 50 × 23 km2 Lauca Caldera occupies a large part of the Cordon Belen and Lauca river basin yet only its western margin is visible (Fig. 1).
Cardones ignimbrite
The Oxaya Formation forms a plateau comprising three distinct large-volume ignimbrites, the Cardones, Molinos, and Oxaya, which overlie the much smaller-volume Poconchile ignimbrite. The large-volume Cardones ignimbrite is exposed over an area of ~ 4200 km2. Its varies from circa 1 km in the deeply-incised paleo-canyons in the more eastern reaches, to around 100 m on topographic highs and in the more distal western reaches (van Zalinge et al. 2016, 2017a). Minimum volume estimates are on the order of 1260 km3 (García et al. 2004). The Cardones has a weighted mean 238U/206Pb age of 21.92 ± 0.02 Ma (van Zalinge et al. 2016).
At the coring site, the Cardones ignimbrite is a massive, ~ 1 km thick, eutaxitic, crystal-rich, lithic-poor, and red rhyolitic tuff (Fig. 2). It is ubiquitously welded with pervasively flattened juvenile clasts (fiamme) that are altered to clays at the top and base of the flow. The three main components of the ignimbrite at this location are free crystals, juvenile clasts, and lithic clasts. Free crystal fragments include quartz, plagioclase, potassium feldspar, biotite, and amphibole (Fig. 3a,b) with accessory minerals including magnetite, ilmenite, and hematite. Modal abundance of the crystal fragments varies between 23 and 51% (van Zalinge et al. 2016) and sizes range from < 0.5 to 5 mm. Juvenile clasts constitute < 5% of the bulk ignimbrite and are generally deformed into fiamme. Lithic clasts, more abundant toward the base of the flow, are typically sub-rounded volcanic lapilli of variable composition. The microcrystalline ash matrix is largely devitrified. Based on detailed analysis of clast distribution, welding intensity, and crystal modes, van Zalinge et al. (2016) divided the Cardones ignimbrite into two eruptive units, the lower of which was further divided into four subunits.
Depositional fabrics within the Cardones are defined macroscopically by the orientation of fiamme and the preferred orientation of crystal fragments such as biotite. An almost pervasive imbricated fabric of fiamme and biotite crystals (Fig. 2) is observed at nearly all levels in the flow. Primary welding is evidenced by the presence of devitrified remnant fluidal juvenile shard textures (Fig. 3c), the ubiquitous flattened juvenile fiamme and loading induced, in situ secondary crystal fragmentation (van Zalinge et al. 2018). The observed architecture is likely to arise from numerous factors relating to the generation, transport, emplacement and post-emplacement modification of the ignimbrite.
Methods
To avoid overloading the cryogenic magnetometer during rock magnetic analysis, small, ~ 1 cm3 core samples, were obtained every 20 m primarily from the fine-grained matrix of the drill core. Prior to analysis, samples were weighed and measured to obtain a density profile through the ignimbrite.
Detailed measurements of the variation in bulk magnetic properties including magnetic susceptibility, natural remanent magnetization (NRM) and anisotropy of magnetic susceptibility (AMS) were used to monitor variation in petrofabric intensity, shape, and orientation with depth in the flow. Complementary rock magnetic experiments including isothermal remanence (IRM) acquisition followed by alternating field (AF) demagnetization, low-field magnetic susceptibility vs temperature and thermal demagnetization of 3-component IRM experiments were run on selected samples to characterize the magnetic carriers. Further observations were made using both reflected and transmitted light on an optical microscope.
Low-field AMS was measured on a KLY-3 Kappabridge housed at the University of Southern California. Data analysis was done using Anisoft 4.2 software (Chadima and Jelínek 2008) and Cureval software (Chadima and Hrouda 2009). AMS exploits magnetic susceptibility anisotropy of minerals (see reviews in Martin-Hernandez et al. 2004). In an individual mineral crystal, the ability to acquire a magnetization in a specified direction is commonly dependent on crystallography or shape. The magnetic anisotropy of the bulk rock will then depend on its mineralogy, the preferred orientation of the magnetic minerals as well as on the distribution of the magnetic grains within the rock. Closely spaced, strong magnetic grains will interact magnetically and influence the bulk AMS (Hargraves et al. 1991). AMS is commonly expressed as a second rank tensor and represented as an ellipse with principal directions: k1 maximum, k2 intermediate, and k3 minimum (k1 > k2 > k3). The mean susceptibility kmean is simply (k1 + k2 + k3)/3. By analogy to the strain tensor, the magnetic lineation (L = k1/k2) is defined as a vector in the direction of k1. The magnetic foliation (F = k2/k3) has a direction defined by the pole to the foliation, k3. The ratio k1/k3 (P) thus expresses the degree of anisotropy, which reflects the strength of the magnetic fabric.
The shape of the susceptibility ellipsoid can be represented by a parameter (T) where T = (lnF − lnL) / (lnF + lnL) (Jelinek 1981). If k1 = k2 > k3, the ellipsoid will be flattened (oblate) and T will have a value between 0 and 1 whereas if k1 > k2 = k3 it will be elongate (prolate) and T will have a value between 0 and − 1.
