Abstract
Advanced oxidation processes (AOPs) involving the production of strongly oxidizing active substances for elimination of various organic pollutants have shown great potential in current water purification. Among them, especially the heterogeneous nanocatalysis based on nanotechnology and nanomaterials provides a promising alternative due to the adjustable physicochemical properties for enhanced catalytic efficiency. Therefore, in this handbook, we will focus on and summarize the current heterogeneous nanocatalysis water treatment technologies according to our previous work and the latest literature. The characteristics of typical AOPs including photocatalysis, Fenton catalysis, persulfate activation, and ozone oxidation are firstly introduced briefly. Secondly, a comprehensive overview of the used nanotechnology and nanomaterials will be summarized such as their physiochemical characterization, catalytic activity, reaction mechanism, and the key factors that affect their performance. Finally, the application of typical heterogeneous AOPs in practical water purification and the present engineering projects will be given. We think this handbook can provide the quick reference for researchers of the historical development, research status, and development trend of AOPs for water treatment using nanomaterials.
Similar content being viewed by others
References
Neyens E, Baeyens J (2003) A review of classic Fenton’s peroxidation as an advanced oxidation technique. J Hazard Mater 98(1–3):33–50
Jin H, Tian X, Nie Y, Zhou Z, Yang C, Li Y, Lu L (2017) Oxygen vacancy promoted heterogeneous Fenton-like degradation of ofloxacin at pH 3.2–9.0 by Cu substituted magnetic Fe3O4@FeOOH nanocomposite. Environ Sci Technol 51(21):12699–12706
Zhu Y, Zhu R, Xi Y, Zhu J, Zhu G, He H (2019) Strategies for enhancing the heterogeneous Fenton catalytic reactivity: a review. Appl Catal B Environ 255:117739
Jin Q, Kang J, Chen Q, Shen J, Guo F, Chen Z (2019) Efficiently enhanced Fenton-like reaction via Fe complex immobilized on silica particles for catalytic hydrogen peroxide degradation of 2,4-dichlorophenol. Appl Catal B Environ 268:118453
Xu X, Chen W, Zong S, Ren X, Liu D (2019) Magnetic clay as catalyst applied to organics degradation in a combined adsorption and Fenton-like process. Chem Eng J 373:140–149
Dai C, Tian X, Nie Y, Lin H-M, Yang C, Han B, Wang Y (2018) Surface facet of CuFeO2 nanocatalyst: a key parameter for H2O2 activation in Fenton-like reaction and organic pollutant degradation. Environ Sci Technol 52(11):6518–6525
Liao X, Wang F, Wang F, Cai Y, Yao Y, Teng B-T, Hao Q, Shuxiang L (2019) Synthesis of (100) surface oriented MIL-88A-Fe with rod-like structure and its enhanced Fenton-like performance for phenol removal. Appl Catal B Environ 259:118064
Niu H, He D, Yang Y, Lv H, Cai Y, Liang Y (2019) Long-lasting activity of Fe0-C internal microelectrolysis-Fenton system assisted by Fe@C-montmorillonites nanocomposites. Appl Catal B Environ 256:117820
Yang Z, Gong XB, Peng L, Yang D, Liu Y (2018) Zn0-CNTs-Fe3O4 catalytic in situ generation of H2O2 for heterogeneous Fenton degradation of 4-chlorophenol. Chemosphere 208:665–673
Yang Z, Zhang X, Pu S, Ni R, Lin Y, Liu Y (2019) Novel Fenton-like system (Mg/Fe-O2) for degradation of 4-chlorophenol. Environ Pollut 250:906–913
Ling L, Liu Y, Pan D, Lyu W, Xu X, Xiang X, Lyu M, Zhu L (2020) Catalytic detoxification of pharmaceutical wastewater by Fenton-like reaction with activated alumina supported CoMnAl composite metal oxides catalyst. Chem Eng J 381:122607
