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Numerical Analysis of the Effect of Pore Size Toward the Performance of Solid Oxide Fuel Cell

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Proceedings of the 11th International Conference on Robotics, Vision, Signal Processing and Power Applications

Part of the book series: Lecture Notes in Electrical Engineering ((LNEE,volume 829))

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Abstract

The effect of the anode pore size is numerically investigated with the aids of artificial solid oxide fuel cell (SOFC) microstructure information. The standalone effect of the pore size is impossible to be realized by the experimental approach. Additionally, the complete real microstructure information is also limited in the open literature as it required sub-micron 3D imaging equipment. The dusty-gas model is implemented into the developed quasi-3D SOFC model for the gas diffusion in the anode. The model with real microstructure information is successfully validated. The actual anode pore radius of 0.283 μm is artificially replaced with a radius of 0.025, 0.050, 0.250, 0.500, and 2.500 μm. Decrement of area-specific reactant (ASR) for the anode concentration is found with the increment of pore radius. Also, such increment promotes a small increment of ASRs for the anode activation and the anode ohmic loss.

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References

  1. Ab Rahman, M., et al.: Development of high-performance anode/electrolyte/cathode micro-tubular solid oxide fuel cell via phase inversion-based co-extrusion/co-sintering technique. J. Power Sources 467, 228345 (2020)

    Google Scholar 

  2. Ren, C., Zhang, Y., Xu, Q., Tian, T., Chen, F.: Effect of non-solvent from the phase inversion method on the morphology and performance of the anode supported microtubular solid oxide fuel cells. Int. J. Hydrogen Energy 45, 6926–6933 (2020)

    Article  Google Scholar 

  3. Rabuni, M.F., Vatcharasuwan, N., Li, T., Li, K.: High performance micro-monolithic reversible solid oxide electrochemical reactor. J. Power Sources, 458, 228026 (2020)

    Google Scholar 

  4. Liu, Y., Jia, L., Li, J., Chi, B., Pu, J., Li, J.: High-performance Ni in-situ exsolved Ba(Ce0.9Y0.1)0.8Ni0.2O3-δ/Gd0.1Ce0.9O1.95 composite anode for SOFC with long-term stability in methane fuel. Compos. Part B Eng. 193, 108033 (2020)

    Google Scholar 

  5. Price, R., Grolig, J.G., Mai, A., Irvine, J.T.S.: Evaluating sulfur-tolerance of metal/Ce0.80Gd0.20O1.90 co-impregnated La0.20Sr0.25Ca0.45TiO3 anodes for solid oxide fuel cells. Solid State Ionics, 347, 115254 (2020)

    Google Scholar 

  6. Shahid, M., He, C., Sankarasubramanian, S., Ramani, V., Basu, S.: Enhanced methane electrooxidation by ceria and nickel oxide impregnated perovskite anodes in solid oxide fuel cells. Int. J. Hydrogen Energy 45, 11287–11296 (2020)

    Article  Google Scholar 

  7. Tan, W.C., Iwai, H., Kishimoto, M., Brus, G., Szmyd, J.S., Yoshida, H.: Numerical analysis on effect of aspect ratio of planar solid oxide fuel cell fueled with decomposed ammonia. J. Power Sources 384, 367–378 (2018)

    Article  Google Scholar 

  8. Tan, W.C., Iwai, H., Kishimoto, M., Yoshida, H.: Quasi-three-dimensional numerical simulation of a solid oxide fuel cell short stack: effects of flow configurations including air-flow alternation. J. Power Sources 400, 135–146 (2018)

    Article  Google Scholar 

  9. Tan, W.C., Iwai, H., Kishimoto, M., Yoshida, H.: Implementation of multi-component dusty-gas model for species transport in quasi-three-dimensional numerical analysis of solid oxide fuel cell. Part II: direct ammonia fuel. IOP Conf. Ser. Mater. Sci. Eng. 670, 012022 (2019)

    Google Scholar 

  10. Brus, G., et al.: Combining structural, electrochemical, and numerical studies to investigate the relation between microstructure and the stack performance. J. Appl. Electrochem. 47(9), 979–989 (2017). https://doi.org/10.1007/s10800-017-1099-5

