Abstract
With the rapid industrialization and urbanization, different kinds of undesirable and harmful heavy metal ions in large amounts are discharged into the water environment. As well known, the adsorption technique is proven to be effective in removing heavy metals from water. Due to its earth-abundant, environmentally friendly, and cost-effective properties, iron oxide has been widely used as an adsorbent in water remediation. Therefore, this chapter will give an overview of the application of iron oxide nanomaterials for the removal of heavy metals. It mainly includes the following contents. Firstly, the typical iron oxide nanomaterials such as FeOOH, Fe2O3, and Fe3O4 will be introduced, including the composition, structure, preparation method, surface modification strategy, etc. Secondly, the adsorption kinetics and underlying mechanism will be summarized based on the different iron oxide nanomaterials. Finally, the actual application of iron oxide nanomaterials in the removal of heavy metals is introduced, of course, the potential applications and further challenges are also discussed. The aim of this handbook is to outline the recent development, history of iron oxide nanomaterials, and their application for heavy metals treatment.
Access this chapter
Tax calculation will be finalised at checkout
Purchases are for personal use only
Similar content being viewed by others
References
Zhang X, Huang Q, Deng F, Huang H, Wan Q, Liu M, Wei Y (2017) Mussel-inspired fabrication of functional materials and their environmental applications: progress and prospects. Appl Mater Today 7:222–238
Bali M, Tlili H (2019) Removal of heavy metals from wastewater using infiltration-percolation process and adsorption on activated carbon. Int J Environ Sci Technol 16(1):249–258
Bharath G, Ponpandian N (2015) Hydroxyapatite nanoparticles on dendritic α-Fe2O3 hierarchical architectures for a heterogeneous photocatalyst and adsorption of Pb(II) ions from industrial wastewater. RSC Adv 5(103):84685–84693
Nassar NN (2010) Rapid removal and recovery of Pb(II) from wastewater by magnetic nanoadsorbents. J Hazard Mater 184(1–3):538–546
Shen Y, Tang J, Nie Z, Wang Y, Ren Y, Zuo L (2009) Tailoring size and structural distortion of Fe3O4 nanoparticles for the purification of contaminated water. Bioresour Technol 100(18):4139–4146
Schwertmann U, Cornell RM (2008) Iron Oxides in the Laboratory: Preparation and Characterisation. 2nd Edition, Wiley-VCH, New York, 15
Nassar NN (2012) Iron oxide nanoadsorbents for removal of various pollutants from wastewater: an overview. In: Application of adsorbents for water pollution control, pp 81–118
Li Y, Liao H, Qian Y (1998) Hydrothermal synthesis of ultrafine α-Fe2O3 and Fe3O4 powders. Mater Res Bull 33(6):841–844
Dave PN, Chopda LV (2014) Application of iron oxide nanomaterials for the removal of heavy metals. J Nanotechnol. https://doi.org/10.1155/2014/398569
Joseyphus RJ, Kodama D, Matsumoto T, Sato Y, Jeyadevan B, Tohji K (2007) Role of polyol in the synthesis of Fe particles. J Magn Magn Mater 310(2-part-P3):2393–2395
Cai W, Wan J (2007) Facile synthesis of superparamagnetic magnetite nanoparticles in liquid polyols. J Colloid Interface Sci 305(2):366–370
Kim EH, Lee HS, Kwak BK, Kim B-K (2005) Synthesis of ferrofluid with magnetic nanoparticles by sonochemical method for MRI contrast agent. J Magn Magn Mater 289:328–330
Yunfeng L, Yanjie H, Guangjian H, Chunzhong L (2013) Metallic iron nanoparticles: Flame synthesis, characterization and magnetic properties. Particuology 11:460–467
Cui H, Liu Y, Ren W (2013) Structure switch between α-Fe2O3, γ-Fe2O3 and Fe3O4 during the large scale and low temperature sol–gel synthesis of nearly monodispersed iron oxide nanoparticles. Adv Powder Technol 24(1):93–97
Fajaroh F, Setyawan H, Widiyastuti W, Winardi S (2012) Synthesis of magnetite nanoparticles by surfactant-free electrochemical method in an aqueous system. Adv Powder Technol 23(3):328–333