Wang H, Jing M, Wu Y, Chen W, Ran Y (2018) Effective degradation of phenol via Fenton reaction over CuNiFe layered double hydroxides. J Hazard Mater 353:53–61
Tian X, Jin H, Nie Y, Zhou Z, Yang C, Li Y, Wang Y (2017) Heterogeneous Fenton-like degradation of ofloxacin over a wide pH range of 3.6–10.0 over modified mesoporous iron oxide. Chem Eng J 328:397–405
Wang N, Zhu L, Lei M, She Y, Cao M, Tang H (2011) Ligand-induced drastic enhancement of catalytic activity of nano-BiFeO3 for oxidative degradation of bisphenol A. ACS Catal 1(10):1193–1202
Sun H, Xie G, He D, Zhang L (2019) Ascorbic acid promoted magnetite Fenton degradation of alachlor: mechanistic insights and kinetic modeling. Appl Catal B Environ 267:118383
Xing M, Xu W, Dong C, Bai Y, Zeng J, Zhou Y, Zhang J, Yin Y (2018) Metal sulfides as excellent co-catalysts for H2O2 decomposition in advanced oxidation processes. Chem 4(6):1359–1372
Tong M, Liu F, Dong Q, Ma Z, Liu W (2020) Magnetic Fe3O4-deposited flower-like MoS2 nanocomposites for the Fenton-like Escherichia coli disinfection and diclofenac degradation. J Hazard Mater 385:121604
Zhang N, Xue C, Wang K, Fang Z (2020) Efficient oxidative degradation of fluconazole by a heterogeneous Fenton process with Cu-V bimetallic catalysts. Chem Eng J 380:122516
[Online]. http://www.mcwongtech.com/en/CasesDetail.aspx?id=2074&cid=11
Huang J, Zhang H (2019) Mn-based catalysts for sulfate radical-based advanced oxidation processes: a review. Environ Int 133(Pt A):105141
Tian X, Gao P, Nie Y, Yang C, Zhou Z, Li Y, Wang Y (2017) A novel singlet oxygen involved peroxymonosulfate activation mechanism for degradation of ofloxacin and phenol in water. Chem Commun (Camb) 53(49):6589–6592
Tian N, Tian X, Nie Y, Yang C, Zhou Z, Li Y (2018) Biogenic manganese oxide: An efficient peroxymonosulfate activation catalyst for tetracycline and phenol degradation in water. Chem Eng J 352:469–476
Dong X, Ren B, Sun Z, Li C, Zhang X, Kong M, Zheng S, Dionysiou DD (2019) Monodispersed CuFe2O4 nanoparticles anchored on natural kaolinite as highly efficient peroxymonosulfate catalyst for bisphenol a degradation. Appl Catal B Environ 253:206–217
Zhu S, Xu Y, Zhu Z, Liu Z, Wang W (2020) Activation of peroxymonosulfate by magnetic Co-Fe/SiO2 layered catalyst derived from iron sludge for ciprofloxacin degradation. Chem Eng J 384:123298
Zhang A-Y, He Y-Y, Chen Y-P, Feng J-W, Huang N-H, Lian F (2018) Degradation of organic pollutants by Co3O4-mediated peroxymonosulfate oxidation: roles of high-energy {001}-exposed TiO2 support. Chem Eng J 334:1430–1439
Xiao S, Cheng M, Zhong H, Liu Z, Liu Y, Yang X, Liang Q (2020) Iron-mediated activation of persulfate and peroxymonosulfate in both homogeneous and heterogeneous ways: a review. Chem Eng J 384:123265
He Y, Zhang J, Zhou H, Yao G, Lai B (2020) Synergistic multiple active species for the degradation of sulfamethoxazole by peroxymonosulfate in the presence of CuO@FeOx@Fe0. Chem Eng J 380:122568
Shah NS, Khan JA, Sayed M, Khan ZUH, Iqbal J, Imran M, Murtaza B, Zakir A, Polychronopoulou K (2020) Nano zerovalent zinc catalyzed peroxymonosulfate based advanced oxidation technologies for treatment of chlorpyrifos in aqueous solution: a semi-pilot scale study. J Clean Prod 246:119032
Ye Q, Xu H, Zhang J, Wang Q, Zhou P, Wang Y, Huang X, Huo X, Liu C, Lu J (2020) Enhancement of peroxymonosulfate activation for antibiotics removal by nano zero valent tungsten induced Cu(II)/Cu(I) redox cycles. Chem Eng J 382:123054
Li W, Li Y, Zhang D, Lan Y, Guo J (2020) CuO-Co3O4@CeO2 as a heterogeneous catalyst for efficient degradation of 2,4-dichlorophenoxyacetic acid by peroxymonosulfate. J Hazard Mater 381:121209