As analogous to granular flow in sedimentary systems, the long axis of the susceptibility ellipsoid (k1) is commonly imbricated parallel to the main flow direction and the pole to the magnetic foliation (k3) deviates at a small angle (typically < 20°) from the bounding upper surface of the ignimbrite. In some high-concentration flows in which rolling or saltation become important, k1, like other elongate grains, could align perpendicular to the flow (Ort 1993). Therefore, in this study, analysis of k3 imbrication was used preferentially to determine the direction of flow.
Results
Density profile
The density profile of an ignimbrite reflects the degree of compaction (Smith 1960; Ragan and Sheridan 1972; Sheridan and Ragan 1975; Sparks et al. 1999; Sheridan and Wang 2005), which is in turn related to its history of temperature, fluid solubility, pressure, loss of porosity and strain. A profile of density vs depth can therefore be used to place constraints on the welding history of the flow (Sheridan and Wang 2005). The large-volume Cardones ignimbrite has a simple density profile exhibiting no obvious breaks or discontinuities (Fig. 4: and van Zalinge et al. 2016, Fig. 6). The density profile divides the ignimbrite into three distinct zones similarly observed in other ignimbrites (Ragan and Sheridan 1972). The upper zone comprises the top 80 m of the flow and shows a rapid linear increase in density with depth from a low of 1900 to a high of 2200 kg/m3. Although the Cardones is exposed at the surface at the drill site, the first 30 m of the ignimbrite proved to be extremely friable and was not systematically recovered in the drill core. Observations from the other drill cores (van Zalinge et al. 2016), however, indicates that this upper zone can reach thicknesses of > 100 m, indicating that the topmost layer was partially eroded at this location.
Extending from 80 to 880 m depth, excluding outliers that likely include fragments of lower density crystal-rich pumice (van Zelinge et al. 2016), the matrix density increases gradually with depth from 2200 kg/m3 at 80 m to a maximum value of 2360 kg/m3 at 880 m. A marked decrease in density is observed 65 m above the base of the flow, at ~ 90% of the total depth and the fiamme aspect ratio decreases markedly below 800 m (van Zalinge et al. 2018). The region of maximum density and pumice deformation is inferred to be where the combined effects of temperature, loading, and volatile dissolution (Sparks et al. 1999) were maximized and where nearly all pore space has been eliminated in the devitrified ignimbrite. The smooth pattern of density variation with depth indicates that, at this location, we are looking at a simple, single cooling unit. The cooling unit may represent a single flow or it could be a composite of many flows that have been emplaced in such rapid succession that they cannot be differentiated (Smith 1960).
Below 880 m, the density of the ignimbrite falls back to a value of 1900 kg/m3, measured close to the base of the flow at 945 m (Fig. 4). Low density at the base of the flow suggests rapid cooling resulting in decreased welding, increased alteration and secondary clay formation.
Microscopy
Iron oxide crystals observable in thin section, represent slightly less then 1% of the total crystal assemblage of the Cardones ignimbrite (van Zalinge et al. 2016, 2017b). This visible iron-oxide assemblage can be further subdivided into four distinct populations.
The first population comprises large, commonly > 100 μm and up to 500 μm, euhedral oxide crystals (Fig. 3f). At all levels in the ignimbrite, most of these large crystals exhibit classic oxidative exsolution (oxyexsolution) textures. Oxyexsolution trellis textures in magnetite and ilmenite or Ti-magnetite are indicative of slow cooling and/or oxidizing conditions. Previous studies have interpreted them as reflecting either a slow ascent of magma prior to eruption (Saito et al. 2004; Turner et al. 2008) or the slow cooling of the ignimbrite after hot emplacement (Bowles et al. 2013; Jackson and Bowles 2014).
The second population of iron-oxides has a very fine, micron to submicron grain-size. This population is barely discernable with the optical microscope yet is prevalent throughout the devitrified groundmass. Previous studies have shown that these ultra-fine oxides can occur both as a primary phase in the ash and as a secondary phase that forms along shard rims and within vesicle walls of pumice fragments during high-temperature crystallization (Schlinger et al. 1988; Thomas et al. 1992; Palmer et al. 1996; Pioli et al. 2008).
A third group of iron oxides consists of those associated with primary inclusions in, or secondary alteration of, biotite and amphibole. Primary inclusions as shown in Fig. 3a tend to occur as large inclusions (tens of μm) while iron oxides resulting from alteration and mineralization (Fig. 3d) typically have grain sizes < 10 μm. They are commonly concentrated along cleavage planes or surrounding the altered biotite and amphibole reaction rims (van Zalinge et al. 2017b) or overgrowths. Tabular, euhedral biotite (2–4 vol%) is widespread throughout the ignimbrite with crystals typically ~ 100 μm in width. The extent of alteration and the amount of magnetite/hematite inclusions, however, are observed to vary markedly with depth in the ignimbrite. The less-dense top and bottom zones of the ignimbrite have fewer and predominately unaltered biotite crystals (Fig. 3a,e). The high-density, intensely welded, central section of the flow, in contrast, has abundant iron oxides associated with increased alteration and deformation of the biotite. Therefore, although biotite abundance, size, and shape-preferred orientation contribute to the magnetic susceptibility throughout the ignimbrite, at depths where biotite alteration and magnetite exsolution is prevalent, alteration products are likely to dominate the anisotropy of magnetic susceptibility.
