Abstract
The Salau deposit, located in the Axial Zone of the French Pyrenees, is the most important tungsten deposit ever mined in France. Two types of mineralization, both closely associated with a granodiorite intrusion, are distinguished. The first is a fine-grained scheelite skarn related to contact metamorphic and metasomatism between the intrusion and the adjacent carbonate rocks. The second type is represented by massive sulfides accompanied by coarse-grained scheelite, apatite, and electrum. This syn-kinematic mineralization is found enclosed within the skarn ore but occurs also within the granodiorite stock along major ductile–brittle shear zones. REE contents of scheelite and apatite from the two types of mineralization show differences suggesting that the two types derived from two different fluids. U/Pb dating on zircon, apatite and scheelite illustrates that magmatic zircon and apatite formed at 295 ± 2 Ma during emplacement and cooling of the granodiorite intrusion. These are cogenetic to the fine-grained scheelite skarn. Hydrothermal apatite from massive sulfide ores yields a younger age of 289 ± 2 Ma, whereas closely associated coarse-grained scheelite yields a consistent although less precise age of 284 ± 11 Ma. These results suggest that the late massive sulfide ore with abundant coarse-grained scheelite and electrum is related to the emplacement of an underlying, more evolved intrusion, accompanied during its ascent by the development of steeply dipping reverse-dextral shear zones.
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Introduction
Mineral deposits are the result of a complex combination of geological processes that cause local metal enrichment in the Earth’s crust. Geochemical tools may be applied to identify these processes. Among these tools, development of laser ablation inductively coupled plasma mass spectrometry (LA-ICP-MS) in situ analyses can provide either the age of the U-Th bearing phases associated with mineralization or their geochemical signature (Sylvester and Ghaderi 1997; Jackson et al. 2004; Cocherie et al. 2005; Harley et al. 2007; Raju et al. 2015; Mao et al. 2016; Poulin et al. 2018). Due to recent developments of U/Pb dating of minerals, geochronology now allows to date successive mineralizing and alteration events. A wide range of minerals and isotopic systems are now used for direct dating of ore minerals including Rb/Sr on sphalerite (Nakai et al. 1993; Christensen et al. 1995); Re/Os on sulfide minerals (Stein et al. 1998, 2000; Morelli et al. 2005); K/Ar and Ar/Ar on Mn oxides (Vasconcelos et al. 1992; Ruffet et al. 1996; Spier et al. 2006), illite (Bechtel et al. 1996; Clauer et al. 2015; Bozkaya et al. 2016), adularia (Lang et al. 1994; Sanematsu et al. 2006; Oze et al. 2017), lepidolite (Smith et al. 2005); or Sm/Nd on fluorite (Chesley et al. 1991, 1994), and scheelite (Bell et al. 1989; Anglin et al. 1996; Eichhorn et al. 1999). The U–Th/Pb system allows to date uraninite (Ludwig et al. 1987; Bowles 1990; Fayek et al. 2002; Ballouard et al. 2017, 2018), heterogenite (Decrée et al. 2010, 2014), apatite (Pochon et al. 2016; Ballouard et al. 2018), columbite–tantalite (Romer and Wright 1992; Romer and Lehmann 1995; Smith et al. 2004; Che et al. 2015; Melleton et al. 2015; Fosso Tchunte et al. 2018), wolframite (Frei et al. 1998; Romer and Lüders 2006; Harlaux et al. 2018), cassiterite (Gulson and Jones 1992; Yuan et al. 2008), and scheelite (Wintzer et al. 2016) or bastnaesite (Ntiharirizwa et al. 2018).
The Axial Zone of the Pyrenees (France) comprises Paleozoic rocks affected by polyphased tectonometamorphic events during the Variscan and Alpine events (Casas et al. 1989; Vissers and Meijer 2012; Denèle et al. 2014; Cochelin et al. 2017). The area is known to host several tungsten and gold deposits and occurrences (Derré 1973; Guy 1988). Among these, the Salau deposit was the most important tungsten mine in France, with a production of 13,950 t WO3 between 1970 and 1986, with an exceptional high average grade of 1.5% WO3. The deposit is located at the contact between the la Fourque granodioritic intrusion and metacarbonate host rocks. The ore, traditionally considered as a scheelite skarn, has a complex mineralogy and morphology, affected by a late “hydrothermal alteration” (Fonteilles et al. 1989). Similar skarn occurrences exist in the vicinity of Salau, such as Aurenere, in Spain (Fig. 1).
In addition to scheelite, the Salau deposit also contains gold in economic concentrations (1–10 g/t; Guiraudie et al. 1963; Fonteilles et al. 1989). However, the ore-forming processes and the paragenetic position of gold remain unclear. Some authors considered that sulfides, related to the late “hydrothermal alteration,” are the retrograde stage of the scheelite skarn formation (Fonteilles et al. 1988). Other studies interpreted these sulfides as the expression of a shear zone mineralization without a genetic link with the La Fourque intrusion (Ledru and Autran 1987). This results, in part, from the fact that neither the emplacement age of the intrusive rocks nor metal deposition has been dated. The age of intrusion and skarn is interpreted to be late Variscan (Derré 1973). Similarly, deformation along the shear zone is the latest deformation event in the deposit (Kaelin 1982).
