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Complexation with Transition Metals

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Handbook of Fullerene Science and Technology

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Abstract

The electron-deficiency fullerenes that resemble olefins are facile to react with nucleophilic transition metals to form related complexes with novel structures and unique properties. So far, mononuclear, multinuclear metal complexes and ionic salts of fullerenes have been prepared by the reaction with metal clusters. The coordination reactions of C60, higher fullerenes and metallofullerenes have usually shown very high regioselectivity to afford mono-, bis-, and even tetra- and hexa-adducts. Various crystallographic structures and spectroscopic results demonstrate that the mononuclear cluster binds to a C–C bond or a single carbon atom on the fullerene, forming η2 or η1 coordination, respectively, leading to the distortion of fullerene cage. In the multinuclear metal complexes of fullerenes, the metal clusters except for Ir4(CO)8(PMe3)4 will uniformly coordinate with the fullerenes in η2 fashion, such as the typical μ3-η2:η2:η2-C60 coordination seen in trinuclear complexes, and the binding mode could undergo a transformation to a mixed coordination of η2 and η1 through the insertion of ligands into the multinuclear clusters. Remarkably, some metal clusters act like bridges to link fullerenes, forming dimers and even organometallic fullerene polymers. In addition, the electrochemical studies of η2-C60 complexes indicate that the redox process is related to the reduction of fullerenes and the oxidation of metal clusters.

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  1. College of Chemistry and Chemical Engineering, Jinggangshan University, Ji’an, Jiangxi, China

    Changwang Pan

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  1. School of Materials Science and Eng., Huazhong University of Science and Technology., Wuhan, Hubei, China

    Xing Lu

  2. Foundation for Advancement of International Science, Tsukuba, Japan

    Takeshi Akasaka

  3. School of Materials Science and Engineering, Huangzhou University of Science and Technology, Wuhan, Hebei, China

    Zdenek Slanina

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  1. Tsukuba, Ibaraki, Japan

    Takeshi Akasaka

  2. School of Materials Science and Engineering, Huazhong University of Science and Technology, Wuhan, Hubei, P. R. China

    Takeshi Akasaka

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Pan, C. (2022). Complexation with Transition Metals. In: Lu, X., Akasaka, T., Slanina, Z. (eds) Handbook of Fullerene Science and Technology. Springer, Singapore. https://doi.org/10.1007/978-981-13-3242-5_12-1

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  • DOI: https://doi.org/10.1007/978-981-13-3242-5_12-1

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  • Print ISBN: 978-981-13-3242-5

  • Online ISBN: 978-981-13-3242-5

  • eBook Packages: Springer Reference Chemistry and Mat. ScienceReference Module Physical and Materials ScienceReference Module Chemistry, Materials and Physics

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