Skip to main content

Recent Advances in the MXenes for Photocatalytic and Hydrogen Production Applications

  • Reference work entry
  • First Online:
Handbook of Smart Materials, Technologies, and Devices

Abstract

Currently, the thorny issues of environmental pollution, energy crisis, and abnormal climatic changes have turned researchers’ attention toward sustainable solar energy. Therefore, in the last couple of years, MXenes as a novel fascinating class of two-dimensional transition metal carbides, nitrides, and/or carbonitrides have been widely used to address these evils, as MXenes display numerous outstanding properties like remarkable electrical conductivity, high chemical stability, large specific surface area, good hydrophilicity, and high-reactive adsorption sites. In particular, hybrids of MXenes with semiconductors are effective photocatalysts due to their specific interface and Schottky heterojunction characteristics, which are proficient for enabling faster charge separation and a lower Schottky barrier for photocatalytic applications. Thus, MXenes have widely stirred up interdisciplinary attention and research interest in various fields especially in photocatalytic, hydrogen production, pollutants degradation, nitrogen fixation, and carbon dioxide reduction. In this chapter, the modernistic synthesis methods, structure, properties, and intricate applications of MXenes are presented in detail. Moreover, the mechanism of photocatalysis and its related characteristics are also explored. Thus, the recent advancements in MXene-based photocatalysis have been critically reviewed in this chapter. It is strongly believed that this chapter would offer productive reference for researchers in the field of MXene-based photocatalysis. Finally, challenges and revitalizing outlooks for the photocatalytic applications of MXenes are also considered and summarized.

This is a preview of subscription content, log in via an institution to check access.

Access this chapter

Subscribe and save

Springer+ Basic
$34.99 /Month
  • Get 10 units per month
  • Download Article/Chapter or eBook
  • 1 Unit = 1 Article or 1 Chapter
  • Cancel anytime
Subscribe now

Buy Now

Chapter
USD 29.95
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
eBook
USD 899.99
Price excludes VAT (USA)
  • Available as EPUB and PDF
  • Read on any device
  • Instant download
  • Own it forever
Hardcover Book
USD 1,399.99
Price excludes VAT (USA)
  • Durable hardcover edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info

Tax calculation will be finalised at checkout

Purchases are for personal use only

Institutional subscriptions

Similar content being viewed by others

References

  • Ansori B, Gogotsi Y (2019) 2D metal carbides and nitrides (MXenes): structure, properties and applications. Springer, Cham

    Book  Google Scholar 

  • Bae S, Kang Y, Khazaei M, Ohno K, Kim Y, Han M, Chang K, Raebiger H (2020) Electronic and magnetic properties of carbide MXenes – the role of electron correlations. Mater Today Adv 9:100118

    Article  Google Scholar 

  • Barsoum MW, Radovic M (2011) Elastic and mechanical properties of the MAX phases. Annu Rev Mater Res 41:195–227

    Article  Google Scholar 

  • Bhat A, Anwer S, Bhat KS, Mohideen MIH, Liao K, Qurashi A (2021) Prospects challenges and stability of 2D MXenes for clean energy conversion and storage applications. npj 2D Mater Appl 5:1–21

    Article  Google Scholar 

  • Borysiuk VN, Mochalin VN, Gogotsi Y (2015) Molecular dynamic study of the mechanical properties of two-dimensional titanium carbides Tin+1Cn (MXenes). Nanotechnology 26:265705

    Article  Google Scholar 

  • Cao S, Shen B, Tong T, Fu J, Yu J (2018) 2D/2D heterojunction of ultrathin MXene/Bi2WO6 nanosheets for improved photocatalytic CO2 reduction. Adv Funct Mater 28:1800136

    Article  Google Scholar 

  • Cheng L, Chen Q, Li J, Liu H (2020) Boosting the photocatalytic activity of CdLa2S4 for hydrogen production using Ti3C2 MXene as a co-catalyst. Appl Catal B Environ 267:118379