The aim of this paper is to constrain the timing and the origin of high-grade W/Au mineralization during the late-orogenic evolution of the Axial Zone of the Pyrenees. The Salau deposit and Aurenere occurrence were studied in order to characterize mineralization using field, petrography, SEM imagery, whole rock, and mineral geochemistry (apatite, scheelite). In addition, LA-ICP-MS U/Pb in situ dating on zircon, apatite, and scheelite was performed to constrain ages of emplacement of the intrusive rocks or of mineralizing event(s).
Geological background
Regional geology
The Pyrenees are an east–west trending Alpine orogenic segment located between France and Spain. The Axial Zone of the Pyrenees is a segment of the southern external zone of the Variscan belt, which has structured the whole western Europe at the end of the Paleozoic, mostly during the Pennsylvanian (Garcia-Sansegundo et al. 2011). Ediacarian to Paleozoic metasedimentary and plutonic rocks related to the Variscan orogeny crop out in the Axial Zone (Fig. 1). A strong structural contrast exists in the Axial Zone between middle crust rocks with flat-lying foliation and the upper crust rocks with a steeply dipping schistosity (Carreras and Capellà 1994; Denèle et al. 2009a; Cochelin et al. 2017). Four major successive deformation events have been documented (Denèle et al. 2009a; Laumonier et al. 2010; Denèle et al. 2014; Cochelin et al. 2017). The first stage is of crustal thickening during N–S to NE–SW compressive tectonics, responsible for fold–thrust belt development in the upper crust (323–310 Ma; Bodin and Ledru 1986). The second stage is localized in the middle crust (310–305 Ma). This is a crustal-scale stage of syn-convergence and horizontal lateral flow of the middle crust contemporaneous with the HT/LP metamorphic peak and partial melting (Vilà et al. 2007). The third stage corresponds to deformation in reverse-dextral shear zones during cooling of the Variscan crust as exemplified by the Merens shear zone (Denèle et al. 2008). The activity of the shear zone has never been dated using robust methods. The latest stages of deformation are marked by a strong heat anomaly at the bottom of the upper crust between ca. 305 to 285 Ma (Romer and Soler 1995; Aguilar et al. 2014). The emplacement of calc-alkaline and more evolved plutons is responsible for contact metamorphism, locally accompanied by skarn formation (Autran et al. 1970; Fonteilles et al. 1989; Soler et al. 1990; Cardellach et al. 1992; Ayora and Casas 1995; Barnolas and Chiron 1996). Several scheelite occurrences located in Devonian carbonate formations of the Axial Zone are known, for example in Salau, Aurenere, Costabonne, or les Tourrettes (Fig. 1).
Local geology
Stratigraphy and tectonometamorphic evolution of the wall-rocks
In the Salau/Aurenere district, the Paleozoic stratigraphic succession forms a large-scale monocline (Charuau and Derré 1976; Derré et al. 1980; Fig. 1). From bottom to top, the following stratigraphic units are defined:
The Mont Rouch Formation (Early to Middle Ordovician) is a flysch complex reaching up to 2 km in thickness. It is followed by a monotonous series of graphitic and pyritic Silurian shales known to act regionally as a thrusting level underneath the more competent Devonian rocks. To the north, the Salau Formation comprises various carbonate and pelite intercalations. It consists of a lower member of graphitic limestones followed by centimetric alternations of siltstone and limestone beds. Near the top of the Salau Formation, the massive gray limestones occur. The top of the Salau Formation consists of bluish shales.
Three main tectonic stages of deformation have been distinguished in the study area (Derré et al. 1980), which correspond well with the regional tectonic evolution (Denèle et al. 2014; Cochelin et al. 2017). The first stage of deformation (D1) involved a top-to-the-SE shear deformation responsible for the development of recumbent isoclinal P1 folds of all dimensions whose axes have a consistent N45°E direction. These folds, which partially transpose the compositional layering, are associated with the development of a crenulation cleavage and a subhorizontal schistosity S1 (Déramond 1970; Charuau 1974; Derré 1979; Colchen et al. 1997; Denèle et al. 2014; Cochelin et al. 2017). The D2 deformation stage resulted in the formation of sub-vertical folds associated with epizonal regional metamorphism (greenschist facies 300–350 °C). P2 folds are isoclinal, hectometric in size, and overturned towards the North. Fold axis have a N110°E–N120°E direction. They are accompanied by a crenulation cleavage S2 parallel to their axial planes. The axial plane foliation (S2) is marked by muscovite and chlorite. This stage (D2) is also marked by the emplacement of the granodioritic apex, accompanied by contact metamorphism. The final D3 deformation stage is represented by large E–W (N80 to N120°E), steeply dipping (60 to 80°N), ductile shear zones and other brittle faults at the contact between the la Fourque granodiorite and the carbonate host rocks. These dextral reverse faults with a displacement of more than 200 m (Fig. 2; Lecouffe 1987) are characterized by strain folds in marbles, C–S structures in the granodiorite, and breccias.