The final population of iron oxides is associated with the lithic inclusions. Volcanic fragments, predominately of andesitic and granitic composition, typically contain primary iron oxides of magmatic origin.
Paleomagnetic results
Characteristic remanent magnetization
Initial measurements of natural remanent magnetization (NRM) measured on a 2G magnetometer in the Paleomagnetism Laboratory at Occidental College reveal a variation with depth in the flow reflecting changes in both the concentration and the mineralogy of the remanence-carrying fraction (Fig. 5a). The NRM profile further subdivides the flow into four distinct units that broadly correspond with the subunits defined by van Zalinge et al. (2016) based on juvenile and lithic clast distribution. The uppermost unit, defined by the top ~ 190 m of the core, reveals NRM intensities that vary about a mean value of 0.45 A/m. Below this layer, at depths of ~ 190–650 m, we observe a distinctive interval characterized by anomalously low NRM intensities (0.15 A/m) with little variability (± 0.03). In contrast, the third zone at depths of ~ 650–900 m, displays higher magnetization intensities and high variability. NRM intensities in this lower unit are observed to increase stepwise to reach a maximum value of 2.52 A/m at a depth of 900 m. This increase in intensity and variability likely reflects an increase in andesite and granite lithic content (van Zalinge et al. 2016). Below 900 m, within the low-density unit at the base of the ignimbrite, NRM intensities decrease precipitously by two orders of magnitude from 2.52 to 0.03 A/m.
NRM was routinely demagnetized in alternating magnetic fields (AF) of 10, 20, 40, 60, and 90 mT. A typical plot of intensity loss as a function of AF demagnetization is shown in Fig. 5b. In most samples, half of the initial remanent intensity is lost by ~ 30–35 mT and typically ~ 80% is lost by 90 mT. These experiments reveal that the NRM is composed of one or, in some cases, two overlapping components of remanent magnetization. The characteristic remanent magnetization (ChRM) demagnetizes straight toward the origin of demagnetization plots. ChRMs were generally determined from 4 to 5 demagnetization steps from 10/20 mT to 90 mT with an average maximum angular deviation (MAD) of 2.8°. The broad coercivity spectrum observed reflects a range of magnetic grain sizes and mineralogy.
In a large-volume welded ignimbrite, the direction of the magnetic remanence vector will typically record the direction of the Earth’s magnetic field either at the time the flow cooled through the Curie temperature of the constituent magnetic minerals or at the time the magnetic assemblage grew through the blocking volume. Substantial welding (Dingwell 1998; Russell and Quane 2005) indicates emplacement temperatures above the Curie temperature of magnetite (575 °C) and the resulting remanence of the primary mineral assemblage is likely to be thermal in origin (thermal remanent magnetism; TRM). The predicted declination and inclination for the axial-dipole at this latitude are 359° and − 34°. Individual measured declinations, however, scatter randomly within the plane normal to the core axis (α95 = 90) because of the inherent degree of freedom of rotation about the axis of the drill core. In contrast, observed inclinations have a mean value of 37° ± 12° ranging from 12 to 68° with a generally Fisherian distribution. Statistical analysis of inclination-only paleomagnetic data (McFadden and Reid 1982; Enkin and Watson 1996; Arason and Levi 2010) demonstrates that the inclination measured in a drill core will, on average, be shallower than the true average inclination with the amount of apparent flattening dependent on the magnitude of the inclination. For an average inclination of 37°, apparent flattening is predicted to be less than 1° (Arason and Levi 2010). The magnitude of the average inclination is not significantly different from the predicted value of 34° for the axial-dipole at this latitude. The polarity, however, is consistently reversed, indicating that the Cardones ignimbrite was emplaced and acquired a TRM or thermochemical remanent magnetism (TCRM) during a single reverse polarity interval. Constraints from U/Pb geochronology (21.92 ± 0.02 Ma 2 σ; van Zalinge et al. 2016) indicate that the Cardones ignimbrite was erupted during chron 6AAr (21.877–22.166 Ma) of the magnetic polarity time scale (MPTS) of Cande and Kent (1995).
Rock magnetic results
Measurement of bulk magnetic susceptibility and magnetic susceptibility vs temperature shows that the mean susceptibility of the Cardones ignimbrite is 31.97 × 10−4 SI ranging from 4.95–58.08 × 10−4 SI. The susceptibility versus depth profile largely mirrors the density profile (Fig. 6a), increasing gradually with depth before falling off precipitously toward the base of the flow. A simple biplot of density vs susceptibility shows a good correlation (R = 0.78). (Fig. 6b). This correlation suggests that, as the density and welding intensity increases, the concentration of magnetic minerals also increases.
Bulk low-field magnetic susceptibility vs temperature was measured on samples from five depths: 30 m, 80 m, 478 m, 920 m, and 944 m. Figure 7 displays three characteristic curves. Results indicate only minor variations in magnetic mineralogy with depth. In most of the samples, heating and cooling curves are similar, indicating that the susceptibility is reversible and new magnetic material was not created during the experiments. Throughout much of the flow, the dominant carrier appears to be magnetite with a Curie temperature approaching 575 °C (525–580 °C). However, in most samples, additional magnetic phases including titanomagnetite, maghemite, and hematite, are also evident. At 478 m (sample FCD1456, Fig. 7b), we observe a marked increase in susceptibility resulting from heating that may reflect an increased contribution of paramagnetic phases such as biotite, which is more conspicuous in thin section at intermediate depths. Samples FCD1478 and FCD1479 (920 and 944 m) collected near the base of the flow display Curie temperatures above 600 °C, more indicative of hematite, and heating curves with multiple inflection points, suggestive of several magnetic phases (Fig. 7c).