Tian N, Tian X, Nie Y, Yang C, Zhou Z, Li Y (2019) Enhanced 2, 4-dichlorophenol degradation at pH 3-11 by peroxymonosulfate via controlling the reactive oxygen species over Ce substituted 3D Mn2O3. Chem Eng J 355:448–456
Ding M, Chen W, Xu H, Shen Z, Lin T, Hu K, Lu CH, Xie Z (2020) Novel alpha-Fe2O3/MXene nanocomposite as heterogeneous activator of peroxymonosulfate for the degradation of salicylic acid. J Hazard Mater 382:121064
Sun P, Liu H, Feng M, Guo L, Zhai Z, Fang Y, Zhang X, Sharma VK (2019) Nitrogen-sulfur co-doped industrial graphene as an efficient peroxymonosulfate activator: singlet oxygen-dominated catalytic degradation of organic contaminants. Appl Catal B Environ 251:335–345
Zhou H, Lai L, Wan Y, He Y, Yao G, Lai B (2020) Molybdenum disulfide (MoS2): a versatile activator of both peroxymonosulfate and persulfate for the degradation of carbamazepine. Chem Eng J 384:123264
Tan C, Lu X, Cui X, Jian X, Hu Z, Dong Y, Liu X, Huang J, Deng L (2019) Novel activation of peroxymonosulfate by an easily recyclable VC@Fe3O4 nanoparticles for enhanced degradation of sulfadiazine. Chem Eng J 363:318–328
Tan C, Jian X, Dong Y, Lu X, Liu X, Xiang H, Cui X, Deng J, Gao H (2019) Activation of peroxymonosulfate by a novel EGCE@Fe3O4 nanocomposite: free radical reactions and implication for the degradation of sulfadiazine. Chem Eng J 359:594–603
Dong X, Duan X, Sun Z, Zhang X, Li C, Yang S, Ren B, Zheng S, Dionysiou DD (2020) Natural illite-based ultrafine cobalt oxide with abundant oxygen-vacancies for highly efficient Fenton-like catalysis. Appl Catal B Environ 261:118214
Gao P, Tian X, Nie Y, Yang C, Zhou Z, Wang Y (2019) Promoted peroxymonosulfate activation into singlet oxygen over perovskite for ofloxacin degradation by controlling the oxygen defect concentration. Chem Eng J 359:828–839
Guo X, Ma Y-W, Wan J-Q (2012) Advanced treatment of papermaking wastewater by sulfate radical-based advanced oxidation process. China Pulp Paper 31(9):32
Wang B, Zhang H, Wang F, Xiong X, Tian K, Sun Y, Yu T (2019) Application of heterogeneous catalytic ozonation for refractory organics in wastewater. Catalysts 9(3):241
Wang J, Chen H (2020) Catalytic ozonation for water and wastewater treatment: recent advances and perspective. Sci Total Environ 704:135249
Zhu S, Dong B, Yu Y, Bu L, Deng J, Zhou S (2017) Heterogeneous catalysis of ozone using ordered mesoporous Fe3O4 for degradation of atrazine. Chem Eng J 328:527–535
Liu D, Wang C, Song Y, Wei Y, He L, Lan B, He X, Wang J (2019) Effective mineralization of quinoline and bio-treated coking wastewater by catalytic ozonation using CuFe2O4/Sepiolite catalyst: efficiency and mechanism. Chemosphere 227:647–656
Wang D, Xu H, Ma J, Lu X, Qi J, Song S (2018) Morphology control studies of MnTiO3 nanostructures with exposed {0001} facets as a high-performance catalyst for water purification. ACS Appl Mater Interfaces 10(37):31631–31640
Afzal S, Quan X, Lu S (2019) Catalytic performance and an insight into the mechanism of CeO2 nanocrystals with different exposed facets in catalytic ozonation of p-nitrophenol. Appl Catal B Environ 248:526–537
Zhu H, Ma W, Han H, Han Y, Ma W (2017) Catalytic ozonation of quinoline using nano-MgO: efficacy, pathways, mechanisms and its application to real biologically pretreated coal gasification wastewater. Chem Eng J 327:91–99
Vittenet J, Aboussaoud W, Mendret J, Pic J-S, Debellefontaine H, Lesage N, Faucher K, Manero M-H, Thibault-Starzyk F, Leclerc H, Galarneau A, Brosillon S (2015) Catalytic ozonation with γ-Al2O3 to enhance the degradation of refractory organics in water. Appl Catal A Gen 504:519–532