Intrusive rocks
The La Fourque granodiorite crops out at the bottom of the Salat valley (Fig. 1). Its shape is almost equidimensional occupying an area of about 1 km2. The morphology of the intrusive stock, established in an antiform, seems to be controlled by the regional structures defined by the thick carbonate formations surrounding it (Derré et al. 1984).
Kaelin (1982) and Soler (1977) showed that the granodiorite postdates the main foliation stage D2 (Denèle et al. 2014). The mylonites at the contact with carbonate country rocks are related to a more recent ductile–brittle or brittle deformation (Fonteilles et al. 1988).
Three main types of intrusive rocks can be distinguished in the vicinity of the Salau deposit: the apical marginal facies of the La Fourque granodiorite, a porphyritic facies in the centre of the intrusion, and aphanitic dykes or sills distinguished on the basis of their grain size, chemical, and mineralogical compositions (Toulhoat 1982; Guy 1988; ESM 1 Fig. 1). The marginal facies is a relatively dark, fine-grained granodiorite with an equigranular texture (0.5–1 mm) 100 to 250 m thick. It becomes thinner at depth where it disappears. This “apical granodiorite” is composed of interstitial crystalline quartz, plagioclase (An 20–60), rare microcline, abundant biotite, and accessory minerals (zircon, apatite). The chemical composition of the marginal facies corresponds to a granodiorite with a low K2O content (2.6 wt%) compared to other granitoids in the upper Pyrenean massifs. The porphyritic facies in the center of the massif is a diorite–monzogranite, rich in potassium feldspar (20%) with higher K20 (4.6 wt%). The two petrographic types belong to two different geochemical lineages (Raimbault and Kaelin 1987).
Different types of aphanitic sills and dykes are observed. Microdioritic dykes are cut by the apical granodiorite which contain dark microdiorite enclaves (Fonteilles et al. 1989). Aplite dykes cut both the La Fourque intrusive rocks and the marbles. They are commonly epidotized on the southern side of the La Fourque granodiorite.
The Aurenere W/Au occurrence crops out at 5 km to the West of the Salau deposit. The occurrence is also located at the contact between a granodioritic stock and Devonian marbles that are skarnified and mineralized over ca.100 m2 (Fig. 1). The bulk chemical composition of the granodiorite stock is similar to that of La Fourque (ESM 1 Fig. 1), but, due to the erosion level, only the marginal facies is observed in the field. At its contact, the marbles are skarnified.
Mineralization styles
The first tungsten-bearing skarn was discovered in 1951, in contact with calc-alkaline intrusions at Costabonne in the Axial Zone of the Pyrenees (Guy 1988). The Salau deposit was discovered by in 1959, during regional tungsten exploration (Guiraudie et al. 1960). The deposit was estimated to contain 20,000 t of WO3 from 1.3 Mt of ore at 1.5% WO3 using a cutoff grade of 0.8 wt% WO3 (Fonteilles et al. 1989). The orebodies located on the southern margin of the La Fourque granodioritic intrusion (Derré et al. 1980) were mined between 1970 and 1986 (Lecouffe 1987). The deposit was historically described as a scheelite skarn due to the presence of calcic silicates (grossular, hedenbergite) and because of its close spatial association with an intrusion. The deposit comprises two main orebodies, the Bois d’Anglade and the Veronique fault (Fonteilles et al. 1989). The Bois d’Anglade orebody is subdivided in three, named “Formation Nord,” “Golfe,” and “Formation Sud” (Fig. 2).
Two types of skarn were described at the Salau deposit (Derré et al. 1984). The first is massive and resulted from the transformation of the lower graphitic marbles or the upper marbles. It is often characterized by an almost monomineralic gangue mineralogy of either garnet or pyroxene. This first skarn does not carry significant tungsten mineralization. In contrast, the second skarn formed by metasomatism of calcic hornfels consists of alternating garnet-, pyroxene-, epidote-, and titanite-rich bands. These banded zones are inherited from the pre-existing sedimentary bedding.
A massive sulfide body of pyrrhotite, chalcopyrite, and sphalerite of 500 m × 250 m and 5 m thick is spatially associated to the Veronique Fault at the southern contact of the granodiorite with the country rocks. It is considered as part of the retrograde stage of the skarn (Fonteilles et al. 1989).
Mineralization at the Aurenere W/Au occurrence is similar to the Salau deposit. A grossular–hedenbergite–wollastonite skarn was formed during the prograde stage, whereas low contents of scheelite and disseminated sulfides (pyrrhotite, arsenopyrite) were developed during the retrograde stage. Late quartz veins cut skarn mineralization and contain coarse-grained scheelite and a massive arsenopyrite, pyrrhotite, chalcopyrite, sphalerite, and electrum (Palau i Ramirez et al. 1995; Palau i Ramirez et al. 1997; Palau i Ramirez 1998).