Isothermal remanent magnetization (IRM) acquisition curves indicate a dominance of low coercivity magnetic minerals that begin to saturate in fields of ~ 0.1 T but rarely completely saturate, even at the maximum field of 1 T. The magnetized samples were subsequently stepwise AF demagnetized and the IRM acquisition versus demagnetization is shown in Fig. 8a. Results show the intersection of the magnetization and demagnetization curves, at fields approximating the coercive force (Hcr), and yield “R” values (ratio of the saturation remanence demagnetized to the coercive force to the undemagnetized saturation remanence), consistently < 0.40 and, in some cases, as low as 0.27, indicating a prevalence of strongly interacting magnetic particles (Cisowski 1981). The acquired IRM is almost completely erased in AC fields of only 100 mT also pointing to strong interaction fields. A complementary experiment (Fig. 8b) comparing the AF demagnetization behavior of IRM and anhysteretic remanent magnetization (ARM) known as the Lowrie-Fuller test (Lowrie and Fuller 1971; Johnson et al. 1975) indicates that the stable remanent magnetization is likely to be held predominately in a small (~ 0.05 to ~ 10 μm), single domain (SD), or pseudo-single domain (PSD) particles. Mean destructive fields (MDF), typically < 40 mT corroborate this.
In a final rock magnetic experiment (Fig. 9), samples were given three components of IRM magnetization in fields of 0.12 T, 0.3 T, and 1.0 T sequentially along the x, y, and z axis of the sample. The samples were then stepwise thermally demagnetized. This procedure characterizes the magnetic carriers based on both their coercivity spectrum and their unblocking temperature characteristics (Lowrie 1990). Results reveal that the magnetization is held principally in the low coercivity fraction, which demagnetizes between 575 and 625 °C. This confirms that the principal carrier of the remanent magnetization is likely to be interacting magnetite particles. The remaining smaller portion of remanent magnetization resides in the highest coercivity fraction, which demagnetizes at 675 °C, characteristic of hematite.
AMS results
The AMS tensor has a magnitude, represented by anisotropy parameter P, a shape represented by anisotropy parameter T, and a spatial orientation (Table 1).
The anisotropy parameter P (k1/k3), shown in Fig. 10a as a function of depth in the flow, ranges from 1.015 to 1.099, indicating that the percent magnetic anisotropy varies from ~ 1 to ~ 10%. Higher values of P tend to be recorded between 200 and 550 m depth. There are additional spikes in P deeper in the flow, with the highest value at 944 m. To constrain the origin of this variation, we examine the relationship of P with other rock magnetic parameters. Rheological control (composition, concentration) of fabric intensity would be expected to lead to a correlation of P with compositional layering. Compositional layering in an ignimbrite can result from changes in clast population supplied at source or temporal changes in physical conditions within the flow. Comparison of the anisotropy parameter P with the magnetic susceptibility (Fig. 10b), a proxy for magnetic mineral concentration, reveals that these parameters are poorly correlated (R = 0.094). Likewise, a comparison of P with the NRM intensity, which reflects the concentration of only the remanence-carrying magnetic fraction, shows a poor correlation (R = 0.13), indicating that the observed variation in P in the vertical profile is not primarily a function of the composition or concentration of magnetic minerals. This conclusion is corroborated by geochemical analyses that show the Cardones ignimbrite has a largely homogeneous bulk composition and nonsystematic variation in pumice geochemistry (van Zalinge et al. 2016).
It is also possible that the fabric intensity might be principally related to the degree of welding and compaction, which is expected to increase with depth in the flow. Near the base of the flow at 945 m (Fig. 10a), an anomalously high value of P (1.1) implies that there may have been enhanced compaction and shear at this level. In general, however, P is largely uncorrelated with density (R = 0.04), leading us to conclude that compaction-welding is not the primary cause of the observed changes in fabric intensity.
In contrast, a comparison of P with the shape parameter T (Fig. 10c) reveals a significant inverse correlation (R = 0.61), suggesting that changes in fabric intensity (P) are associated with the changes in fabric shape (T). Lower degrees of anisotropy (P) are largely associated with oblate fabrics and higher degrees of anisotropy with prolate fabrics.
The shape of the AMS ellipsoid, as defined by the T parameter, varies from prolate to oblate with values varying from + 0.691 to − 0.700 (Fig. 10a). As shown on the Flinn diagram in Fig. 10d, oblate, dominantly planar, fabrics are chiefly associated with the uppermost and basal margins of the core while prolate, linear fabrics dominate the central regions. In detail, above a non-erosive, frictional, contact with the substrata, the basal 125 m (820–945 m) shows a well-defined triaxial oblate fabric (T = 0.364, F = 1.028, L = 1.014). In this interval (~Unit 1, subunit 1of van Zalinge et al. 2016), the magnetic foliation dips 12° to 066° and biotite is well aligned. This layer also shows evidence of inverse grading, with mean grainsize and percentage of free crystals as well as the number of lithic fragments increasing upward (van Zalinge et al. 2016).
