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Miscibility, Phase Separation, and Mechanism of Phase Separation of Epoxy/Block-Copolymer Blends

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Handbook of Epoxy Blends

Abstract

Incorporating block copolymers into epoxy systems has emerged as a versatile and effective methodology not only to enhance their mechanical properties, but also as an intriguing strategy to design advanced materials with tailored properties. Knowledge of microphase separation mechanisms operating during the development of these materials is essential due to the straight relationship between block copolymer characteristics, epoxy system formulation, and curing conditions with the final nanodomain morphology. This chapter is focused on the thermodynamic and kinetic fundamentals describing microphase separation mechanisms by which the nanodomains are obtained. Moreover, key parameters affecting phase separation mechanisms and morphologies are discussed, explaining how different material properties can be tuned by controlling the nanostructure morphology.

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Authors and Affiliations

  1. YPF Tecnología S.A., Baradero 777, CP1925, Ensenada, Buenos Aires, Argentina

    Hernan Garate & Noé J. Morales

  2. IFIBA-CONICET, LP&MC, Departamento de Física, FCEyN-UBA, Ciudad Universitaria, 1428, Ciudad Autónoma de Buenos Aires, Argentina

    Hernan Garate & Silvia Goyanes

  3. CIHIDECAR-CONICET, Departamento de Química Orgánica, FCEyN-UBA, Ciudad Universitaria, 1428, Ciudad Autónoma de Buenos Aires, Argentina

    Hernan Garate & Norma B. D’Accorso

Authors
  1. Hernan Garate
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  2. Noé J. Morales
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  3. Silvia Goyanes
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  4. Norma B. D’Accorso
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Corresponding author

Correspondence to Hernan Garate .

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Editors and Affiliations

  1. Department of Polymer Science and Rubber Technology, Cochin University of Science and Technology, Kochi, India

    Jyotishkumar Parameswaranpillai

  2. Institute for Frontier Materials, Deakin University, Geelong, Victoria, Australia

    Nishar Hameed

  3. Leibniz-Institut für Polymerforschung , Dresden, Germany

    Jürgen Pionteck

  4. Department of Chemical Engineering, National Cheng Kung University, Taiwan, China

    Eamor M. Woo

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Garate, H., Morales, N.J., Goyanes, S., D’Accorso, N.B. (2015). Miscibility, Phase Separation, and Mechanism of Phase Separation of Epoxy/Block-Copolymer Blends. In: Parameswaranpillai, J., Hameed, N., Pionteck, J., Woo, E. (eds) Handbook of Epoxy Blends. Springer, Cham. https://doi.org/10.1007/978-3-319-18158-5_31-1

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  • DOI: https://doi.org/10.1007/978-3-319-18158-5_31-1

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  • Online ISBN: 978-3-319-18158-5

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