Field observations and mineralogy
The Bois d’Anglade orebody is crosscut by the Veronique Fault along its southern edge (Fig. 3a). The Bois d’Anglade orebody displays a comb shape located in an embayment of the Salau granodiorite. The bedding of Devonian-aged metasedimentary host rocks (N80E 80°N) is perpendicular to the contact with the intrusion in the embayment.
The Formation Nord and the Golfe orebodies consist of skarn (Fig. 3b) containing fine-grained scheelite. The prograde stage of skarn consists of a grossular, hedenbergite, and fine-grained scheelite (< 50 μm) assemblage (Fig. 4a). During the retrograde stage, garnet was replaced by epidote, whereas hedenbergite was replaced by amphibole, accompanied by the deposition of disseminated arsenopyrite and pyrrhotite (Fig. 4f). The proximal zone (up to 30 m from the intrusion) consists of garnet, pyroxene, and scheelite. The distal zone is characterized by a wollastonite-bearing assemblage. In this zone, the scheelite size is mostly fine-grained and less abundant.
In contrast, the Formation Sud orebody located along the strike of the Veronique Fault, which intersects the contact between the granodiorite and the marble (Fig. 3d), consists mainly of massive sulfides without skarn (Fig. 3c). Along the strike of the fault, the granodiorite is altered (albitized and chloritized) and brecciated with mylonitic clasts (Fig. 3e). The massive sulfides hosted by the Veronique Fault consist of coarse-grained scheelite, euhedral apatite, massive pyrrhotite, arsenopyrite, chalcopyrite, sphalerite, native bismuth, electrum (80% Au, 20% Ag), laitakarite, and tetrahedrite (Fig. 4b). Scheelite is coarse-grained (0.2–1 cm) with poikilitic crystals cut by late sulfides (Fig. 4c). Arsenopyrite was the first mineral to appear in this assemblage. It is fractured and filled by late pyrrhotite, chalcopyrite, and sphalerite accompanied by the crystallization of euhedral apatite, native bismuth, electrum, laitakarite, and tetrahedrite (Fig. 4e). Apatite grains are euhedral and unaltered. (Fig. 4h). Then, late veins of quartz, scheelite, calcite, and powdery chlorite cut the sulfides and represent the last stage of ore formation.
In the Formation Nord and Golfe orebodies, similar massive sulfides form lenses or clusters in the garnet and pyroxene skarn along the bedding of the country rocks or near the contact with the granodiorite. Strain folds, C–S structures and sigma clasts in skarn, cemented by massive sulfides along the contact between the fault and the granodiorite indicate dextral reverse kinematics (Fig. 3f, g). Aplitic dykes are locally spatially associated with the massive sulfide mineralization and crosscut the La Fourque granodiorite and the scheelite skarn (Fig. 3h). In some places, tourmaline veins, spatially related to massive sulfides, cut and alter the granodiorite (Fig. 3h; Lecouffe 1987). The skarn ore is intersected and displaced with a reverse kinematic at the contact with ductile, quartz-bearing, N90E 70°N faults. All around the La Fourque stock, sulfides are disseminated in hydrothermally altered granodiorite. All these features indicate that the massive sulfides formed after the la Fourque intrusion (Fig. 5).
Cathodoluminescence imaging
Cathodoluminescence imaging (Tescan, BRGM Orleans) was realized on selected zircon, apatite, and scheelite grains in order to detect inherited cores or zoning. Zircon grains from the Salau and Aurenere granodiorite do not show inherited cores (ESM 1 Fig. 2a, c and e; Fig. 5), with the exception of two grains (sample TP709 and TP728, ESM 1 Fig. 2b and 2d). Magmatic apatite is poikilitic and altered as droplets with growth zoning (TP 130, TP 608 and TP728, ESM 1 Fig. 3c and d). Hydrothermal apatite is euhedral, unaltered, sometimes with complex zoning, and contrast difference between core and rim (FT19, TP061, and TP 738; ESM 1 Fig. 3a and b). However, given its rhythmic aspect perpendicular to the rim, this contrast difference does not correspond to the presence of an inherited core but rather to compositional changes during the growth of the crystals. Finally, scheelite grains show growth zones without any evidence for inheritance (ESM 1 Fig. 4a, b, c; Fig. 9d).
Mineral chemistry of scheelite and apatite
Materials and methods
Fifty scheelite and 21 apatite grains were selected on thin and polished sections from 8 samples from the intrusive rocks and the two different types of mineralization. The location of the samples is given on Fig. 2. The data set is given in ESM 2 Tables 1 and 2.
LA-ICP-MS analyses were performed at Brest University (France) in order to obtain REE data for scheelite and apatite as well as Mo and W contents in scheelite, using a Geolas 193-nm Excimer Laser coupled to a Thermo Element II ICP-MS. Analytical conditions for the laser include a frequency of 10 Hz, a fluence of 6 J/cm2, and a spot size of 40 μm. Ablated material is transported to the ICP-MS in a helium flux of 253 mL/min. The mass spectrometer is initially calibrated with a multi-element solution. Reference standard is NIST 612, and the quality control standards are BIR 1 and BCR 2. A batch of analyses comprises a sequence of NIST 612, BIR 1, and BCR 2 standards followed by 20 samples. Raw data were processed using Glitter (Van Achterbergh et al. 2001) to obtain atomic concentrations. Ca43 was used as the internal standard. REE concentrations were normalized to chondrite (McDonough and Sun 1995).