The overlying ~ 200 m (600–820 m: ~Unit 1, subunit 2 of van Zalinge et al. 2016), is an interval of inconsistent fabrics. By 820 m, P is at a minimum (P = 1.01) and the magnitude of the magnetic foliation has fallen to F = 1.015, where it remains, with little change (σ = 0.006), up to the surface (Fig. 10a). At this depth, the orientation of the foliation has steepened, dipping 19.8° to 254°, indistinguishable from the mean. In contrast, the magnitude of the magnetic lineation (L) becomes remarkably unstable, swinging from L = 1.004 to L = 1.051. As a consequence, the shape parameter (T) also fluctuates repeatedly from prolate to oblate (− 0.565 < T < + 0.666) in this interval (Fig. 10a).
At a depth of approximately 600 m, fabric intensity (P) begins to rise, accompanied by a corresponding increase in the magnitude of the magnetic lineation (Fig. 10a). In response, the fabric shape transforms to a triaxial prolate ellipsoid and remains prolate for the next ~ 400 m (T = − 0.296, F = 1.015, L = 1.032). It is also in this interval, 180 m–600 m (~Unit 1, subunit 3 of van Zalinge et al. 2016), that the largest fiamme aspect ratio is measured and biotite becomes clearly altered and exsolved (Fig. 3d). Flattened and deformed shards (Fig. 3c) are visible in thin section. Observations of linear magnetic fabrics imply that there is likely to have been an increase in shear strain in this interval.
In the uppermost unit, defined magnetically above 180 m, fabrics once again become oblate (T = 0.376, F = 1.015, L = 1.007). This unit is characterized by a decrease in welding and alteration and the appearance of elongate vesicles (Fig. 3a). It also has a measurably weaker anisotropy (P = 1.022). Fragmented crystals (Fig. 3b) and visible void spaces are observed while spherulites (Fig. 3a) indicate crystallization from high temperatures in supercooled melts (Breitkreuz 2013).
The orientation of the AMS tensor is represented in Fig. 11 by an equal area projection of the directions of the principal susceptibility axes of the AMS ellipsoids. As in most layered deposits the orientation of the uncorrected k3 minimum axes of the anisotropy tensors (Fig. 11a) scatter around the normal to the depositional surface (≈vertical). In contrast, because the core was not oriented during drilling, unconstrained rotation about the drilling axis causes the directions of the maximum and intermediate axes (k1 & k2) to scatter randomly within the plane normal to the core axis (Fig. 11a) . However, because this late rotation affects both orientation of the remanence vector (NRM) and the AMS tensor, we can use the NRM to correct the orientation of the anisotropy ellipsoid. The NRM of the Cardones ignimbrite was acquired at a time when Earth’s ambient magnetic field was reversed, in a direction that was down and toward the south. Rotation about the drill-core axis, which is approximately normal to bedding, should leave the magnetic inclination unchanged. Therefore, simply rotating the declination back to south should, to a first approximation, correct the NRM for the superimposed drilling rotation. The same angular rotation applied to the AMS ellipsoid should, therefore, also correct its orientation for the rotation associated with core recovery. The corrected orientation is expected to vary about the true direction because this correction does not account for variation inherent in the NRM direction due to processes such as secular variation. Uncorrected secular variation, acquired as the flow cooled slowly through the blocking temperature of its magnetic mineral assemblage, would result in increased directional scatter. Despite its limitations, application of this simple correction significantly improves the clustering of the axes of the susceptibility ellipse. Figure 11 shows the orientation of the principal susceptibility axes, k1 (magnetic lineation) and k3 (pole to magnetic foliation), before (Fig. 11a) and after (Fig. 11b) this simple correction. Corrected k3 axes reveal a well grouped mean of 71° toward 247° (α95 = 6.2°; K = 13.5), indicating a well-defined imbrication of the magnetic foliation of 19°. Investigation of imbrication as a function of depth in the ignimbrite suggests that the hot-welded interior shows a somewhat steeper imbrication than the less welded margins. Given, however, that the two populations both have an α95~6°, this result is highly suggestive but not statistically significant at the 95% confidence level.
The statistically simple/single flow direction throughout the 1 km thick unit implies that during deposition, as the topography progressively infilled, AMS orientations did not vary appreciably in response to changing boundary conditions, as has been observed in other studies (Hillhouse and Wells 1991; Baer et al. 1997; Branney and Kokelaar 2002; Ort et al. 2003; LaBerge et al. 2009; Cas et al. 2011). This result, together with previously published observations of considerable thickness variations within the Cardones ignimbrite across the Andean forearc (van Zalinge et al. 2016) indicate that the flow at this location was constrained by a deep (~ 1 km) major paleovalley in which the flow developed a well-defined fabric orientation. If the measured SW flow direction (247°) is presumed to have been down the paleoslope away from the source caldera (Ellwood 1982; Incoronato et al. 1983; Knight et al. 1986; MacDonald and Palmer 1990; Hillhouse and Wells 1991; Seaman et al. 1991; Ort 1993; Fisher et al. 1993; Lamarche and Frogatt 1993; Palmer and MacDonald 1999; Ort et al. 2003; Cas et al. 2011; Dedzo et al. 2011), then our result supports the proposed source area of García et al. (2000). They suggested that the Oxaya Formation was the equivalent of the coeval intracaldera Lupica formation farther east, which is exposed and deformed in the Cordon Belen and Lauca river basin (Fig. 12).