Bowles WJF (2003) The iron oxides: structure, properties reactions occurrence and uses. Mineral Mag 61(408):740–741
Uddin MK (2017) A review on the adsorption of heavy metals by clay minerals, with special focus on the past decade. Chem Eng J 308:438–462
Swedlund PJ, Webster JG, Miskelly GM (2009) Goethite adsorption of Cu (II), Pb (II), Cd (II), and Zn (II) in the presence of sulfate: properties of the ternary complex. Geochim Cosmochim Acta 73(6):1548–1562
Eigen M, Tamm UK (2015) Schallabsorption in Elektrolytlösungen als Folge chemischer Relaxation II. Meßergebnisse und Relaxationsmechanismen für 2—2-wertige. Elektrolyte 66(2):107–121
Xie J, Gu X, Tong F, Zhao Y, Tan Y (2015) Surface complexation modeling of Cr (VI) adsorption at the goethite–water interface. J Colloid Interface Sci 455:55–62
Mamindy-Pajany Y, Hurel C, Marmier N, Roméo M (2009) Arsenic adsorption onto hematite and goethite. C R Chim 12(8):876–881
Jiangbo S, Shanbin GWCHM (2006) A study of chromium adsorption on natural goethite biomineralized with iron bacteria. Acta Geol Sin (English edition) 80(4):597–603
Weng L, Van Riemsdijk WH, Hiemstra T (2008) Cu2+ and Ca2+ adsorption to goethite in the presence of fulvic acids. Geochim Cosmochim Acta 72(24):5857–5870
Dickson D, Liu G, Cai Y (2017) Adsorption kinetics and isotherms of arsenite and arsenate on hematite nanoparticles and aggregates. J Environ Manag 186:261–267
Liu Z, Yu R, Dong Y, Li W, Zhou W (2016) Preparation of α-Fe2O3 hollow spheres, nanotubes, nanoplates and nanorings as highly efficient Cr (vi) adsorbents. RSC Adv 6(86):82854–82861
Bereket G, Arog AZ, Özel MZ (1997) Removal of Pb (II), Cd (II), Cu (II), and Zn (II) from aqueous solutions by adsorption on bentonite. J Colloid Interface Sci 187(2):338–343
Kefeni KK, Msagati TA, Nkambule TT, Mamba BB (2018) Synthesis and application of hematite nanoparticles for acid mine drainage treatment. J Environ Chem Eng 6(2):1865–1874
Su H, Ye Z, Hmidi N (2017) High-performance iron oxide–graphene oxide nanocomposite adsorbents for arsenic removal. Colloids Surf A Physicochem Eng Asp 522:161–172
Ravindranath R, Roy P, Periasamy AP, Chen Y-W, Liang C-T, Chang H-T (2017) Fe2O3/Al2O3 microboxes for efficient removal of heavy metal ions. New J Chem 41(15):7751–7757
Shipley HJ, Engates KE, Grover VA (2013) Removal of Pb (II), Cd (II), Cu (II), and Zn (II) by hematite nanoparticles: effect of sorbent concentration, pH, temperature, and exhaustion. Environ Sci Pollut Res 20(3):1727–1736
Mahapatra A, Mishra B, Hota G (2013) Electrospun Fe2O3–Al2O3 nanocomposite fibers as efficient adsorbent for removal of heavy metal ions from aqueous solution. J Hazard Mater 258:116–123
Verdugo EM, Xie Y, Baltrusaitis J, Cwiertny DM (2016) Hematite decorated multi-walled carbon nanotubes (α-Fe2O3/MWCNTs) as sorbents for Cu (II) and Cr (VI): comparison of hybrid sorbent performance to its nanomaterial building blocks. RSC Adv 6(102):99997–100007
Hu J, Chen G, Lo IM (2005) Removal and recovery of Cr (VI) from wastewater by maghemite nanoparticles. Water Res 39(18):4528–4536
Rajput S, Singh LP, Pittman CU Jr, Mohan D (2017) Lead (Pb2+) and copper (Cu2+) remediation from water using superparamagnetic maghemite (γ-Fe2O3) nanoparticles synthesized by Flame Spray Pyrolysis (FSP). J Colloid Interface Sci 492:176–190
Chávez-Guajardo AE, Medina-Llamas JC, Maqueira L, Andrade CA, Alves KG, de Melo CP (2015) Efficient removal of Cr (VI) and Cu (II) ions from aqueous media by use of polypyrrole/maghemite and polyaniline/maghemite magnetic nanocomposites. Chem Eng J 281:826–836
Predescu A, Nicolae A (2012) Adsorption of Zn, Cu and Cd from waste waters by means of maghemite nanoparticles. UPB Bull Sci Series B Chem Mater Sci 74(1):255–264
Yuan P, Fan M, Yang D, He H, Liu D, Yuan A, Zhu J, Chen T (2009) Montmorillonite-supported magnetite nanoparticles for the removal of hexavalent chromium [Cr (VI)] from aqueous solutions. J Hazard Mater 166(2–3):821–829
Maity D, Agrawal D (2007) Synthesis of iron oxide nanoparticles under oxidizing environment and their stabilization in aqueous and non-aqueous media. J Magn Magn Mater 308(1):46–55