Results
Early fine-grained scheelite has a higher content in Mo (75–240 ppm) than the late coarse-grained scheelite (0–70 ppm; Fig. 6).
Magmatic apatite shows a relatively flat REE pattern with a prominent negative Europium anomaly (Fig. 7a) with Eu/Eu* and Ce/Ce* values ranging from 0.03 to 0.08 and 0.88 to 1.03, respectively (Fig. 8a). A similar REE distribution is observed for fine-grained scheelite from Salau and Aurenere, with a large negative Europium anomaly (Fig. 7b, c). Eu/Eu* and Ce/Ce* ratios yield similar values ranging between 0.06–0.14 and 0.89–1.07 for Salau and 0.4–0.55 and 0.76–0.87 for Aurenere, respectively (Fig. 8a)
Hydrothermal apatite crystals, which are texturally co-genetic with the massive sulfides, show two types of REE patterns, correlated with inner textures of the grains. Core of grains (ESM 1 Fig. 3a and b) are enriched in light REE, depleted in heavy REE with a moderate negative Europium anomaly (Fig. 7d). Rims of the same apatite grains (ESM 1 Fig. 3a and b) are also enriched in light REE and depleted in heavy REE but present a positive Europium anomaly (Fig. 7d). Eu/Eu* and Ce/Ce* returned values of 0.22–6.4 and 0.74–1.05, respectively (Fig. 8a) and therefore plot out of the domain of magmatic apatite.
Coarse-grained scheelite from massive sulfides contemporaneous of hydrothermal apatite presents an enrichment in light REE (except La and Ce) and a depletion in heavy REE with small or absent Eu anomalies (Fig. 7e). These scheelite grains yield very different Eu/Eu* ratios from hydrothermal apatite ranging from 0.6 up to 1.48 for Ce/Ce* showing low variation around 0.81–1.03 (Fig. 8b). Late scheelite crystals found in quartz–calcite–chlorite veins and have a REE chemistry similar to the rims of the apatite grains in the massive sulfide ores (Fig. 7f, g) with slightly higher Ce/Ce* ratios reaching ca. 0.9–1.15. Very coarse-grained scheelite has two REE patterns: one is similar to late scheelite, the other is enriched in LREE (Fig. 7g).
LA-ICP-MS U/Pb geochronology
Materials and methods
Zircon, apatite, and scheelite grains were selected from 12 samples issued from the intrusive rocks and the two different types of mineralization. The location of the samples is provided on Fig. 2. Raw data is given in ESM 2 Tables 3, 4, and 5. Five fresh samples of igneous rocks were selected for U/Pb dating on zircon, three samples from the La Fourque intrusion (TP 754, TP 608, TP 610), and two samples from the Aurenere intrusion (TP 728, TP 709). Four samples were selected for U/Pb dating on apatite. One sample (TP 130) is magmatic apatite from the marginal facies of the La Fourque granodiorite. Three samples (TP 061, FT19, TP 738) are hydrothermal apatite associated with coarse-grained and massive sulfides. Three samples of coarse-grained scheelite contemporaneous to the massive sulfide ore hosted by the Veronique fault were selected for U/Pb dating.
A classic mineral separation procedure was applied to concentrate the zircon grains using the facilities available at ISTO laboratory. Rock samples were crushed, and the fractions with a particle size below 250 μm were processed further. Heavy minerals were concentrated by heavy liquids from the size fraction. Magnetic minerals were then removed with an isodynamic Frantz magnetic separator. Zircon grains were carefully handpicked under a binocular microscope and embedded in epoxy mounts that were then polished. For apatite and scheelite, U/Pb dating was realized in context on regular thin sections. U/Pb geochronology was conducted in situ by laser ablation inductively coupled plasma mass spectrometry (LA-ICP-MS) at Geosciences Rennes using an ESI NWR193UC Excimer laser coupled to an Agilent 7700x quadrupole ICP-MS equipped with a dual pumping system to enhance sensitivity (Paquette et al. 2014). The instrumental conditions are reported in ESM 2 Table 6. Additional information about the protocols used for U/Pb zircon dating can be found in Ballouard et al. (2015), and in Pochon et al. (2016) for apatite. According to Horstwood et al. (2016), uncertainties obtained for the reference material Plesovice were propagated to the analyzed zircon grains.
For U–Pb dating of scheelite, we followed the protocol of Wintzer et al. (2016) and used the NIST 612 glass standard as our primary standard (see ESM 2 Table 6). For all the samples, results are plotted in Tera-Wasserburg diagrams using Isoplot/Ex (Ludwig 2012). All errors are provided at 1σ level for zircon and 2σ level for apatite and scheelite.