Discussion
A pyroclastic flow is a mix of hot gas and particles that emanates from an explosive volcanic eruption. The internal architecture of the resulting ignimbrite reflects the complex interactions and processes occurring at the source, during transport and deposition and post emplacement. Here, we discuss the origin of the magnetic petrofabric and interpret the internal architecture of the Cardones ignimbrite in terms of fabric-forming processes.
Origin of the magnetic petrofabric
Microscopy and rock magnetic experiments show that the Cardones ignimbrite has a magnetic mineral fraction that is a mixture of paramagnetic and “ferromagnetic” (used generally for remanence carrying phases) phases. Paramagnetic minerals including biotite, amphibole, plagioclase, and ilmenite and ferromagnetic minerals, including magnetite and hematite/maghemite occur throughout the flow. Given this mixture, the ferromagnetic mineral phases are predicted to dominate the AMS signal because the intrinsic susceptibility of the paramagnetic phases is orders of magnitude lower than that of the ferromagnetic minerals.
In the Cardones ignimbrite the ferromagnetic Fe-oxides occur as free crystals, inclusions in other minerals (notably biotite and amphibole) and as a component of the devitrified fine grained matrix. Large free crystals of magnetite, which comprise the majority of the free opaque minerals, typically form in a magma before eruption and exsolve sub-micron magnetite and ilmenite lamellae during cooling. These large subhedral Fe-oxide crystals contribute to the bulk magnetization of the ignimbrite. However, because they are largely equant with cubic symmetry and isotropic magnetic properties and are well dispersed within the matrix, these crystals are unlikely to have a significant influence on either the orientation or shape of the AMS tensor. Likewise magnetic minerals incorporated into roughly equant, randomly oriented igneous lithics will contribute to the bulk magnetization but little to the shape or orientation of the anisotropy ellipse.
In contrast with the large, free Fe-oxides crystals, Fe-oxide inclusions in other mineral grains and ultra-fine Fe-oxides within the matrix and along the edges of pumice are likely to make a substantive contribution to the magnitude, shape, and orientation of the magnetic tensor. Fe-oxide inclusions in biotite are observed as both primary magmatic inclusions and as secondary inclusions formed by subsequent alteration. These two populations vary in concentration with depth in the ignimbrite. Primary magnetite inclusions, which appear commonly as isolated crystals in unaltered biotite and amphibole, are observed predominately at the top (< 200 m) and toward the base (> 600 m) of the flow. At intermediate depths (~ 200 to 600 m) the biotite is generally altered with the replacement products pseudomorphing the original mica. A consequence of this replacement reaction is the exsolution of magnetite and ilmenite along cleavage planes and as overgrowths along the crystal margin where it is partly oxidized to maghemite or hematite (Fig. 3d). This secondary Fe-oxide growth will contribute to the AMS in this interval and enhance the fabric related to the biotite.
Rock magnetic experiments suggest that the magnetization of the ignimbrite largely originates from interacting single domain (SD) or pseudo-single domain (PSD) magnetite particles. This includes the fine-grained magnetite observed along biotite cleavage planes in reaction rims but also includes the sub-micron ultrafine magnetite in the matrix and along the edges of pumice. Sub-micron, ultra-fine-grained magnetite has been reported in a number of other high-temperature silicic ignimbrites (Geissman et al. 1983; Schlinger et al. 1988; Wolff et al. 1989; Thomas et al. 1992; Pioli et al. 2008; Worm and Jackson 1999). These microlites of magnetite, with grain sizes in the superparamagnetic (SP) to (SD) size-range, form as high temperature precipitates along the rims of glass shards and within vesicle walls of pumice fragments during high-temperature, vapor-phase crystallization. They are principally composed of acicular or lath shaped crystals that commonly have a strong shape and distribution anisotropy. During fabric development, as the glass shards flow, the microlites have been shown to mimic the fabric created by the shards (Pioli et al. 2008). Therefore, although the microcrystalline Fe-oxides can be either primary or post-depositional, the orientation and shape of the resultant AMS fabric will largely reflect the flow fabric of the ignimbrite.
Processes controlling fabric formation
This is the first study to systematically sample a continuous vertical section through a large-volume (~ 1 km thick), single ignimbrite cooling unit. Previous studies have shown that welded ignimbrites typically exhibit a planar, oblate fabric, inferred to have formed largely as a result of welding compaction (Ellwood 1982; MacDonald and Palmer 1990; Palmer et al. 1996; Le Pennec et al. 1998; Pioli et al. 2008; LaBerge et al. 2009). Predominately linear, prolate fabrics are not reported as commonly and are typically associated with high-grade rheomorphic ignimbrites (Ellwood 1982; Knight et al. 1986; Pioli et al. 2008). Reports of ignimbrites displaying both oblate and prolate fabrics are even less common (Knight et al. 1986; Pioli et al. 2008; Wilcock et al. 2015). Pioli et al. (2008) examined fabric-shape variation as a function of stratigraphic height in an ~ 8 m section of the rheomorphic Nuraxi Tuff . Willcock et al. (2015) described vertical changes in petrofabric in a ~ 1300 m succession of the non-rheomorphic, intra-caldera Permian Ora ignimbrite in northern Italy. Despite apparent differences in physical conditions and depositional environments, comparison of our analyses to these studies reveals similarities. The ignimbrites are commonly imbricated in the direction of flow and have oblate fabrics toward the base of the sequence, a central interval dominated by linear, prolate fabrics, and an upper oblate layer, suggesting common processes control fabric development in large volume ignimbrites.