Warner CL, Addleman RS, Cinson AD, Droubay TC, Engelhard MH, Nash MA, Yantasee W, Warner MG (2010) High-performance, superparamagnetic, nanoparticle-based heavy metal sorbents for removal of contaminants from natural waters. ChemSusChem 3(6):749–757
Mahmoud ME, Abdelwahab MS, Abdou AE (2016) Enhanced removal of lead and cadmium from water by Fe3O4-cross linked-O-phenylenediamine nano-composite. Sep Sci Technol 51(2):237–247
Jamshidiyan M, Shirani A, Alahyarizadeh G (2017) Solvothermal synthesis and characterization of magnetic Fe3O4 nanoparticle by different sodium salt sources. Mater Sci-Pol 35(1):50–57
Giraldo L, Erto A, Moreno-Piraján JC (2013) Magnetite nanoparticles for removal of heavy metals from aqueous solutions: synthesis and characterization. Adsorption 19(2–4):465–474
Mayo J, Yavuz C, Yean S, Cong L, Shipley H, Yu W, Falkner J, Kan A, Tomson M, Colvin V (2007) The effect of nanocrystalline magnetite size on arsenic removal. Sci Technol Adv Mater 8(1–2):71–75
Zhang C, Mo Z, Zhang P, Feng C, Guo R (2013) Facile synthesis of porous carbon@ Fe3O4 composites and their applications in wastewater treatment. Mater Lett 106:107–110
Badruddoza AZM, Shawon ZBZ, Rahman MT, Hao KW, Hidajat K, Uddin MS (2013) Ionically modified magnetic nanomaterials for arsenic and chromium removal from water. Chem Eng J 225:607–615
Huang S-H, Chen D-H (2009) Rapid removal of heavy metal cations and anions from aqueous solutions by an amino-functionalized magnetic nano-adsorbent. J Hazard Mater 163(1):174–179
Adeli M, Yamini Y, Faraji M (2017) Removal of copper, nickel and zinc by sodium dodecyl sulphate coated magnetite nanoparticles from water and wastewater samples. Arab J Chem 10:S514–S521
Yavuz CT, Mayo J, Suchecki C, Wang J, Ellsworth AZ, D’Couto H, Quevedo E, Prakash A, Gonzalez L, Nguyen C (2010) Pollution magnet: nano-magnetite for arsenic removal from drinking water. Environ Geochem Health 32(4):327–334
Saharan P, Chaudhary GR, Mehta S, Umar A (2014) Removal of water contaminants by iron oxide nanomaterials. J Nanosci Nanotechnol 14(1):627–643
Wang L, Li J, Jiang Q, Zhao L (2012) Water-soluble Fe3O4 nanoparticles with high solubility for removal of heavy-metal ions from waste water. Dalton Trans 41(15):4544–4551
Singh S, Barick K, Bahadur D (2011) Surface engineered magnetic nanoparticles for removal of toxic metal ions and bacterial pathogens. J Hazard Mater 192(3):1539–1547
Qiu H, Zhang S, Pan B, Zhang W, Lv L (2013) Oxalate-promoted dissolution of hydrous ferric oxide immobilized within nanoporous polymers: effect of ionic strength and visible light irradiation. Chem Eng J 232:167–173
Zhang Y, Li Z (2017) Heavy metals removal using hydrogel-supported nanosized hydrous ferric oxide: synthesis, characterization, and mechanism. Sci Total Environ 580:776–786
Xiong W, Peng J (2008) Development and characterization of ferrihydrite-modified diatomite as a phosphorus adsorbent. Water Res 42(19):4869–4877
Tamaura Y, Katsura T, Rojarayanont S, Yoshida T, Abe H (1991) Ferrite process; heavy metal ions treatment system. Water Sci Technol 23(10–12):1893–1900
Author information
Authors and Affiliations
Corresponding author
Editor information
Editors and Affiliations
Rights and permissions
Copyright information
© 2021 Springer Nature Switzerland AG
About this entry
Cite this entry
Luo, T., Yang, C., Tian, X., Luo, W., Nie, Y., Wang, Y. (2021). Application of Iron Oxide Nanomaterials for the Removal of Heavy Metals. In: Kharissova, O.V., Torres-Martínez, L.M., Kharisov, B.I. (eds) Handbook of Nanomaterials and Nanocomposites for Energy and Environmental Applications. Springer, Cham. https://doi.org/10.1007/978-3-030-36268-3_76
Download citation
DOI: https://doi.org/10.1007/978-3-030-36268-3_76
Published:
Publisher Name: Springer, Cham
Print ISBN: 978-3-030-36267-6
Online ISBN: 978-3-030-36268-3
eBook Packages: Chemistry and Materials ScienceReference Module Physical and Materials ScienceReference Module Chemistry, Materials and Physics