Results
Zircon dating
Sample TP 754 is from the marginal facies at the SE edge of the La Fourque intrusion. Twenty-one zircon grains were analyzed (ESM 2 Table 3; Fig. 9a). Thirteen of these analyses are concordant (Fig. 9a) and define a concordia date of 295 ± 2.4 Ma (MSWD = 0.57). Five analyses either in zircon cores or in homogeneous grains define inherited apparent ages from older material around 325 and 350 Ma. Finally, 6 analyses are sub-concordant to discordant and are interpreted as reflecting the presence of a small amount of common Pb together with a slight Pb loss.
Sample TP 608 was collected in the porphyritic facies of the La Fourque intrusion. Eighteen zircon grains were analyzed (ESM 2 Table 3; Fig. 9b). Seven of these analyses (Fig. 9b) are concordant and yield a Concordia date of 296.9 ± 3.2 Ma (MSWD = 1.4) interpreted as the age of the intrusion. The remaining data are discordant at 280 Ma and attributed to Pb loss.
Sample TP 610 was collected on the northern side of the La Fourque intrusion from porphyritic facies. Twenty-four zircon grains were analyzed (ESM 2 Table 3; Fig. 9c). Fifteen analyses are concordant and yield a concordia date of 294.5 ± 2.2 Ma (MSWD = 0.81; Fig. 9c) interpreted as the emplacement age for this granodiorite. One concordant analysis yields an inherited apparent age from older material of ca. 320 Ma. Six analyses are discordant perhaps because of Pb loss and/or the presence of common Pb. In summary, all three samples from the La Fourque granodiorite yield concordant ages comparable within error at ca 295 Ma.
TP 709 and TP 728 were sampled on the Aurenere granodioritic intrusion. For sample TP 709, nineteen analyses were performed (ESM 2 Table 3; Fig. 9d). Nine of them are concordant (Fig. 9d) and yield a Concordia age of 293.9 ± 2.8 Ma (MSWD = 0.29). Twelve discordant results show either older, inherited, apparent ages, or Pb loss. On sample TP 728, eighteen analyses are concordant and yield a Concordia age of 293.4 ± 2 Ma (MSWD = 1.13) (ESM 2 Table 3; Fig. 9e). Two analyses define older inherited apparent ages from older material at ca. 700 and 570 Ma while one analysis shows signs of Pb loss. Therefore, all these results agree for an emplacement age at ca. 295 Ma for the Aurenere intrusion, indistinguishable from the emplacement age of the La Fourque intrusion.
Apatite dating
For sample TP 130, seventeen grains that were analyzed (ESM 2 Table 4) are discordant position (Fig. 10b) with a lower intercept of 297.3 ± 7.1 Ma (MSWD = 6.7).
Hydrothermal apatite grains were collected in massive sulfides of the Golfe (TP 061), the Formation Sud (TP 738), and the Veronique Fault (FT19). All the apparent ages obtained on these apatites are similar within error (Fig. 10a, c, d) if discordia are forced to a common Pb composition of 207Pb/206Pb = 0.870 obtained on galena from the massive sulfide mineralization (Marcoux and Moëlo 1991; Chew et al. 2014; Cochrane et al. 2014): TP 061 yields an age of 278 ± 9.7 Ma (N = 17; MSWD = 0.25), TP 738 gives a date of 287 ± 4.6 Ma (N = 15; MSWD = 3.2), and FT19 yields a date of 288.2 ± 3.4 Ma (N = 16; MSWD = 21). If all these data are plotted together in the same Tera-Wasserburg diagram (Fig. 10e), they return a date of 289.1 ± 1.9 Ma (N = 48; MSWD = 9.2).
Scheelite dating
Discordia ages were calculated for the coarse-grained scheelite (100 μm–2 mm) from Salau (211p, 214p, and 255p) (Fig. 10f, g h). Only scheelite from sample 255p contains sufficient uranium for dating (Fig. 10h). Sample 255p from Veronique Fault (n = 56; MSWD = 8.6) yields an age of 284 ± 11 Ma (2σ) when forced to 207Pb/206Pb = 0.870 (Marcoux and Moëlo 1991). Data with slight Pb loss were not taken into account for the calculation. Other samples returned poorly constrained ages of 256 ± 28 Ma (2σ) (214p) and 262 ± 16 Ma (2σ) (211p).
Discussion
In contrast to several skarn deposits worldwide, the Salau deposit has the particularity to host two different types of mineralization. The combination of field observations with mineral chemistry and geochronology provides insights to decipher the evolution stages of the mineralization.
Nature of the fluids
The mineral chemistry of scheelite and apatite provides evidence for mineral formation from different fluid sources. Higher Mo contents in the paragenetically early, skarn-hosted scheelite (Fig. 6) are in a good agreement with observations made on other deposits, such as Los Santos (Timon Sanchez et al. 2009), Mittersill (Eichhorn et al. 1999), Costabonne (Raimbault et al. 1993), or Eastern China (Song et al. 2014; Poulin et al. 2018). The lower Mo contents found for the paragenetically late, coarse-grained, scheelite could suggest formation from a fluid depleted in Mo.