Wang Z, Ma H, Zhang C, Feng J, Pu S, Ren Y, Wang Y (2018) Enhanced catalytic ozonation treatment of dibutyl phthalate enabled by porous magnetic Ag-doped ferrospinel MnFe2O4 materials: performance and mechanism. Chem Eng J 354:42–52
Xiong Z, Lai B, Yuan Y, Cao J, Yang P, Zhou Y (2016) Degradation of p -nitrophenol (PNP) in aqueous solution by a micro-size Fe0/O3 process (mFe0/O3): optimization, kinetic, performance and mechanism. Chem Eng J 302:137–145
Zhang J, Guo J, Wu Y, Lan Y, Li Y (2017) Efficient activation of ozone by zero-valent copper for the degradation of aniline in aqueous solution. J Taiwan Inst Chem E 81:335–342
Xu Y, Lin Z, Zheng Y, Dacquin JP, Royer S, Zhang H (2019) Mechanism and kinetics of catalytic ozonation for elimination of organic compounds with spinel-type CuAl2O4 and its precursor. Sci Total Environ 651(Pt 2):2585–2596
Chen H, Wang J (2019) Catalytic ozonation of sulfamethoxazole over Fe3O4/Co3O4 composites. Chemosphere 234:14–24
Yuan X, Xie R, Zhang Q, Sun L, Long X, Xia D (2019) Oxygen functionalized graphitic carbon nitride as an efficient metal-free ozonation catalyst for atrazine removal: performance and mechanism. Sep Purif Technol 211:823–831
Song Z, Wang M, Wang Z, Wang Y, Li R, Zhang Y, Liu C, Liu Y, Xu B, Qi F (2019) Insights into heteroatom-doped graphene for catalytic ozonation: active centers, reactive oxygen species evolution, and catalytic mechanism. Environ Sci Technol 53:5337–5348
Zhu G, Zhu J, Jiang W, Zhang Z, Wang J, Zhu Y, Zhang Q (2017) Surface oxygen vacancy induced α-MnO2 nanofiber for highly efficient ozone elimination. Appl Catal B Environ 209:729–737
Wang Y, Chen L, Cao H, Chi Z, Chen C, Duan X, Xie Y, Qi F, Song W, Liu J, Wang S (2019) Role of oxygen vacancies and Mn sites in hierarchical Mn2O3/LaMnO3-δ perovskite composites for aqueous organic pollutants decontamination. Appl Catal B Environ 245:546–554
Liu Z-Q, Han B-J, Wen G, Ma J, Wang S-J, Zha R-G, Shen L-P, Wang C (2014) Full-scale application of catalytic ozonation for drinking water treatment: case study in China. J Environ Eng 140(9):A5013002
[Online]. http://aptwater.com/pulseox/case-studies/falconi-tropicana-honda-nv/?tdsourcetag=s_pctim_aiomsg
Zhang S, Gu P, Ma R, Luo C, Wen T, Zhao G, Cheng W, Wang X (2019) Recent developments in fabrication and structure regulation of visible-light-driven g-C3N4-based photocatalysts towards water purification: a critical review. Catal Today 335:65–77
Ghiyasiyan-Arani M, Masjedi-Arani M (2016) Size controllable synthesis of cobalt vanadate nanostructures with enhanced photocatalytic activity for the degradation of organic dyes. J Mol Catal A Chem 425:31–42
Li J, Li X, Yin Z, Wang X, Ma H, Wang L (2019) Synergetic effect of facet junction and specific facet activation of ZnFe2O4 nanoparticles on photocatalytic activity improvement. ACS Appl Mater Interfaces 11(32):29004–29013
Wang C-Y, Zhang Y-J, Wang W-K, Pei D-N, Huang G-X, Chen J-J, Zhang X, Yu H-Q (2018) Enhanced photocatalytic degradation of bisphenol A by Co-doped BiOCl nanosheets under visible light irradiation. Appl Catal B Environ 221:320–328
Xing Y, Gao X, Ji G, Liu Z, Du C (2019) Synthesis of carbon doped Bi2MoO6 for enhanced photocatalytic performance and tumor photodynamic therapy efficiency. Appl Surf Sci 465:369–382
Liu Y, Shen S, Zhang J, Zhong W, Huang X (2019) Cu2−xSe/CdS composite photocatalyst with enhanced visible light photocatalysis activity. Appl Surf Sci 478:762–769