    Article  Google Scholar 

  • Cui C, Guo R, Ren E, Xiao H, Zhou M, Lai X, Qin Q, Jiang S, Qin W (2021) MXene-based rGO/Nb2CTx/Fe3O4 composite for high absorption of electromagnetic wave. Chem Eng J 405:126626

    Article  Google Scholar 

  • Eames C, Islam MS (2014) Ion intercalation into two-dimensional transition-metal carbides: global screening for new high-capacity battery materials. J Am Chem Soc 136:16270–16276

    Article  Google Scholar 

  • Enyashin A, Ivanovskii A (2013) Two-dimensional titanium carbonitrides and their hydroxylated derivatives: structural, electronic properties and stability of MXenes Ti3C2−xNx(OH)2 from DFTB calculations. J Solid State Chem 207:42–48

    Article  Google Scholar 

  • Fang H, Pan Y, Yin M, Xu L, Zhu Y, Pan C (2019) Facile synthesis of ternary Ti3C2–OH/ln2S3/CdS composite with efficient adsorption and photocatalytic performance towards organic dyes. J Solid State Chem 280:120981

    Google Scholar 

  • Fernandes A, Makoś P, Wang Z, Boczkaj G (2020) Synergistic effect of TiO2 photocatalytic advanced oxidation processes in the treatment of refinery effluents. Chem Eng J 391:123488

    Article  Google Scholar 

  • Foster SL, Bakovic SIP, Duda RD, Maheshwari S, Milton RD, Minteer SD, Janik MJ, Renner JN, Greenlee LF (2018) Catalysts for nitrogen reduction to ammonia. Nat Catal 1:490–500

    Article  Google Scholar 

  • Fujishima A, Honda K (1972) Electrochemical photolysis of water at a semiconductor electrode. Nature 238:37–38

    Article  Google Scholar 

  • Gao Y, Wang L, Zhou A, Li Z, Chen J, Bala H, Hu Q, Cao X (2015) Hydrothermal synthesis of TiO2/Ti3C2 nanocomposites with enhanced photocatalytic activity. Mater Lett 150:62–64

    Article  Google Scholar 

  • Gao G, O’Mullane AP, Du A (2017) 2D MXenes: a new family of promising catalysts for the hydrogen evolution reaction. ACS Catal 7:494–500

    Article  Google Scholar 

  • Ge M, Cao C, Huang J, Li S, Chen Z, Zhang K-Q, Al-Deyab S, Lai Y (2016) A review of one-dimensional TiO2 nanostructured materials for environmental and energy applications. J Mater Chem A 4:6772–6801

    Article  Google Scholar 

  • Ghidiu M, Lukatskaya MR, Zhao M-Q, Gogotsi Y, Barsoum MW (2014) Conductive two-dimensional titanium carbide “clay” with high volumetric capacitance. Nature 516:78–81

    Article  Google Scholar 

  • Gul I, Sayed M, Shah NS, Khan JA, Polychronopoulou K, Iqbal J, Rehman F (2020) Solar light responsive bismuth doped titania with Ti3+ for efficient photocatalytic degradation of flumequine: synergistic role of peroxymonosulfate. Chem Eng J 384:123255

    Article  Google Scholar 

  • Gul I, Sayed M, Shah NS, Rehman F, Khan JA, Gul S, Bibi N, Iqbal J (2021) A novel route for catalytic activation of peroxymonosulfate by oxygen vacancies improved bismuth-doped titania for the removal of recalcitrant organic contaminant. Environ Sci Pollut Res 28:1–18

    Article  Google Scholar 

  • Hao H, Zhang L, Wang W, Zeng S (2018) Modification of heterogeneous photocatalysts for selective organic synthesis. Cat Sci Technol 8:1229–1250

    Article  Google Scholar 

  • Hemanth N, Kandasubramanian B (2020) Recent advances in 2D MXenes for enhanced cation intercalation in energy harvesting applications: a review. Chem Eng J 392:123678