REE data for cogenetic scheelite and apatite that provide further evidence for distinct mineralizing events (Raimbault et al. 1993) were two groups of REE patterns and are recognized for both scheelite and apatite, suggesting that two fluids are associated with mineralization. The first group of REE patterns is relatively flat, with a distinct negative Eu anomaly. Both the magmatic apatite of the La Fourque granodiorite (Fig. 7a) and fine-grained scheelite from the scheelite skarn (Fig. 7b) display these typical patterns for minerals derived from a magmatic source (Raju et al. 2015) which suggest they are linked here to the emplacement of the La Fourque granodiorite into Devonian marbles.
The second group of REE patterns is marked by LREE enrichment and moderate to high Eu/Eu* anomalies. Hydrothermal apatite grains present in the massive sulfide ore display negative europium anomalies in the core (Fig. 7c) and positive anomalies in rims (Fig. 7c). Cathodoluminescence images show contrasted growth bands (ESM 1 Fig. 3a and b) and confirm the compositional nature of the observed zonation. These compositional changes reflect the chemical evolution of the hydrothermal fluid. Coarse-grained scheelite, also associated with massive sulfides, presents a similar REE pattern with a weak positive Eu anomaly, as the typical signature of hydrothermal system (Lottermoser 1992).
Figure 11 shows the distribution of the different scheelite generations in a ternary LREE-MREE-HREE (Light Rare Earth Element - Medium Rare Earth Element - Heavy Rare Earth Element) diagram (Raju et al. 2015). The fine-grained scheelite has a strong enrichment in LREE and plots near the “skarn, porphyry W-Mo deposits” cluster, whereas scheelite from massive sulfides, enriched in both LREE and MREE, plots in the “vein Au-W deposits from West Australia” cluster. The discriminant diagram Eu/Eu* = f (Ce/Ce*) (Mao et al. 2016) also distinguishes these two groups for each mineral type (Fig. 8a, b). This likely reflects also the evolution of the fluid redox state. First, magmatic fluids from the La Fourque granodiorite, a reduced intrusion (ilmenite series; Blevin 2004), compatible with disseminated pyrrhotite in the skarn, were recorded in fine grained scheelite (ESM 1 Fig. 5). More oxidized fluids are responsible for the formation of the coarse-grained scheelite, hydrothermal apatite, and massive sulfides as shown by the REE patterns. Combined with field observations, this implies mixing between oxidized meteoric fluids and the contribution of a second magmatic source, different from the granodiorite, to explain the massive sulfide deposition.
This interpretation is corroborated by isotopic studies and fluid inclusion data (Toulhoat 1982; Guy 1988) showing evidence for different stages of mineralization that coincide with a decrease in fluid temperature and evolution of hydrothermal fluid compositions. A first magmatic fluid, which contains H2O and NaCl (Soler 1977), is found in the skarn minerals (quartz, garnet, hedenbergite, and scheelite). After the skarn formation, a H2O–CO2–CH4 fluid was probably linked to the decarbonatation of the country rocks during metasomatism mixed with the magmatic fluid to precipitate scheelite (Krier-Schellen 1988). The parameters for the skarn formation are estimated at 470 < T°C < 530, − 9 < log fS2 < − 6, − 27.7 < log fO2 < − 21.1 and P ≈ 2 kbar (Soler 1977). For the massive sulfides, δ34S values have been interpreted as characteristic of a fluid with a magmatic origin (Guy 1988; Palau i Ramirez 1998). The parameters for the late massive sulfide mineralization are estimated at 335 < T°C < 363, − 9.51 < log fS2 < − 8.45, − 32.8 < log fO2 < − 30.2 and 2.16 < P (kbar) < 2.58 (Krier-Schellen 1988).
Absolute time constraints on the Salau/Aurenere W/Au deposit
Direct in situ U/Pb geochronology on zircon, apatite, and scheelite yields distinct ages for the different stages of ore formation. Zircon and magmatic apatite dating yields an age of ca. 295 Ma, corresponding to the emplacement age of the La Fourque and Aurenere intrusions. The associated massive skarns have the same age. Massive sulfide ores related to the Veronique Fault formed later, as suggested by an age of 289 ± 2 Ma for hydrothermal apatite. Coarse-grained scheelite from massive sulfide ore yields an age of 284 ± 11 Ma consistent with the hydrothermal apatite age. Using the emplacement age of the la Fourque intrusion at 295 ± 2 Ma (and related skarn) and 289 ± 2 Ma for the hydrothermal apatite associated with massive sulfides ore, it appears that these mineralizations are the result of two distinct metallogenic events separated by at least 2 Ma. This interpretation is in agreement with field relations (alteration features, tourmaline veins and breccias observed along the late shear zones), demonstrating that the deposition of the massive sulfide ore postdate granodiorite cooling (Fig. 3e–g).