Modern concepts of pyroclastic density currents that form ignimbrites are based on field observations, laboratory experiments, and theoretical models. These studies suggest that they comprise stratified flows with a basal dense and concentrated laminar granular fluidized flow region (Fisher et al. 1993; Druitt 1998; Wilson and Walker 1982; Roche et al. 2016) and an overlying dilute turbulent region (Breard and Lube 2017). The concentrated and dilute parts can exchange mass and energy (Doyle et al. 2008; Breard et al. 2017). There is a growing consensus that the massive facies that make up much of volume of ignimbrites are formed by deposition from the concentrated basal granular flowing region. Here, we interpret the magnetic fabrics in the Cardones ignimbrite in terms of deposition from a granular fluidized flow and shear flow during post-emplacement compaction and welding.
In the Cardones, the magnetic foliation (k3) is aligned (α95 = 6.2°) and imbricated throughout the entire 1 km cooling unit. This imbrication can be interpreted as a consequence of deposition from the concentrated basal granular flow with an upstream component of accretion (Fig. 13). The ignimbrite is deposited from the basal granular flow as a consequence of loss of pore pressure as the flow advances. We follow Branney and Kokelaar (1992) in envisaging a thin aggradational boundary layer between the flowing granular material and the static deposit. In this interfacial region between flow and deposit, there is pronounced shear.
We propose a waxing and waning history to the basal concentrated flow with a longitudinal and temporal evolution (Fig. 13). The basal flowing region initially grows by transfer of particle mass from the overlying more dilute turbulent regions of the current, perhaps by mechanisms documented in large scale experiments (Breard and Lube 2017). High pore pressures develop in the basal concentrated flow, as envisaged by Roche et al. (2016). As the current propagates, the supply of mass from the overlying current diminishes, the basal granular region starts to thin, pore pressure dissipates, clast collisions and hence friction coefficient increases, transitioning into a waning and depositional phase (Smith et al. 2018). At the flow front, increasing friction and decreasing pore pressure results in increasing the aggradation rate so the interface between deposited material and shearing material at the flow base slopes upstream. Retrogradational deposition has been documented in analogue granular flow experiments (Smith et al. 2018). Thus the aggradation direction has a vertical and an oblique upstream component. We suggest that imbrication is developed within the boundary layer between the basal concentrated flow and the deposit and is frozen in as the interface moves upwards and upstream. Therefore, it is a combination of three interacting factors: shear in the aggradational boundary layer; stacking up of flat particles at an angle to the depositional surface in the same manner as a cobble acquires an imbrication in a stream; and alignment of particles parallel to the depositional interface, which in retrogradational deposition is oblique to the ultimate base and top of the deposit, which enables elongate particles like glass shards and biotite to develop an initial, syn-depositional imbrication.
The initial syn-depositional fabric is subsequently modified by post-emplacement: loading-compaction and welding; shear; and late tectonic tilting. Modification by post-emplacement gravity-driven, loading-compaction will impose a component of pure shear on the rock volume, flattening the AMS ellipsoid into the bedding plane. Density and fiamme aspect ratio profiles (Fig. 3 and van Zalinge et al. 2016) show that the interior of the Cardones ignimbrite is quite strongly welded. van Zalinge et al. (2016) estimated a maximum14% decrease of thickness, in the interior of the flow, as a consequence of post-emplacement compaction and deformation. This would flatten the imbrication angle in the central units of the ignimbrite from approximately 25° to the observed mean of 19°. Similarly, post-emplacement flow or late slumping will impose a component of slope-parallel simple shear on the ignimbrite, which will rotate the depositional fabric into the shear plane or superimpose a secondary fabric on the syn-depositional fabric. Finally, late tectonic tilting of ~ 4.5° westward (van Zalinge et al. 2017a) and a hole inclination correction, which the site survey indicates is near vertical (89.6°) at the surface and deviates to 2.9° ± 0.1° toward 249° beginning at ~ 450 m, does not change the fabric shape but it would alter the observed fabric imbrication by approximately 1°.
AMS fabric data reveal that while the orientation of the imbrication remains statistically constant throughout the 1 km thick ignimbrite there is a tendency for it to be slightly flatter and more oblate nearer the margins and somewhat steeper and more prolate in the interior (Fig. 10a). As both post-depositional welding and downslope shear are expected to reduce imbrication angles in the densely welded ignimbrite interior, an attractive explanation for the somewhat higher imbrication angles could be related to lateral changes in ignimbrite rheology, which thins, cools, and becomes more viscous downslope. A cooler, more viscous flow might produce a damming effect resulting in compression normal to the creep direction and a steepening the imbrication angle during agglutination. Comparable compressional structures are commonly observed in lava flows where the flow front decelerates due to increase in viscosity and more fluid lava piles up behind the flow front (Sparks et al. 1993).