    Article  Google Scholar 

  • Hong L-f, Guo R-t, Yuan Y, Ji X-y, Li Z-s, Lin Z-d, Pan W-g (2020) Recent progress of two-dimensional MXenes in photocatalytic applications: a review. Mater Today Energy 18:100521

    Article  Google Scholar 

  • Jin H, Guo C, Liu X, Liu J, Vasileff A, Jiao Y, Zheng Y, Qiao S-Z (2018) Emerging two-dimensional nanomaterials for electrocatalysis. Chem Rev 118:6337–6408

    Article  Google Scholar 

  • Jin L, Chai L, Yang W, Wang H, Zhang L (2020) Two-dimensional titanium carbides (Ti3C2Tx) functionalized by poly (m-phenylenediamine) for efficient adsorption and reduction of hexavalent chromium. Int J Environ Res Public Health 17:167

    Article  Google Scholar 

  • Khan S, Han C, Sayed M, Sohail M, Jan S, Sultana S, Khan HM, Dionysiou DD (2019) Exhaustive photocatalytic lindane degradation by combined simulated solar light-activated nanocrystalline TiO2 and inorganic oxidants. Catalysts 9:425

    Article  Google Scholar 

  • Khan JA, Sayed M, Shah NS, Khan S, Zhang Y, Boczkaj G, Khan HM, Dionysiou DD (2020) Synthesis of eosin modified TiO2 film with co-exposed {001} and {101} facets for photocatalytic degradation of para-aminobenzoic acid and solar H2 production. Appl Catal B Environ 265:118557

    Article  Google Scholar 

  • Khataee A, Farshchi ME, Fathinia M, Aghdasinia H (2020) Photocatalytic ozonation process for degradation of an anthelmintic drug using ceramic coated TiO2 NPs: CFD simulation coupling with kinetic mechanisms. Process Saf Environ Prot 141:37–48

    Article  Google Scholar 

  • Khazaei M, Arai M, Sasaki T, Chung CY, Venkataramanan NS, Estili M, Sakka Y, Kawazoe Y (2013) Novel electronic and magnetic properties of two-dimensional transition metal carbides and nitrides. Adv Funct Mater 23:2185–2192

    Article  Google Scholar 

  • Li Y, Yin Z, Ji G, Liang Z, Xue Y, Guo Y, Tian J, Wang X, Cui H (2019a) 2D/2D/2D heterojunction of Ti3C2 MXene/MoS2 nanosheets/TiO2 nanosheets with exposed (001) facets toward enhanced photocatalytic hydrogen production activity. Appl Catal B Environ 246:12–20

    Article  Google Scholar 

  • Li Y, Ding L, Guo Y, Liang Z, Cui H, Tian J (2019b) Boosting the photocatalytic ability of g-C3N4 for hydrogen production by Ti3C2 MXene quantum dots. ACS Appl Mater Interfaces 11:41440–41447

    Article  Google Scholar 

  • Li J, Zhao L, Wang S, Li J, Wang G, Wang J (2020) In situ fabrication of 2D/3D g-C3N4/Ti3C2 (MXene) heterojunction for efficient visible-light photocatalytic hydrogen evolution. Appl Surf Sci 515:145922

    Article  Google Scholar 

  • Li X, Ran F, Yang F, Long J, Shao L (2021a) Advances in MXene films: synthesis, assembly, and applications. Transactions of Tianjin University 27:1–31

    Article  Google Scholar 

  • Li X, Bai Y, Shi X, Su N, Nie G, Zhang R, Nie H, Ye L (2021b) Applications of MXene (Ti3C2Tx) in photocatalysis: a review. Mater Adv 2:1570–1594

    Article  Google Scholar 

  • Ling Z, Ren CE, Zhao M-Q, Yang J, Giammarco JM, Qiu J, Barsoum MW, Gogotsi Y (2014) Flexible and conductive MXene films and nanocomposites with high capacitance. Proc Natl Acad Sci U S A 111:16676–16681