    Article  Google Scholar 

  11. Brus, G., Iwai, H., Otani, Y., Saito, M., Yoshida, H., Szmyd, J.S.: Local evolution of triple phase boundary in solid oxide fuel cell stack after long-term operation. Fuel Cells. 15, 545–548 (2015)

    Article  Google Scholar 

  12. Bhattacharyya, D., Rengaswamy, R., Finnerty, C.: Isothermal models for anode-supported tubular solid oxide fuel cells. Chem. Eng. Sci. 62, 4250–4267 (2007)

    Article  Google Scholar 

  13. Kanno, D., Shikazono, N., Takagi, N., Matsuzaki, K., Kasagi, N.: Evaluation of SOFC anode polarization simulation using three-dimensional microstructures reconstructed by FIB tomography. Electrochim. Acta. 56, 4015–4021 (2011)

    Article  Google Scholar 

  14. Nelson, G.J., et al.: Three-dimensional microstructural changes in the Ni–YSZ solid oxide fuel cell anode during operation. Acta Mater. 60, 3491–3500 (2012)

    Google Scholar 

  15. Huang, X., Reimert, R.: Kinetics of steam reforming of ethane on Ni/YSZ (yttria-stabilised zirconia) catalyst. Fuel 106, 380–387 (2013)

    Article  Google Scholar 

  16. Yoon, K.J., et al.: Gas transport in hydrogen electrode of solid oxide regenerative fuel cells for power generation and hydrogen production. Int. J. Hydrogen Energy 39, 3868–3878 (2014)

    Article  Google Scholar 

  17. Kishimoto, M., Lomberg, M., Ruiz-Trejo, E., Brandon, N.P.: Enhanced triple-phase boundary density in infiltrated electrodes for solid oxide fuel cells demonstrated by high-resolution tomography. J. Power Sources 266, 291–295 (2014)

    Article  Google Scholar 

  18. Brus, G., Miyawaki, K., Iwai, H., Saito, M., Yoshida, H.: Tortuosity of an SOFC anode estimated from saturation currents and a mass transport model in comparison with a real micro-structure. Solid State Ionics 265, 13–21 (2014)

    Article  Google Scholar 

  19. Shimada, H., Suzuki, T., Yamaguchi, T., Sumi, H., Hamamoto, K., Fujishiro, Y.: Challenge for lowering concentration polarization in solid oxide fuel cells. J. Power Sources 302, 53–60 (2016)

    Article  Google Scholar 

  20. Nakajo, A., et al.: Accessible triple-phase boundary length: a performance metric to account for transport pathways in heterogeneous electrochemical materials. J. Power Sources, 325, 786–800 (2016)

    Google Scholar 

  21. Lu, X., et al.: Correlation between triple phase boundary and the microstructure of Solid Oxide Fuel Cell anodes: the role of composition, porosity and Ni densification. J. Power Sources 365, 210–219 (2017)

    Article  Google Scholar 

  22. Yan, Z., He, A., Hara, S., Shikazono, N.: Modeling of solid oxide fuel cell (SOFC) electrodes from fabrication to operation: correlations between microstructures and electrochemical performances. Energy Convers. Manag. 190, 1–13 (2019)

    Article  Google Scholar 

  23. Chen, B., Xu, H., Ni, M.: Modelling of finger-like channelled anode support for SOFCs application. Sci. Bull. 61(17), 1324–1332 (2016). https://doi.org/10.1007/s11434-016-1131-x

    Article  Google Scholar 

  24. Fuller, E.N., Schettler, P.D., Giddings, J.C.: New method for prediction of binary gas-phase diffusion coefficients. Ind. Eng. Chem. 58, 18–27 (1966)

    Article  Google Scholar 

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Correspondence to Wee Choon Tan .

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Tan, W.C., Lim, E.A., Cheng, E.M., Tan, W.H. (2022). Numerical Analysis of the Effect of Pore Size Toward the Performance of Solid Oxide Fuel Cell. In: Mahyuddin, N.M., Mat Noor, N.R., Mat Sakim, H.A. (eds) Proceedings of the 11th International Conference on Robotics, Vision, Signal Processing and Power Applications. Lecture Notes in Electrical Engineering, vol 829. Springer, Singapore. https://doi.org/10.1007/978-981-16-8129-5_24

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