A model for the cooling of the La Fourque intrusion, computed using Darcy’s law and convection/conduction in porous media for an intrusion, was emplaced at 2 kbar. A geothermal gradient of 40 °C/km was used for the marble host rocks (Cochelin et al. 2017) and an initial temperature of 900 °C for the granodiorite. The permeability of the marble is set at 1.10−16 m2 and that of the granodiorite is 1.10−19 m2. In this example, the la Fourque granodiorite intrusive body (1 km2) cooled to geothermal gradient in less than ca. 40,000 years, comparable to other values of ca. 200,000 years (Petford et al. 2000; Eldursi et al. 2009; Chauvet et al. 2012; Nabelek et al. 2012; Bucholz et al. 2017). This implies that it cannot be the source for the coarse-grained scheelite, massive sulfide, and gold mineralization as they form at least 2 Ma after the intrusion had cooled.
At Salau, where massive sulfide mineralization within shear zone has a magmatic origin according to δ34S and fluid inclusions studies (Toulhoat 1982; Guy 1988; Krier-Schellen 1988), an igneous source other than La Fourque granodiorite is required. In Salau mine, evidence for possible intrusive bodies, younger than the La Fourque granodiorite, includes tourmaline veinlets and aplite veins (Fig. 3h). That could be derived from an evolved granite, emplaced deeper in the crust. This granitic stock could thus be considered as part of a long-lasting, multi-intrusion event that was emplaced during D3 deformation event and which was ultimately responsible for the scheelite bearing massive sulfide ores. Such relationships between different intrusive rocks were also observed in the nearby massifs of Marimanya (Palau i Ramirez 1998) and Cauterets (Reyx 1973). Similar observations were made at Hämmerlein (Lefebvre et al. 2018) or Los Santos in Spain (Timon Sanchez et al. 2009), where different granites were emplaced within a time gap of ca. 10 Ma. Throughout the Variscan Orogen, other examples of sulfide mineralization, consecutive to an early, mostly tungsten-rich mineralization, were described, such as Puy les Vignes (Harlaux et al. 2018) and Panasqueira (Codeço et al. 2017).
Concluding remarks
The Salau deposit is the expression of regional deformation and magmatism in the axial zone of the Pyrenees during the late Variscan evolution (Fig. 12). The La Fourque granodiorite was emplaced at ca. 295 Ma contemporaneously to D2 event, in compressional regime into the upper crust at ca. 2 kbar. The intrusion is associated with contact metamorphism and the formation of skarns along the intrusive contact. This event corresponds to a period where the upper crust of the Axial Zone was abnormally warm and the N-S compressive tectonic regime was marked by hectometric E–W trending folds. Later, at ca. 289 Ma with crust cooling, the deformation regime changed and was localized in shear zones along previously emplaced granitic stocks and gneiss domes. As a consequence, shear zones were developed at their contact with host rocks or within graphitic metasedimentary beds.
The Salau deposit consists of two types of mineralization. The first is a skarn with garnet, pyroxene, and fine-grained scheelite mineralization with disseminated arsenopyrite and pyrrhotite. The second type, a breccia, consists of a coarse-grained scheelite with abundant massive sulfide mineralization (arsenopyrite, pyrrhotite, chalcopyrite, sphalerite, sulfosalts, native bismuth, and electrum) located in a major fault. The skarn is related to the La Fourque granodiorite emplacement at ca. 295 Ma (zircon and magmatic apatite). The massive sulfides ore is related to a reverse dextral, E–W trending Veronique Fault developed at ca. 289 Ma (hydrothermal apatite and coarse-grained scheelite). This age result is the first direct dating of the D3 Variscan deformation event. This interpretation is corroborated by isotopic and fluid inclusion data, indicating that the massive sulfides and scheelite mineralization were formed by a buried younger intrusion.
At a larger scale, this study points out that magmatism and hydrothermal events are phenomena which take place on relatively short timescales, generally between ca. 104 to 106 years. Nevertheless, these events can be the expression of the regional evolution typically in late-orogenic stage, extending over several millions of years, explaining the superimposed mineralization events.
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Acknowledgments
This investigation was supported by the society e-Mines through its R&D activity and the ISTO. The authors thank the following persons for their support on the field: F. Carbalido, F. Cheval-Garabedian, Q. Monge, J.L. Carbalido, and M. Bonnemaison. C. Derré, P. d’Arco, A.S. Audion, M. Picault, J. Gouin, G. Raoult, and B. Cochelin are thanked for their technical support including the provision of samples and valuable advice. I. Di Carlo (ISTO) is acknowledged for the MEB cathodoluminescence and microprobe analytical analyses. We particularly thank S. Janiec, G. Badin, and P. Benoist from ISTO laboratory for the thin sections and rock-crushing preparations. We also address our thanks to the IUEM (Brest) for LA-ICP-MS analyses. Finally, we would like to acknowledge the editor in chief G. Beaudoin, the associate editor J. Gutzmer, and two anonymous reviewers for their careful reading of this article and constructive remarks.
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Poitrenaud, T., Poujol, M., Augier, R. et al. The polyphase evolution of a late Variscan W/Au deposit (Salau, French Pyrenees): insights from REE and U/Pb LA-ICP-MS analyses. Miner Deposita 55, 1127–1147 (2020). https://doi.org/10.1007/s00126-019-00923-2
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DOI: https://doi.org/10.1007/s00126-019-00923-2