    Article  Google Scholar 

  • Lipatov A, Alhabeb M, Lukatskaya MR, Boson A, Gogotsi Y, Sinitskii A (2016) Effect of synthesis on quality, electronic properties and environmental stability of individual monolayer Ti3C2 MXene flakes. Adv Electron Mater 2:1600255

    Article  Google Scholar 

  • Liu N, Lu N, Yu H, Chen S, Quan X (2020) Efficient day-night photocatalysis performance of 2D/2D Ti3C2/Porous g-C3N4 nanolayers composite and its application in the degradation of organic pollutants. Chemosphere 246:125760

    Article  Google Scholar 

  • Mallakpour S, Behranvand V, Hussain CM (2021) MXenes-based materials: structure, synthesis, and various applications. Ceram Int 47(19):26585–26597

    Article  Google Scholar 

  • Naguib M, Kurtoglu M, Presser V, Lu J, Niu J, Heon M, Hultman L, Gogotsi Y, Barsoum MW (2011) Two-dimensional nanocrystals produced by exfoliation of Ti3AlC2. Adv Mater 23:4248–4253

    Article  Google Scholar 

  • Nguyen TP, Nguyen DMT, Le HK, Vo D-VN, Lam SS, Varma RS, Shokouhimehr M, Nguyen CC, Van Le Q (2020a) MXenes: applications in electrocatalytic, photocatalytic hydrogen evolution reaction and CO2 reduction. Mol Catal 486:110850

    Article  Google Scholar 

  • Nguyen V-H, Nguyen B-S, Hu C, Nguyen CC, Nguyen DLT, Nguyen Dinh MT, Vo D-VN, Trinh QT, Shokouhimehr M, Hasani A (2020b) Novel architecture titanium carbide (Ti3C2Tx) MXene cocatalysts toward photocatalytic hydrogen production: a mini-review. Nanomaterials 10:602

    Article  Google Scholar 

  • Nishan U, Bashir F, Muhammad N, Khan N, Rahim A, Shah M, Nazir R, Sayed M (2019) Ionic liquid as a moderator for improved sensing properties of TiO2 nanostructures for the detection of acetone biomarker in diabetes mellitus. J Mol Liq 294:111681

    Article  Google Scholar 

  • Pang J, Mendes RG, Bachmatiuk A, Zhao L, Ta HQ, Gemming T, Liu H, Liu Z, Rummeli MH (2019) Applications of 2D MXenes in energy conversion and storage systems. Chem Soc Rev 48:72–133

    Article  Google Scholar 

  • Pei D, Luan J (2012) Development of visible light-responsive sensitized photocatalysts. Int J Photoenergy 2012:262831

    Article  Google Scholar 

  • Peng C, Yang X, Li Y, Yu H, Wang H, Peng F (2016) Hybrids of two-dimensional Ti3C2 and TiO2 exposing {001} facets toward enhanced photocatalytic activity. ACS Appl Mater Interfaces 8:6051–6060

    Article  Google Scholar 

  • Qiu W, Xie X-Y, Qiu J, Fang W-H, Liang R, Ren X, Ji X, Cui G, Asiri AM, Cui G (2018) High-performance artificial nitrogen fixation at ambient conditions using a metal-free electrocatalyst. Nat Commun 9:1–8

    Article  Google Scholar 

  • Ran J, Gao G, Li F-T, Ma T-Y, Du A, Qiao S-Z (2017) Ti3C2 MXene co-catalyst on metal sulfide photo-absorbers for enhanced visible-light photocatalytic hydrogen production. Nat Commun 8:1–10

    Article  Google Scholar 

  • Rosca V, Duca M, de Groot MT, Koper MT (2009) Nitrogen cycle electrocatalysis. Chem Rev 109:2209–2244

    Article  Google Scholar 

  • Sayed M, Shah LA, Khan JA, Shah NS, Nisar J, Khan HM, Zhang P, Khan AR (2016) Efficient photocatalytic degradation of norfloxacin in aqueous media by hydrothermally synthesized immobilized TiO2/Ti films with exposed {001} facets. Chem A Eur J 120:9916–9931