Zhao W, Feng Y, Huang H, Zhou P, Li J, Zhang L, Dai B, Xu J, Zhu F, Sheng N, Leung DYC (2019) A novel Z-scheme Ag3VO4/BiVO4 heterojunction photocatalyst: study on the excellent photocatalytic performance and photocatalytic mechanism. Appl Catal B Environ 245:448–458
Cai J, Huang J, Lai Y (2017) 3D Au-decorated Bi2MoO6 nanosheet/TiO2 nanotube array heterostructure with enhanced UV and visible-light photocatalytic activity. J Mater Chem A 5(31):16422
Wen J, Xie J, Chen X, Li X (2017) A review on g-C3N4-based photocatalysts. Appl Surf Sci 391:72–123
Sharma S, Dutta V, Singh P, Raizada P, Rahmani-Sani A, Hosseini-Bandegharaei A, Thakur VK (2019) Carbon quantum dot supported semiconductor photocatalysts for efficient degradation of organic pollutants in water: a review. J Clean Prod 228:755–769
Li X, Yu J, Wageh S, Al-Ghamdi AA, Xie J (2016) Graphene in photocatalysis: a review. Small 12:6640–6696
Chen F, Yang Q, Li X, Zeng G, Wang D, Niu C, Zhao J, An H, Xie T, Deng Y (2017) Hierarchical assembly of graphene-bridged Ag3PO4/Ag/BiVO4 (040) Z-scheme photocatalyst: An efficient, sustainable and heterogeneous catalyst with enhanced visible-light photoactivity towards tetracycline degradation under visible light irradiation. Appl Catal B Environ 200:330–342
Yue X, Miao X, Ji Z, Shen X, Zhou H, Kong L, Zhu G, Li X, Shah SA (2018) Nitrogen-doped carbon dots modified dibismuth tetraoxide microrods: a direct Z-scheme photocatalyst with excellent visible-light photocatalytic performance. J Colloid Interf Sci 531:473–482
Xia P, Zhu B, Cheng B, Yu J, Xu J (2017) 2D/2D g-C3N4/MnO2 nanocomposite as a direct Z-scheme photocatalyst for enhanced photocatalytic activity. ACS Sustain Chem Eng 6(1):965–973
Xu Y, Li H, Sun B, Qiao P, Ren L, Tian G, Jiang B, Pan K, Zhou W (2020) Surface oxygen vacancy defect-promoted electron-hole separation for porous defective ZnO hexagonal plates and enhanced solar-driven photocatalytic performance. Chem Eng J 379:122295
Jia Y, Li S, Ma H, Gao J, Zhu G, Zhang F, Park JY, Cha S, Bae JS, Liu C (2020) Oxygen vacancy rich Bi2O4-Bi4O7-BiO2−x composites for UV-vis-NIR activated high efficient photocatalytic degradation of bisphenol A. J Hazard Mater 382:121121
Sörensen M, Zegenhagen F, Weckenmann J (2015) State of the art wastewater treatment in pharmaceutical and chemical industry by advanced oxidation. Pharm Ind 77(4):594–607
Author information
Authors and Affiliations
Corresponding author
Editor information
Editors and Affiliations
Rights and permissions
Copyright information
© 2021 Springer Nature Switzerland AG
About this entry
Cite this entry
Dai, C., Tian, X., Yang, C., Nie, Y., Wang, Y. (2021). Application of Heterogeneous Nanocatalysis-Based Advanced Oxidation Processes in Water Purification. In: Kharissova, O.V., Martínez, L.M.T., Kharisov, B.I. (eds) Handbook of Nanomaterials and Nanocomposites for Energy and Environmental Applications. Springer, Cham. https://doi.org/10.1007/978-3-030-11155-7_64-2
Download citation
DOI: https://doi.org/10.1007/978-3-030-11155-7_64-2
Received:
Accepted:
Published:
Publisher Name: Springer, Cham
Print ISBN: 978-3-030-11155-7
Online ISBN: 978-3-030-11155-7
eBook Packages: Springer Reference Chemistry and Mat. ScienceReference Module Physical and Materials ScienceReference Module Chemistry, Materials and Physics
Publish with us
Chapter history
-
Latest
Application of Heterogeneous Nanocatalysis-Based Advanced Oxidation Processes in Water Purification- Published:
- 04 March 2021
DOI: https://doi.org/10.1007/978-3-030-11155-7_64-2
-
Original
Current Water Treatment Technologies- Published:
- 28 November 2020
DOI: https://doi.org/10.1007/978-3-030-11155-7_64-1