Shape and intensity variation of petrofabric within a stratigraphic succession has been interpreted by previous authors as a combination of changes in welding compaction and simple shear during rheomorphism (Pioli et al. 2008; Knight et al. 1986), increasing shear stress with depth in flow produced by paleotopography, changes in boundary layer conditions or interactions of flow pulses (Branney and Kokelaar 1992; Willcock et al. 2015 An additional alternative is that petrofabric shape and intensity variation in the Cardones ignimbrite might be explained by changes in late-stage strain associated with a depth-dependent variation in emplacement temperatures, cooling rate, and hence viscosity, which allowed late downslope flow and shear in the hot, less viscous interior of the ignimbrite. This flow must have been synchronous with densification by compaction and deformation of the pumice into fiamme.
There is abundant evidence of spatial and temporal temperature variation in the ignimbrite. As the glass transition temperature of hydrous rhyolitic melts (Dingwell 1998; Russell and Quane 2005) similar to the Cardones ignimbrite (van Zalinge et al. 2018) is below 600 °C, uncompacted cuspate and blocky shards (Fig. 3e) observed along the lower margin (~ 940 m), reflect rapid cooling and emplacement temperatures less than 600 °C. After insulation from the substratum, cooler temperatures within the basal unit would likely have persisted as a consequence of the abundant cold lithic clasts included within the basal unit (Marti et al. 1991; van Zalinge et al. 2016). Similarly, within the upper unit (0–180 m), fragmented crystals (Fig. 3b) attest to explosively of eruption (van Zalinge et al. 2018) while spherulites in the glassy material (Fig. 3a) indicate crystallization from temperatures at or near the glass transition (Breitkreuz 2013) and rapid cooling. In contrast, evidence suggests that the interior of the 1 km thick Cardones ignimbrite (Fig. 3c), with fewer lithic clasts and abundant deformed glass shards, was emplaced at temperatures at or above the glass transition and cooled significantly slower. Petrologic data reveal a coincident zone of a low % orthoclase in sanidine (van Zalinge et al. 2016, 2017b) indicating magmatic temperatures ≤ 730 °C in the central units. At these depths, the petrofabrics are likely to have been produced by shear strain imposed on the ignimbrite at temperatures between ~ 500 and 725 °C, where hydrous rhyolite behaves as a fluid (Dingwell 1998; Russell and Quane 2005), yet prior to devitrification of the glass. Modeling results (Riehle et al. 1995) suggest that for rhyolitic glass significant compaction develops at temperatures above 600 °C for a layer 80 m thick. In addition, for a length scale of 200 m and a thermal diffusivity of 5 × 10−7 m2/s, the conductive cooling time would be approximately 650 years while the center of the flow (a length scale of 500 m) would have taken of order 104 years to cool to temperatures outside the welding window (Russell and Quane 2005). Long residence times at elevated temperatures will enable strain to develop from downslope creep. Under these conditions, the observed prolate, constrictional fabrics, showing downslope elongation, might reflect the basinward narrowing of the deeply incised paleovalley, common in regions with convex hypsometry like the central Andes (Montgomery et al. 2001) or simply downslope creep of a thick flow during compaction.
Conclusions
Rock magnetic results indicate that magnetization of the large-volume Cardones ignimbrite in northern Chile is carried by a mixture of magnetite and hematite/maghemite. These magnetic minerals are both primary and secondary: exsolved within igneous Fe-oxides, along biotite cleavage planes, and in the matrix along rims of glass shards and collapsed voids. The magnetic fabric was thus likely to have been acquired largely post-emplacement mimicking syn-emplacement imbrication of micas and syn and post-emplacement shear of glass shards.
Magnetic fabrics reflect rapid deposition from a concentrated granular fluidized flow with an upstream component of accretion. The ubiquitous imbricated foliation is inclined parallel or sub-parallel to the emplacement direction, indicating flow to the southwest (247°) following a paleo-channel away from its probable source in the Lauca caldera. Systematic vertical sampling through the ~ 1 km-thick cooling unit reveals that the imbrication angle and shape of the magnetic fabric varies systematically with depth in the ignimbrite. The hot-welded interior displays a steeper imbrication and the development of a prolate, predominantly linear fabric while the cooler margins have an oblate, predominately planar fabric and a shallower imbrication. We suggest that superimposed on an inherent temperature variation within the ignimbrite, compression during agglutination and constrictional creep within the narrow, deeply incised paleovalley during rheomorphism might explain both the observed variation in imbrication angle and the development of prolate, linear fabrics. Therefore, measurement of the magnetic petrofabrics in the Cardones ignimbrite allows us not only to constrain the location of the source caldera but yields fundamental insights into depositional and emplacement processes associated with catastrophic, large-volume eruptions.
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Acknowledgments
We are grateful to Jean des Rivières for granting access to the drill core and all the BHP staff in Chile who helped us during this study. We would also like to thank Scott Bogue at Occidental College for use of the Paleomagnetism Laboratory. This paper has also benefitted from the reviews of M. Ort and R. Cas.
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This work was funded by the BHP.
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Platzman, E.S., Sparks, R.S.J. & Cooper, F.J. Fabrics, facies, and flow through a large-volume ignimbrite: Pampa De Oxaya, Chile. Bull Volcanol 82, 8 (2020). https://doi.org/10.1007/s00445-019-1345-2
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DOI: https://doi.org/10.1007/s00445-019-1345-2