    Google Scholar 

  • Sayed M, Khan JA, Shah LA, Shah NS, Shah F, Khan HM, Zhang P, Arandiyan H (2018a) Solar light responsive poly (vinyl alcohol)-assisted hydrothermal synthesis of immobilized TiO2/Ti film with the addition of peroxymonosulfate for photocatalytic degradation of ciprofloxacin in aqueous media: a mechanistic approach. J Phys Chem C 122:406–421

    Article  Google Scholar 

  • Sayed M, Arooj A, Shah NS, Khan JA, Shah LA, Rehman F, Arandiyan H, Khan AM, Khan AR (2018b) Narrowing the band gap of TiO2 by co-doping with Mn2+ and Co2+ for efficient photocatalytic degradation of enoxacin and its additional peroxidase like activity: a mechanistic approach. J Mol Liq 272:403–412

    Article  Google Scholar 

  • Sayed M, Khan A, Rauf S, Shah NS, Rehman F, Al-Kahtani AA, Khan JA, Iqbal J, Boczkaj G, Gul I (2020) Bismuth-doped nano zerovalent iron: a novel catalyst for chloramphenicol degradation and hydrogen production. ACS Omega 5:30610–30624

    Article  Google Scholar 

  • Sui J, Chen X, Li Y, Peng W, Zhang F, Fan X (2021) MXene derivatives: synthesis and applications in energy convention and storage. RSC Adv 11:16065–16082

    Article  Google Scholar 

  • Sun Y, Li Y (2021) Potential environmental applications of MXenes: a critical review. Chemosphere 271:129578

    Article  Google Scholar 

  • Tan C, Cao X, Wu X-J, He Q, Yang J, Zhang X, Chen J, Zhao W, Han S, Nam G-H (2017) Recent advances in ultrathin two-dimensional nanomaterials. Chem Rev 117:6225–6331

    Article  Google Scholar 

  • Wang C, Shen J, Chen R, Cao F, Jin B (2020) Self-assembled BiOCl/Ti3C2Tx composites with efficient photo-induced charge separation activity for photocatalytic degradation of p-nitrophenol. Appl Surf Sci 519:146175

    Article  Google Scholar 

  • Wu S, Su Y, Zhu Y, Zhang Y, Zhu M (2020) In-situ growing Bi/BiOCl microspheres on Ti3C2 nanosheets for upgrading visible-light-driven photocatalytic activity. Appl Surf Sci 520:146339

    Article  Google Scholar 

  • Xu C, Wang L, Liu Z, Chen L, Guo J, Kang N, Ma X-L, Cheng H-M, Ren W (2015) Large-area high-quality 2D ultrathin Mo2C superconducting crystals. Nat Mater 14:1135–1141

    Article  Google Scholar 

  • Xu X, Sun B, Liang Z, Cui H, Tian J (2020) High-performance electrocatalytic conversion of N2 to NH3 using 1T-MoS2 anchored on Ti3C2 MXene under ambient conditions. ACS Appl Mater Interfaces 12:26060–26067

    Article  Google Scholar 

  • Yang XH, Li Z, Sun C, Yang HG, Li C (2011) Hydrothermal stability of {001} faceted anatase TiO2. Chem Mater 23:3486–3494

    Article  Google Scholar 

  • Yang C, Li Q, Xia Y, Lv K, Li M (2019) Enhanced visible-light photocatalytic CO2 reduction performance of Znln2S4 microspheres by using CeO2 as cocatalyst. Appl Surf Sci 464:388–395

    Article  Google Scholar 

  • Yang C, Tan Q, Li Q, Zhou J, Fan J, Li B, Sun J, Lv K (2020) 2D/2D Ti3C2 MXene/g-C3N4 nanosheets heterojunction for high efficient CO2 reduction photocatalyst: dual effects of urea. Appl Catal B Environ 268:118738

    Article  Google Scholar 

  • Yang C, Huang H, He H, Yang L, Jiang Q, Li W (2021a) Recent advances in MXene-based nanoarchitectures as electrode materials for future energy generation and conversion applications. Coord Chem Rev 435:213806

    Article  Google Scholar 

  • Yang L, Kan D, Dall’Agnese C, Dall’Agnese Y, Wang B, Jena AK, Wei Y, Chen G, Wang X-F, Gogotsi Y (2021b) Performance improvement of MXene-based perovskite solar cells upon property transition from metallic to semiconductive by oxidation of Ti3C2Tx in air. J Mater Chem A 9:5016–5025

    Article  Google Scholar 

  • Ye M, Wang X, Liu E, Ye J, Wang D (2018) Boosting the photocatalytic activity of P25 for carbon dioxide reduction by using a surface-alkalinized titanium carbide MXene as cocatalyst. ChemSusChem 11:1606–1611

    Article  Google Scholar 

  • Zeng Z, Yan Y, Chen J, Zan P, Tian Q, Chen P (2019) Boosting the photocatalytic ability of Cu2O nanowires for CO2 conversion by MXene quantum dots. Adv Funct Mater 29:1806500

    Article  Google Scholar 

  • Zhang H, Zhu C, Cao J, Tang Q, Li M, Kang P, Shi C, Ma M (2018) Ultrasonic-assisted synthesis of 2D α-Fe2O3@g-C3N4 composite with excellent visible light photocatalytic activity. Catalysts 8:457

    Article  Google Scholar 

  • Zhao J, Zhang L, Xie X-Y, Li X, Ma Y, Liu Q, Fang W-H, Shi X, Cui G, Sun X (2018) Ti3C2Tx (T = F, OH) MXene nanosheets: conductive 2D catalysts for ambient electrohydrogenation of N2 to NH3. J Mater Chem A 6:24031–24035

    Article  Google Scholar 

  • Zheng M, Guo R, Liu Z, Wang B, Meng L, Li F, Li T, Luo Y (2018) MoS2 intercalated p-Ti3C2 anode materials with sandwich-like three dimensional conductive networks for lithium-ion batteries. J Alloys Compd 735:1262–1270

    Article  Google Scholar 

  • Zheng S, Li S, Mei Z, Hu Z, Chu M, Liu J, Chen X, Pan F (2019) Electrochemical nitrogen reduction reaction performance of single-boron catalysts tuned by MXene substrates. J Phys Chem Lett 10:6984–6989

    Article  Google Scholar 

  • Zhong Q, Li Y, Zhang G (2020) Two-dimensional MXene-based and MXene-derived photocatalysts: recent developments and perspectives. Chem Eng J 409:128099

    Article  Google Scholar 

  • Zhu J, Ha E, Zhao G, Zhou Y, Huang D, Yue G, Hu L, Sun N, Wang Y, Lee LYS (2017) Recent advance in MXenes: a promising 2D material for catalysis, sensor and chemical adsorption. Coord Chem Rev 352:306–327

    Article  Google Scholar 

  • Zhuang Y, Liu Y, Meng X (2019) Fabrication of TiO2 nanofibers/MXene Ti3C2 nanocomposites for photocatalytic H2 evolution by electrostatic self-assembly. Appl Surf Sci 496:143647

    Article  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Murtaza Sayed .

Editor information

Editors and Affiliations

Rights and permissions

Reprints and permissions

Copyright information

© 2022 The Author(s), under exclusive license to Springer Nature Switzerland AG

About this entry

Check for updates. Verify currency and authenticity via CrossMark

Cite this entry

Gul, I., Sayed, M., Bushra, M., Gohar, F., Khan, Q. (2022). Recent Advances in the MXenes for Photocatalytic and Hydrogen Production Applications. In: Hussain, C.M., Di Sia, P. (eds) Handbook of Smart Materials, Technologies, and Devices. Springer, Cham. https://doi.org/10.1007/978-3-030-84205-5_81

Download citation

Publish with us

Policies and ethics